The preparation, identification and properties of chlorophyll derivatives

In the investigation of 10-hydroxy chlorophylls a and b novel techniques included modification of chromatography and the use of fully-deuterated compounds isolated from fully-deuterated autotropic algae to determine the molecular structure of the chlorophylls

Nitrogen isotope abundance measurements

The abundance of the nitrogen isotopes in several sources of nitrogen have been determined. In atmospheric nitrogen the absolute ratio, N14/N15, is 272.0 ± 0.3. Small variations were observed for various sources of compressed gas but the isotopic composition of the nitrogen isotopes of the atmosphere was constant, to 1 part in 7000, in samples collected at different geographical sites and altitudes above these sites

Unitarity and Interfering Resonances in pipi Scattering and in Pion Production piN->pipiN

Additivity of Breit-Wigner phases has been proposed to describe interfering resonances in partial waves in $\pi\pi$ scattering. This assumption leads to an expression for partial wave amplitudes that involves products of Breit-Wigner amplitudes. We show that this expression is equivalent to a coherent sum of Breit-Wigner amplitudes with specific complex coefficients which depend on the resonance parameters of all contributing resonances. We use analyticity of $\pi\pi$ partial wave amplitudes to show that they must have the form of a coherent sum of Breit-Wigner amplitudes with complex coefficients and a complex coherent background. The assumption of additivity of Breit-Wigner phases restricts the partial waves to analytical functions with very specific form of residues of Breit-Wigner poles. We argue that the general form provided by the analyticity is more appropriate in fits to data to determine resonance parameters. The partial wave unitarity can be imposed using the modern methods of constrained optimization. We discuss unitarity and the production amplitudes in $\pi N\to\pi\pi N$ and use analyticity in the dipion mass variable to justify the common practice of writing the production amplitudes as a coherent sum of Breit-Wigner amplitudes with free complex coefficients and a complex coherent background in fits to mass spectra with interfering resonances.Comment: 31 page

Visitors' preferences of renewable energy options in 'green' hotels.

Tourism belongs to the industries with significant energy consumption. Visitors as well as hotel managers have, however, a positive attitude towards the responsible use of energy resources. The level of research on visitors’ preferences of using different types of renewable energy is low, unlike findings on factual characteristics of conventional and renewable energies. That is why our aim was to assess visitors’ preferences of environmentally friendly energy sources in hotels. Preferences of six types of renewable energy - “green” tariff energy, solar panels on the rooftops, solar panels on the ground, heat pumps, AD, wind turbine, were measured at four tourist destinations in the Czech Republic. The positive attitude of tourists towards the selected types of energy sources was confirmed. The highest preferences were found for solar panels installed on the rooftops. A typology of preferences was revealed by cluster analysis and differences between clusters were tested for independent variables. Clusters of visitors with a high and low interest in any type of renewable energy were identified as well as a cluster of visitors with interest in all types apart from solar panels installed on the ground - the visitor’s origin was found as the main differentiation factor

Mass and width of sigma(750) scalar meson from measurements of piN->pi(-)pi(+)N on polarized targets

The measurements of reactions $\pi^- p_\uparrow \to \pi^- \pi^+ n$ at 17.2 GeV/c and $\pi^+ n_\uparrow \to \pi^+ \pi^- p$ at 5.98 and 11.85 GeV/c made at CERN with polarized targets provide a model-independent and solution-independent evidence for a narrow scalar state sigma(750). The original chi^2 minimization method and the recent Monte Carlo method for amplitude analysis of data at 17.2 GeV/c are in excellent agreement. Both methods find that the mass distribution of the measured amplitude $|\overline S |^2\Sigma$ with recoil transversity ``up'' resonates near 750 MeV while the amplitude $|S|^2\Sigma$ with recoil transversity ``down'' is large and nonresonating. The amplitude $|S|^2\Sigma$ contributes as a strong background to S-wave intensity I_S = (|S|^2 + |\overline S |^2)\Sigma$and distorts the determinations of$\sigma$resonance parameters from$I_S$. To avoid this problem we perform a series of Breit-Wigner fits directly to the measured distribution$|\overline S |^2\Sigma$. The inclusion of various backgrounds causes the width of sigma(750) to become very narrow. Our best fit with$t$-averaged coherent background yields$m_\sigma = 753 \pm 19$MeV and$\Gamma_\sigma = 108 \pm 53$MeV. These values are in excellent agreement with Ellis-Lanik theorem for the width of scalar gluonium. The gluonium interpretation of$\sigma(750)$is also supported by the absence of$\sigma(750)$in reactions$\gamma\gamma \to \pi\pi$. We also show how data on polarized target invalidate essential assumptions of past determinations of$\pi\pi$ phase shifts .Comment: 77 page

Microstructure of (Hf-Ta-Zr-Nb)C high-entropy carbide at micro and nano/atomic level

Support from the projects APVV-15-0469, APVV-15-0621, VEGA 2/0163/16, and VEGA 2/0082/17 is acknowledged. MJR and EGC acknowledge the support of EPSRC grant XMAT (EP/K008749/2)

Vector and Scalar Meson Resonances in K→πππK\rightarrow\pi\pi\pi Decays

Corrections to $K\rightarrow\pi\pi\pi$ induced by vector and scalar meson exchange are investigated within chiral perturbation theory.Comment: 15pages, Latex-file, TUM-T31-41/9

Role of Scalar Meson Resonances in $K_{L}^{0} \rightarrow \pi^{0} \gamma \gamma Decay

Corrections to $K_{L}^{0}\rightarrow \pi^{0} \gamma \gamma$ decay induced by scalar meson exchange are studied within chiral perturbation theory. In spite of bad knowledge of scalar-mesons parameters, the calculated branching ratio can be changed by a few percent.Comment: 18 pages of text, 2 figures (available upon request); preprint IJS-TP-16-94 , TUM-T31-63-94