4 research outputs found
Bromination of Graphene: A New Route to Making High Performance Transparent Conducting Electrodes with Low Optical Losses
The unique optical and electrical
properties of graphene have triggered great interest in its application
as a transparent conducting electrode material and significant effort
has been invested in achieving high conductivity while maintaining
high transparency. Doping of graphene has been a popular route for
reducing its sheet resistance, but this has typically come at a significant
loss in optical transmittance. We demonstrate doping of few layers
graphene (FLG) with bromine as a means of enhancing the conductivity
via intercalation without major optical losses. Our results demonstrate
the encapsulation of bromine within the FLG, leading to air-stable
transparent conducting electrodes with 5-fold improvement of sheet
resistance reaching ∼180 Ω/□ at the cost of only
2–3% loss of optical transmittance. The remarkably low trade-off
in optical transparency leads to the highest enhancements in the figure
of merit reported thus far for FLG. Furthermore, we tune the work
function by up to 0.3 eV by tuning the bromine content. These results
should help pave the way for further development of graphene as a
potential substitute to transparent conducting polymers and metal
oxides used in optoelectronics, photovoltaics, and beyond
Functional Two-Dimensional Coordination Polymeric Layer as a Charge Barrier in Li–S Batteries
Ultrathin
two-dimensional (2D) polymeric layers are capable of
separating gases and molecules based on the reported size exclusion
mechanism. What is equally important but missing today is an exploration
of the 2D layers with charge functionality, which enables applications
using the charge exclusion principle. This work demonstrates a simple
and scalable method of synthesizing a free-standing 2D coordination
polymer Zn<sub>2</sub>(benzimidazolate)<sub>2</sub>(OH)<sub>2</sub> at the air–water interface. The hydroxyl (−OH) groups
are stoichiometrically coordinated and implement electrostatic charges
in the 2D structures, providing powerful functionality as a charge
barrier. Electrochemical performance of the Li–S battery shows
that the Zn<sub>2</sub>(benzimidazolate)<sub>2</sub>(OH)<sub>2</sub> coordination polymer layers efficiently mitigate the polysulfide
shuttling effects and largely enhance the battery capacity and cycle
performance. The synthesis of the proposed coordination polymeric
layers is simple, scalable, cost saving, and promising for practical
use in batteries
Surface Restructuring of Hybrid Perovskite Crystals
Hybrid
perovskite crystals have emerged as an important class of
semiconductors because of their remarkable performance in optoelectronics
devices. The interface structure and chemistry of these crystals are
key determinants of the device’s performance. Unfortunately,
little is known about the intrinsic properties of the surfaces of
perovskite materials because extrinsic effects, such as complex microstructures,
processing conditions, and hydration under ambient conditions, are
thought to cause resistive losses and high leakage current in solar
cells. We reveal the intrinsic structural and optoelectronic properties
of both pristinely cleaved and aged surfaces of single crystals. We
identify surface restructuring on the aged surfaces (visualized on
the atomic-scale by scanning tunneling microscopy) that lead to compositional
and optical bandgap changes as well as degradation of carrier dynamics,
photocurrent, and solar cell device performance. The insights reported
herein clarify the key variables involved in the performance of perovskite-based
solar cells and fabrication of high-quality surface single crystals,
thus paving the way toward their future exploitation in highly efficient
solar cells
Double Charged Surface Layers in Lead Halide Perovskite Crystals
Understanding defect
chemistry, particularly ion migration, and its significant effect
on the surface’s optical and electronic properties is one of
the major challenges impeding the development of hybrid perovskite-based
devices. Here, using both experimental and theoretical approaches,
we demonstrated that the surface layers of the perovskite crystals
may acquire a high concentration of positively charged vacancies with
the complementary negatively charged halide ions pushed to the surface.
This charge separation near the surface generates an electric field
that can induce an increase of optical band gap in the surface layers
relative to the bulk. We found that the charge separation, electric
field, and the amplitude of shift in the bandgap strongly depend on
the halides and organic moieties of perovskite crystals. Our findings
reveal the peculiarity of surface effects that are currently limiting
the applications of perovskite crystals and more importantly explain
their origins, thus enabling viable surface passivation strategies
to remediate them