Large Magneto-Dielectric Effects in Orthorhombic HoMnO3 and YMnO3

We have found a remarkable increase (up to 60 %) of the dielectric constant with the onset of magnetic order at 42 K in the metastable orthorhombic structures of YMnO3 and HoMnO3 that proves the existence of a strong magneto-dielectric coupling in the compounds. Magnetic, dielectric, and thermodynamic properties show distinct anomalies at the onset of the incommensurate magnetic order and thermal hysteresis effects are observed around the lock-in transition temperature at which the incommensurate magnetic order locks into a temperature independent wave vector. The orders of Mn3+ spins and Ho3+ moments both contribute to the magneto-dielectric coupling. A large magneto-dielectric effect was observed in HoMnO3 at low temperature where the dielectric constant can be tuned by an external magnetic field resulting in a decrease of up to 8 % at 7 Tesla. By comparing data for YMnO3 and HoMnO3 the contributions to the coupling between the dielectric response and Mn and Ho magnetic orders are separated.Comment: revised manuscrip

Site-dependent charge transfer at the Pt(111)-ZnPc interface and the effect of iodine

The electronic structure of ZnPc, from sub-monolayers to thick films, on bare and iodated Pt(111) is studied by means of X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS) and scanning tunneling microscopy (STM). Our results suggest that at low coverage ZnPc lies almost parallel to the Pt(111) substrate, in a non-planar configuration induced by Zn-Pt attraction, leading to an inhomogeneous charge distribution within the molecule and charge transfer to the molecule. ZnPc does not form a complete monolayer on the Pt surface, due to a surface-mediated intermolecular repulsion. At higher coverage ZnPc adopts a tilted geometry, due to a reduced molecule-substrate interaction. Our photoemission results illustrate that ZnPc is practically decoupled from Pt, already from the second layer. Pre-deposition of iodine on Pt hinders the Zn-Pt attraction, leading to a non-distorted first layer ZnPc in contact with Pt(111)-I $\left(\sqrt{3}\times\sqrt{3}\right)$ or Pt(111)-I $\left(\sqrt{7}\times\sqrt{7}\right)$, and a more homogeneous charge distribution and charge transfer at the interface. On increased ZnPc thickness iodine is dissolved in the organic film where it acts as an electron acceptor dopant.Comment: 12 pages, 9 figure

Temperature dependence of electron-spin relaxation in a single InAs quantum dot at zero applied magnetic field

The temperature-dependent electron spin relaxation of positively charged excitons in a single InAs quantum dot (QD) was measured by time-resolved photoluminescence spectroscopy at zero applied magnetic fields. The experimental results show that the electron-spin relaxation is clearly divided into two different temperature regimes: (i) T < 50 K, spin relaxation depends on the dynamical nuclear spin polarization (DNSP) and is approximately temperature-independent, as predicted by Merkulov et al. (ii) T > about 50 K, spin relaxation speeds up with increasing temperature. A model of two LO phonon scattering process coupled with hyperfine interaction is proposed to account for the accelerated electron spin relaxation at higher temperatures.Comment: 10 pages, 4 figure

Brueckner-Hartree-Fock and its renormalized calculations for finite nuclei

We have performed self-consistent Brueckner-Hartree-Fock (BHF) and its renormalized theory to the structure calculations of finite nuclei. The $G$-matrix is calculated within the BHF basis, and the exact Pauli exclusion operator is determined by the BHF spectrum. Self-consistent occupation probabilities are included in the renormalized Brueckner-Hartree-Fock (RBHF). Various systematics and convergences are studies. Good results are obtained for the ground-state energy and radius. RBHF can give a more reasonable single-particle spectrum and radius. We present a first benchmark calculation with other {\it ab initio} methods using the same effective Hamiltonian. We find that the BHF and RBHF results are in good agreement with other $\it{ab}$ $\it{initio}$ methods

Nitrogen-induced magnetic transition in small chromium clusters

Using density functional theory with generalized gradient approximation for exchange and correlation, we show that otherwise antiferromagnetically coupled chromium atoms in very small chromium clusters couple ferromagnetically when doped with a nitrogen atom, thus leading to giant magnetic moments. For example, the magnetic moment of Cr2N is found to be 9μBwhile that of Cr2 is 0μB. Strong bonding between Cr and N atoms brings about this magnetic transition. The Cr atoms nearest neighbor to N couple ferromagnetically with each other and antiferromagnetically with nitrogen. The significance of these results in understanding the ferromagnetic order in Cr-doped GaN is discussed