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Atomic data from the Iron Project XLV. Relativistic transition probabilities for carbon-like Ar XIII and Fe XXI using Breit-Pauli R-matrix method
The Breit-Pauli R-matrix method developed under the Iron Project has been
used to obtain extensive sets of oscillator strengths and transition
probabilities for dipole allowed and intercombination fine structure
transitions in carbon like ions, Ar XIII and Fe XXI. The complete set consists
of 1274 fine structure bound energy levels and 198,259 oscillator strengths for
Ar XIII, and 1611 bound levels and 300,079 oscillator strengths for Fe XXI.
These correspond to levels of total angular momenta of 0 <= J <= 7 of even and
odd parities formed from total spin of 2S+1=5,3,1, and orbital angular momenta
0 <= L <= 9 with n <= 10, 0 <= l <= 9 for each ion. The relativistic effects
are included in the Breit-Pauli approximation. The close coupling wavefunction
expansion for each ion is represented by the lowest 15 fine structure levels of
target configuations, 2s2.2p, 2s.2p2 and 2p3. The energy levels are identified
spectroscopically using a newly developed identification procedure. The
procedure also makes a correspondence between the fine strucure energy levels
and LS terms. This provides the check for completeness of the calculated
levels. Comparison is made of the present energies and the f-values with the
available observed and theoretical values. Present transition probabilitis
agree very well with the relativistic atomic structure calculations of Mendoza
et al. for the intercombination transitions, 2s.2p3(5So)2 -
2s2.2p2(3P){1,2},(1D)2. This further indicates that the importance of the
neglected Breit interaction decreases with ion charge and constrains the
uncertainty in the present calculations to within 15% even for the weak
transitions.Comment: Submitted to AA Sup
Electron-Ion Recombination Rate Coefficients and Photoionization Cross Sections for Astrophysically Abundant Elements. VII. Relativistic calculations for O VI and O VII for UV and X-ray modeling
Aimed at ionization balance and spectral analysis of UV and X-ray sources, we
present self-consistent sets of photoionization cross sections, recombination
cross sections, and rate coefficients for Li-like O VI and He-like O VII.
Relativistic fine structure is considered through the Breit-Pauli R-matrix
(BPRM) method in the close coupling approximation, implementing the unified
treatment for total electron-ion recombination subsuming both radiative and
di-electronic recombination processes. Self-consistency is ensured by using an
identical wavefunction expansion for the inverse processes of photoionization
and photo-recombination. Radiation damping of resonances, important for H-like
and He-like core ions, is included. Compared to previous LS coupling results
without radiative decay of low-n (<= 10) resonances, the presents results show
significant reduction in O VI recombination rates at high temperatures. In
addition to the total rates, level-specific photoionization cross sections and
recombination rates are presented for all fine structure levels n (lSLJ) up to
n <= 10, to enable accurate computation of recombination-cascade matrices and
spectral formation of prominent UV and X-ray lines such as the 1032,1038 A
doublet of O VI, and the `triplet' forbidden, intercombination, and resonance
X-ray lines of O VII at 22.1, 21.8, and 21.6 \ang respectively. Altogether,
atomic parameters for 98 levels of O VI and 116 fine structure levels of O VII
are theoretically computed. These data should provide a reasonably complete set
of photoionization and recombination rates in collisional or radiative
equilibrium.Comment: 33 pages, 8 figures, submitted to ApJ
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