Air/methane mixture ignition with Multi-Walled Carbon Nanotubes (MWCNTs) and comparison with spark ignition

The possibility to ignite the single wall carbon nanotubes (SWCNTs) containing impurities of iron in atmosphere once exposed to the radiation of a flash camera was observed for the first time in 2002. Afterwards, it was proposed to exploit this property in order to use nanostructured materials as ignition agents for fuel mixtures. Finally, in 2011 it was shown that SWCNTs can be effectively used as ignition source for an air/ethylene mixture filling a constant volume combustion chamber; the observed combustion presented the characteristics of a homogeneous-like combustion. In this paper a system for the ignition of an air/methane mixture is proposed, based on the exposition of multi wall carbon nanotubes (MWCNTs) to a low consumption flash camera. Namely, several experiments have been run in which 20 mg of MWCNTs, containing 75% in weight of ferrocene, have been added to an air/methane fuel mixture inside a constant volume combustion chamber. The mixture has been heated up to 373 K and the onset pressure was set equal to 3 bar. The experiments have been run varying the equivalence ratio in the range 1–2. The combustion process so realized has been compared to that obtained igniting the mixture with a traditional spark as in spark ignition engines. The comparison has been based on chamber pressure measurement as well as combustion process images, both sampled at a frequency equal to 2,5 kHz for an overall duration of 1.8 s. Results confirm that the ignition triggered with MWCNTs leads to a homogeneous-like combustion, without observing a well-defined flame front propagation. The contrary is observed, as expected, with the spark assisted ignition. Moreover, dynamic pressure measurements show that, compared to spark assisted ignition, the MWCNTs photo-ignition determines a more rapid pressure gradient and a higher peak pressure which corresponds to a higher energy release rate

Multi-Walled Carbon Nanotubes (MWCNTs) as ignition agents for air/methane mixtures

The possibility to ignite the Single Wall Carbon Nanotubes (SWCNTs) once exposed to the radiation of a flash camera, was observed for the first time in 2002. Subsequently, it was proposed to exploit this property in order to use nanostructured materials as ignition agents for fuel mixtures. Lastly, in 2011, it was shown that SWCNTs can be effectively used as ignition source for an air/ethylene mixture filling a constant volume combustion chamber; the observed combustion presented the characteristics of a homogeneous-like combustion. In the presented experimental activity, the potentiality of igniting an air/methane mixture by flashing Multi Wall Carbon Nanotubes (MWCNTs) has been exploited, and the results compared with those obtained igniting the mixture with a traditional spark plug. In detail, two types of tests have been carried out: the first, aiming at comparing the combustion process flashing a variable amount of nanoparticles introduced into the combustion chamber at fixed air/methane ratio; the second, at comparing the combustion process with the one obtained using a traditional engine spark plug, varying the air/methane ratio and at fixed amount of MWCNTs. During tests, the combustion process has been characterized measuring the pressure into the combustion chamber as well as acquiring images with a high-speed camera. The results confirm that the ignition triggered with MWCNTs leads to a faster combustion, without observing a well-defined flame front propagation, observed, as expected, with the spark assisted ignition. Moreover, dynamic pressure measurements show that the MWCNTs photo-ignition determines a more rapid pressure gradient and a higher heat release rate compared to spark assisted ignition

Improvement of dual-fuel biodiesel-producer gas engine performance acting on biodiesel injection parameters and strategy

none4noDual-fuel biodiesel-producer gas combustion has shown potential in reducing nitric oxides and particulate emission levels compared to only diesel operation; however, engine overall efficiency is slightly penalized, while the main drawbacks are represented by the higher levels of total hydrocarbons and carbon monoxide emissions. In this work, the improvements in the combustion development deriving from the splitting of the liquid fuel injection at low loads have been assessed using a 0.51 L single-cylinder research diesel engine equipped with a high pressure common rail injection system and operated in dual-fuel mode. In this case, a synthetic producer gas was used as inducted gaseous fuel, while biodiesel was used as pilot fuel. Initially, the spray morphology was characterized in a constant-volume vessel for different values of injection duration and pressure, as well as vessel backpressure. Then, the experimental campaign, run on the engine at 1500 rpm, was divided in two sessions. During the former, only one pilot injection of constant fuel amount (11 mm3/cycle) was performed, the rail pressure was set equal to 500 or 1000 bar, the injection timing was varied in the range −50 ÷ 5 degrees crank angle after top dead center while the amount of gaseous fuel inducted in the cylinder was varied on three levels. During the latter, the pilot fuel amount, kept equal to the one pilot injection tests, was split in two smaller injections and the effect of the dwell between them – varied in the range 5 ÷50 degrees crank angle – was investigated as well. The results of the first set of experiments revealed that pilot injection timing and pressure both affect the combustion development. This resulted in sensible variations on thermal and combustion efficiencies, and therefore on fuel conversion efficiency, the last one exhibiting higher values with pilot injection timing slightly advanced respect to top dead center and lower injection pressure. In these conditions, total hydrocarbons and carbon monoxide are lowered, while nitric oxides are increased. The amount of gas demonstrated to have asecondary effect on combustion development and emissions levels at the exhaust. Splitting pilot injection, demonstrated to be an effective way to increase fuel conversion efficiency and to reduce the levels of all the pollutant species compared to the single pilot injection strategy. Based on the extensive experimental activity described in this paper, a dwell ranging between 10 and 30 degrees of crank angle, combined with a first injection timing ranging between 35 and 20 degrees of crank angle before top dead center guarantee the highest fuel conversion efficiency and the lowest pollutants emission levels. Injection pressure confirmed to be a significant factor in affecting the combustion development, while a secondary effect was determined by the gaseous mass inducted in the cylinder.Ultimately, pilot injection splitting demonstrated to be an effective way for improving gaseous fuel combustion in dual-fuel mode at low load (lean mixture) conditions.mixedCarlucci, A.P.; Strafella, L.; Ficarella, A.; Laforgia, D.Carlucci, Antonio Paolo; Strafella, Luciano; Ficarella, Antonio; Laforgia, Domenic

