17 research outputs found
Conductivity and permittivity of dispersed systems with penetrable particle-host interphase
A model for the study of the effective quasistatic conductivity and
permittivity of dispersed systems with particle-host interphase, within which
many-particle polarization and correlation contributions are effectively
incorporated, is presented. The structure of the system's components, including
the interphase, is taken into account through modelling their low-frequency
complex permittivity profiles. The model describes, among other things, a
percolation-type behavior of the effective conductivity, accompanied by a
considerable increase in the real part of the effective complex permittivity.
The percolation threshold location is determined mainly by the thickness of the
interphase. The "double" percolation effect is predicted. The results are
contrasted with experiment.Comment: 10 pages, 10 figure
Experimental observation of triple correlations in fluids
We present arguments for the hypothesis that under some conditions, triple
correlations of density fluctuations in fluids can be detected experimentally
by the method of molecular spectroscopy. These correlations manifest themselves
in the form of the so-called 1.5- (i.e., sesquialteral) scattering. The latter
is of most significance in the pre-asymptotic vicinity of the critical point
and can be registered along certain thermodynamic paths. Its presence in the
overall scattering pattern is demonstrated by our processing experimental data
for the depolarization factor. Some consequences of these results are
discussed.Comment: 12 pages 12 figure
Effective permittivity of mixtures of anisotropic particles
We use a new approach to derive dielectric mixing rules for macroscopically
homogeneous and isotropic multicomponent mixtures of anisotropic inhomogeneous
dielectric particles. Two factors of anisotropy are taken into account, the
shape of the particles and anisotropy of the dielectric parameters of the
particles' substances. Our approach is based upon the notion of macroscopic
compact groups of particles and the procedure of averaging of the fields over
volumes much greater than the typical scales of these groups. It enables us to
effectively sum up the contributions from multiple interparticle reemission and
short-range correlation effects, represented by all terms in the infinite
iterative series for the electric field strength and induction. The expression
for the effective permittivity can be given the form of the Lorentz-Lorenz
type, which allows us to determine the effective polarizabilities of the
particles in the mixture. These polarizabilities are found as integrals over
the regions occupied by the particles and taken of explicit functions of the
principal components of the permittivity tensors of the particles' substances
and the permittivity of the host medium. The case of a mixture of particles of
the ellipsoidal shape is considered in detail to exemplify the use of general
formulas. As another example, Bruggeman-type formulas are derived under
pertinent model assumptions. The ranges of validity of the results obtained are
discussed as well.Comment: 9 pages, 4 figure