Colloidal Plasmonic Titanium Nitride Nanoparticles: Properties and Applications

Optical properties of colloidal plasmonic titanium nitride nanoparticles are examined with an eye on their photothermal via transmission electron microscopy and optical transmittance measurements. Single crystal titanium nitride cubic nanoparticles with an average size of 50 nm exhibit plasmon resonance in the biological transparency window. With dimensions optimized for efficient cellular uptake, the nanoparticles demonstrate a high photothermal conversion efficiency. A self-passivating native oxide at the surface of the nanoparticles provides an additional degree of freedom for surface functionalization.Comment: 17 pages, 4 figures, 1 abstract figur

Kpp and KKp Clusters

The three-body kaonic Kpp and KKp clusters are studied using the method of hyperspherical harmonics (HH) in momentum representation and differential Faddeev equations (DFE). We use different NN and KN interactions. Results obtained by the methods of HH and DFE are in reasonable agreement. The binding energy and the width show very strong dependence on the KN potential. We have two different classes of results: the results based on phenomenological strong KN potential, and the results obtained with much weaker chiral SU(3)-based KN potential

The general configuration-space Faddeev formalism for studying pd scattering

The configuration-space Faddeev equations are derived for p-d scattering taking into account the difference in interaction between the participant particles. Appropriate modifications have been made in the well-known configuration-space equations for n-d scattering. To show the effect of these modifications, the s-wave calculations are performed for bound state and scattering problems. We model the charge symmetry breaking effect for 3H and 3He with a modified Malfliet-Tjon MT I-III potential. Results obtained for elastic n-d and p-d scattering at Elab=14.1 MeV are compared with our prediction (Ref. [1]) and those of the Los-Alamos/Iowa group (Ref. [2])

The general configuration-space Faddeev formalism for studying pd scattering

The configuration-space Faddeev equations are derived for p-d scattering taking into account the difference in interaction between the participant particles. Appropriate modifications have been made in the well-known configuration-space equations for n-d scattering. To show the effect of these modifications, the s-wave calculations are performed for bound state and scattering problems. We model the charge symmetry breaking effect for 3H and 3He with a modified Malfliet-Tjon MT I-III potential. Results obtained for elastic n-d and p-d scattering at Elab=14.1 MeV are compared with our prediction (Ref. [1]) and those of the Los-Alamos/Iowa group (Ref. [2])

Colloidal Plasmonic Titanium Nitride Nanoparticles: Properties and Applications

Optical properties of colloidal plasmonic titanium nitride nanoparticles are examined with an eye on their photothermal and photocatalytic applications via transmission electron microscopy and optical transmittance measurements. Single crystal titanium nitride cubic nanoparticles with an average size of 50 nm, which was found to be the optimum size for cellular uptake with gold nanoparticles [1], exhibit plasmon resonance in the biological transparency window and demonstrate a high absorption efficiency. A self-passivating native oxide at the surface of the nanoparticles provides an additional degree of freedom for surface functionalization. The titanium oxide shell surrounding the plasmonic core can create new opportunities for photocatalytic applications

and

The three-body kaonic K̅pp and K̅K̅p clusters are studied using the method of hyperspherical harmonics (HH) in momentum representation and differential Faddeev equations (DFE). We use different NN and K̅N interactions. Results obtained by the methods of HH and DFE are in reasonable agreement. The binding energy and the width show very strong dependence on the K̅N potential. We have two different classes of results: the results based on phenomenological strong K̅N potential, and the results obtained with much weaker chiral SU(3)-based K̅N potential

Non-Collinear Phase in Rare-Earth Iron Garnet Films near the Compensation Temperature

The experimental discovery of the suppression effect of the non-collinear phase in strong magnetic fields near the compensation point in ferrimagnetic structures was made. The observations were carried out using the magneto-optical method by creating a lateral temperature gradient in the plane of the epitaxial films of iron garnets. The non-collinear phase is absent in weak magnetic fields. If an external magnetic field exceeds the first critical value, the non-collinear phase arises near the compensation point. The temperature range of the non-collinear phase expands due to the field increase up to the second critical value. Further field increases conversely reduce the temperature range of the non-collinear phase so that the field above the second critical value causes the disappearance of the non-collinear phase. The effect of the occurrence and suppression of the non-collinear phase is demonstrated on samples of two types of iron garnet films with two and three magnetic sublattices. Phase diagrams of the magnetic states in the vicinity of the critical point are constructed, and it is shown that the region of existence of the non-collinear phase in a two-sublattice magnet is smaller than in a three-sublattice one

Anti-influenza activity of diazaadamantanes combined with monoterpene moieties

The antiviral activity of several diaza-adamantanes containing monoterpenoid moieties against a rimantadine-resistant strain of the influenza A/Puerto Rico/8/34 (H1N1) virus was studied. Hetero-adamantanes containing monoterpene moieties at the aminal position of the heterocycle were found to exhibit lower activity compared to compounds with a diaza-adamantane fragment and a monoterpene moiety linked via an amino group at the 6-position of the hetero-adamantane ring. The highest selectivity index (a ratio of the 50% cytotoxic concentration to the 50% inhibitory concentration) out of 30 was observed for compound 8d, which contains a citronellal monoterpenoid moiety. Diaza-adamantane 8d was superior to its adamantane-containing analog 5 both in its anti-influenza activity and selectivity. Furthermore, 8d has more balanced physicochemical properties than 5, making the former a more promising drug candidate. Modelling these compounds against an influenza virus M2 ion channel predicted plausible binding modes to both the wild-type and the mutant (S31N)