Off-diagonal Interactions, Hund's Rules and Pair-binding in Hubbard Molecules

We have studied the effect of including nearest-neighbor, electron-electron interactions, in particular the off-diagonal (non density-density) terms, on the spectra of truncated tetrahedral and icosahedral ``Hubbard molecules,'' focusing on the relevance of these systems to the physics of doped C$_{60}$. Our perturbation theoretic and exact diagonalization results agree with previous work in that the density-density term suppresses pair-binding. However, we find that for the parameter values of interest for $C_{60}$ the off-diagonal terms {\em enhance} pair-binding, though not enough to offset the suppression due to the density-density term. We also find that the critical interaction strengths for the Hund's rules violating level crossings in C$_{60}^{-2}$, C$_{60}^{-3}$ and C$_{60}^{-4}$ are quite insensitive to the inclusion of these additional interactions.Comment: 20p + 5figs, Revtex 3.0, UIUC preprint P-94-10-08

Effects of Next-Nearest-Neighbor Hopping on the Hole Motion in an Antiferromagnetic Background

In this paper we study the effect of next-nearest-neighbor hopping on the dynamics of a single hole in an antiferromagnetic (N\'{e}el) background. In the framework of large dimensions the Green function of a hole can be obtained exactly. The exact density of states of a hole is thus calculated in large dimensions and on a Bethe lattice with large coordination number. We suggest a physically motivated generalization to finite dimensions (e.g., 2 and 3). In $d=2$ we present also the momentum dependent spectral function. With varying degree, depending on the underlying lattice involved, the discrete spectrum for holes is replaced by a continuum background and a few resonances at the low energy end. The latter are the remanents of the bound states of the $t-J$ model. Their behavior is still largely governed by the parameters $t$ and $J$. The continuum excitations are more sensitive to the energy scales $t$ and $t_1$.Comment: To appear in Phys. Rev. B, Revtex, 23 pages, 10 figures available on request from [email protected]

Robustness of a local Fermi Liquid against Ferromagnetism and Phase Separation

We study the properties of Fermi Liquids with the microscopic constraint of a local self-energy. In this case the forward scattering sum-rule imposes strong limitations on the Fermi-Liquid parameters, which rule out any Pomeranchek instabilities. For both attractive and repulsive interactions, ferromagnetism and phase separation are suppressed. Superconductivity is possible in an s-wave channel only. We also study the approach to the metal-insulator transition, and find a Wilson ratio approaching 2. This ratio and other properties of Sr_{1-x}La_xTiO_3 are all consistent with the local Fermi Liquid scenario.Comment: 4 pages (twocolumn format), can compile with or without epsf.sty latex style file -- Postscript files: fig1.ps and fig2.p

Rigorous results on superconducting ground states for attractive extended Hubbard models

We show that the exact ground state for a class of extended Hubbard models including bond-charge, exchange, and pair-hopping terms, is the Yang "eta-paired" state for any non-vanishing value of the pair-hopping amplitude, at least when the on-site Coulomb interaction is attractive enough and the remaining physical parameters satisfy a single constraint. The ground state is thus rigorously superconducting. Our result holds on a bipartite lattice in any dimension, at any band filling, and for arbitrary electron hopping.Comment: 12 page

Exact ground-state correlation functions of the one-dimensional strongly correlated electron models with the resonating-valence-bond ground state

We investigate the one-dimensional strongly correlated electron models which have the resonating-valence-bond state as the exact ground state. The correlation functions are evaluated exactly using the transfer matrix method for the geometric representations of the valence-bond states. In this method, we only treat matrices with small dimensions. This enables us to give analytical results. It is shown that the correlation functions decay exponentially with distance. The result suggests that there is a finite excitation gap, and that the ground state is insulating. Since the corresponding non-interacting systems may be insulating or metallic, we can say that the gap originates from strong correlation. The persistent currents of the present models are also investigated and found to be exactly vanishing.Comment: 59 pages, REVTeX 3.0, Figures are available on reques

Network Analysis of Biochemical Logic for Noise Reduction and Stability: A System of Three Coupled Enzymatic AND Gates

We develop an approach aimed at optimizing the parameters of a network of biochemical logic gates for reduction of the "analog" noise buildup. Experiments for three coupled enzymatic AND gates are reported, illustrating our procedure. Specifically, starch - one of the controlled network inputs - is converted to maltose by beta-amylase. With the use of phosphate (another controlled input), maltose phosphorylase then produces glucose. Finally, nicotinamide adenine dinucleotide (NAD+) - the third controlled input - is reduced under the action of glucose dehydrogenase to yield the optically detected signal. Network functioning is analyzed by varying selective inputs and fitting standardized few-parameters "response-surface" functions assumed for each gate. This allows a certain probe of the individual gate quality, but primarily yields information on the relative contribution of the gates to noise amplification. The derived information is then used to modify our experimental system to put it in a regime of a less noisy operation.Comment: 31 pages, PD

Magnetic Properties of the t-J Model in the Dynamical Mean-Field Theory

We present a theory for the spin correlation function of the t-J model in the framework of the dynamical mean-field theory. Using this mapping between the lattice and a local model we are able to obtain an intuitive expression for the non-local spin susceptibility, with the corresponding local correlation function as input. The latter is calculated by means of local Goldstone diagrams following closely the procedures developed and successfully applied for the (single impurity) Anderson model.We present a systematic study of the magnetic susceptibility and compare our results with those of a Hubbard model at large U. Similarities and differences are pointed out and the magnetic phase diagram of the t-J model is discussed.Comment: 28 pages LaTeX, postscript figures as compressed and uuencoded file included fil

Plaquette operators used in the rigorous study of ground-states of the Periodic Anderson Model in D=2D = 2 dimensions

The derivation procedure of exact ground-states for the periodic Anderson model (PAM) in restricted regions of the parameter space and D=2 dimensions using plaquette operators is presented in detail. Using this procedure, we are reporting for the first time exact ground-states for PAM in 2D and finite value of the interaction, whose presence do not require the next to nearest neighbor extension terms in the Hamiltonian. In order to do this, a completely new type of plaquette operator is introduced for PAM, based on which a new localized phase is deduced whose physical properties are analyzed in detail. The obtained results provide exact theoretical data which can be used for the understanding of system properties leading to metal-insulator transitions, strongly debated in recent publications in the frame of PAM. In the described case, the lost of the localization character is connected to the break-down of the long-range density-density correlations rather than Kondo physics.Comment: 34 pages, 5 figure

Ferromagnetism in the large-U Hubbard model

We study the Hubbard model on a hypercubic lattice with regard to the possibility of itinerant ferromagnetism. The Dynamical Mean Field theory is used to map the lattice model on an effective local problem, which is treated with help of the Non Crossing Approximation. By investigating spin dependent one-particle Green's functions and the magnetic susceptibility, a region with nonvanishing ferromagnetic polarization is found in the limit $U\to\infty$. The $\delta$-T-phase diagram as well as thermodynamic quantities are discussed. The dependence of the Curie temperature on the Coulomb interaction and the competition between ferromagnetism and antiferromagnetism are studied in the large $U$ limit of the Hubbard model.Comment: 4 pages, 5 figures, accepted for publication in Physical Review B, Rapid Communication