3 research outputs found
Complexation of Fullerenes by Subphthalocyanine Dimers
Tweezer-like
molecules comprised of two boron subphthalocyanine
(SubPc) units were prepared by Sonogashira couplings and investigated
using NMR spectroscopy for their ability to bind fullerenes (C60 and C70). The preorganization of the tweezers
provided association constants of ca. 103 M–1 in toluene-d8, while a SubPc monomer
did not show any association. Nevertheless, the SubPc monomer crystallized
with the fullerenes as 2:1 complexes, supporting the favorable tweezer-like
design for complexation, which was further corroborated by computations