3,267 research outputs found
Spherical solid-propellant rocket motor Patent
Spherical solid propellant rocket engine desig
High-throughput in-situ characterization and modelling of precipitation kinetics in compositionally graded alloys
The development of new engineering alloy chemistries is a time consuming and
iterative process. A necessary step is characterization of the
nano/microstructure to provide a link between the processing and properties of
each alloy chemistry considered. One approach to accelerate the identification
of optimal chemistries is to use samples containing a gradient in composition,
ie. combinatorial samples, and to investigate many different chemistries at the
same time. However, for engineering alloys, the final properties depend not
only on chemistry but also on the path of microstructure development which
necessitates characterization of microstructure evolution for each chemistry.
In this contribution we demonstrate an approach that allows for the in-situ,
nanoscale characterization of the precipitate structures in alloys, as a
function of aging time, in combinatorial samples containing a composition
gradient. The approach uses small angle x-ray scattering (SAXS) at a
synchrotron beamline. The Cu-Co system is used for the proof-of-concept and the
combinatorial samples prepared contain a gradient in Co from 0% to 2%. These
samples are aged at temperatures between 450{\textdegree}C and
550{\textdegree}C and the precipitate structures (precipitate size, volume
fraction and number density) all along the composition gradient are
simultaneously monitored as a function of time. This large dataset is used to
test the applicability and robustness of a conventional class model for
precipitation that considers concurrent nucleation, growth and coarsening and
the ability of the model to describe such a large dataset.Comment: Published in Acta Materiali
Long term time-lapse microgravity and geotechnical monitoring of relict salt-mines, Marston, Cheshire, UK.
The area around the town of Northwich in Cheshire, U. K., has a long history of catastrophic ground subsidence caused by a combination of natural dissolution and collapsing abandoned mine workings within the underlying Triassic halite bedrock geology. In the village of Marston, the Trent and Mersey Canal crosses several abandoned salt mine workings and previously subsiding areas, the canal being breached by a catastrophic subsidence event in 1953. This canal section is the focus of a long-term monitoring study by conventional geotechnical topographic and microgravity surveys. Results of 20 years of topographic time-lapse surveys indicate specific areas of local subsidence that could not be predicted by available site and mine abandonment plan and shaft data. Subsidence has subsequently necessitated four phases of temporary canal bank remediation. Ten years of microgravity time-lapse data have recorded major deepening negative anomalies in specific sections that correlate with topographic data. Gravity 2D modeling using available site data found upwardly propagating voids, and associated collapse material produced a good match with observed microgravity data. Intrusive investigations have confirmed a void at the major anomaly. The advantages of undertaking such long-term studies for near-surface geophysicists, geotechnical engineers, and researchers working in other application areas are discussed
Geodynamic setting and origin of the Oman/UAE ophiolite
The ~500km-long mid-Cretaceous Semail nappe of the Sultanate of Oman and UAE (henceforth referred to as the Oman ophiolite) is the largest and best-preserved ophiolite complex known. It is of particular importance because it is generally believed to have an internal structure and composition closely comparable to that of crust formed at the present-day East Pacific Rise (EPR), making it our only known on-land analogue for ocean lithosphere formed at a fast spreading rate. On the basis of this assumption Oman has long played a pivotal role in guiding our conceptual understanding of fast-spreading ridge processes, as modern fast-spread ocean crust is largely inaccessible
Multispin correlations and pseudo-thermalization of the transient density matrix in solid-state NMR: free induction decay and magic echo
Quantum unitary evolution typically leads to thermalization of generic
interacting many-body systems. There are very few known general methods for
reversing this process, and we focus on the magic echo, a radio-frequency pulse
sequence known to approximately "rewind" the time evolution of dipolar coupled
homonuclear spin systems in a large magnetic field. By combining analytic,
numerical, and experimental results we systematically investigate factors
leading to the degradation of magic echoes, as observed in reduced revival of
mean transverse magnetization. Going beyond the conventional analysis based on
mean magnetization we use a phase encoding technique to measure the growth of
spin correlations in the density matrix at different points in time following
magic echoes of varied durations and compare the results to those obtained
during a free induction decay (FID). While considerable differences are
documented at short times, the long-time behavior of the density matrix appears
to be remarkably universal among the types of initial states considered -
simple low order multispin correlations are observed to decay exponentially at
the same rate, seeding the onset of increasingly complex high order
correlations. This manifestly athermal process is constrained by conservation
of the second moment of the spectrum of the density matrix and proceeds
indefinitely, assuming unitary dynamics.Comment: 12 Pages, 9 figure
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