Morphological analysis of injected sprays of different bio-diesel fuels by using a common rail setup controlled by a programmable electronic system

Biodiesel fuels are increasingly attracting interest in the scientific community and in the world motor industry. The morphological analysis of injected sprays is a key factor to increase engine performances using new biodiesel fuels and to compare them with those related to the use of conventional fuels. In this paper, an experimental setup is realised to carry out test campaigns, in order to analyse and compare the spray injections of different fuel typologies. A PC-interfaced electronic system was realised for driving BOSCH injectors and for varying the injection pressure and opening time. Hence, the morphological analysis was performed for each tested fuel by characterising the shaperatio and penetration depth inside the velocimetric chamber. The results show higher penetration values for biodiesel fuels due to their viscosity and drops in superficial tension, which facilitate a deeper penetration compared to those obtained with conventional diesel fuels. Although used biodiesels contain only 20% of renewable vegetable-origin diesel fuels, the viscosity and superficial tension are slightly higher than those of petroleum diesel, thus determining a weak vaporisation and formation of larger drops. By knowing the morphological behaviour of sprays using biofuels and conventional fuel, it is possible, by using programmable electronic systems, to adjust and improve the spray parameters in order to obtain better engine performances. The results reported in this instance could be utilised by future research works for choosing the most suitable biofuel based on the desired morphological behaviour of the injected sprays

Biodiesel production from Cynara cardunculus L. and Brassica carinata A. Braun seeds and their suitability as fuels in compression ignition engines

The development of energy crops can provide environmental benefits and may represent an opportunity to improve agriculture in areas considered at low productivity. In this work, we studied the energy potential of two species (Brassica carinata A. Braun and Cynara cardunculus L.) and their seed oil productivity under different growth conditions. Furthermore, the biodiesel from the oil extracted from the seeds of these species was produced and analysed in term of utilisation as fuels in compression ignition engines. In particular, the spray penetration and shape ratio were measured in a constant-volume chamber and compared with the results obtained with a standard diesel fuel. These results were obtained using a standard common rail injection system at different injection pressure, injection duration, and constant-volume chamber pressure

Testing the physiological plausibility of conflicting psychological models of response inhibition: A forward inference fMRI study

The neural mechanisms underlying response inhibition and related disorders are unclear and controversial for several reasons. First, it is a major challenge to assess the psychological bases of behaviour, and ultimately brain-behaviour relationships, of a function which is precisely intended to suppress overt measurable behaviours. Second, response inhibition is difficult to disentangle from other parallel processes involved in more general aspects of cognitive control. Consequently, different psychological and anatomo-functional models coexist, which often appear in conflict with each other even though they are not necessarily mutually exclusive. The standard model of response inhibition in go/no-go tasks assumes that inhibitory processes are reactively and selectively triggered by the stimulus that participants must refrain from reacting to. Recent alternative models suggest that action restraint could instead rely on reactive but non-selective mechanisms (all automatic responses are automatically inhibited in uncertain contexts) or on proactive and non-selective mechanisms (a gating function by which reaction to any stimulus is prevented in anticipation of stimulation when the situation is unpredictable). Here, we assessed the physiological plausibility of these different models by testing their respective predictions regarding event-related BOLD modulations (forward inference using fMRI). We set up a single fMRI design which allowed for us to record simultaneously the different possible forms of inhibition while limiting confounds between response inhibition and parallel cognitive processes. We found BOLD dynamics consistent with non-selective models. These results provide new theoretical and methodological lines of inquiry for the study of basic functions involved in behavioural control and related disorders