Quantum interference with molecules: The role of internal states

Recent experiments have shown that fullerene and fluorofullerene molecules can produce interference patterns. These molecules have both rotational and vibrational degrees of freedom. This leads one to ask whether these internal motions can play a role in degrading the interference pattern. We study this by means of a simple model. Our molecule consists of two masses a fixed distance apart. It scatters from a potential with two or several peaks, thereby mimicking two or several slit interference. We find that in some parameter regimes the entanglement between the internal states and the translational degrees of freedom produced by the potential can decrease the visibility of the interference pattern. In particular, different internal states correspond to different outgoing wave vectors, so that if several internal states are excited, the total interference pattern will be the sum of a number of patterns, each with a different periodicity. The overall pattern is consequently smeared out. In the case of two different peaks, the scattering from the different peaks will excite different internal states so that the path the molecule takes become entangled with its internal state. This will also lead to degradation of the interference pattern. How these mechanisms might lead to the emergence of classical behavior is discussed.Comment: 12 pages, 4 eps figures, quality of figures reduced because of size restriction

A scalable optical detection scheme for matter wave interferometry

Imaging of surface adsorbed molecules is investigated as a novel detection method for matter wave interferometry with fluorescent particles. Mechanically magnified fluorescence imaging turns out to be an excellent tool for recording quantum interference patterns. It has a good sensitivity and yields patterns of high visibility. The spatial resolution of this technique is only determined by the Talbot gratings and can exceed the optical resolution limit by an order of magnitude. A unique advantage of this approach is its scalability: for certain classes of nano-sized objects, the detection sensitivity will even increase significantly with increasing size of the particle.Comment: 10 pages, 4 figure

Thermal limitation of far-field matter-wave interference

We assess the effect of the heat radiation emitted by mesoscopic particles on their ability to show interference in a double slit arrangement. The analysis is based on a stationary, phase-space based description of matter wave interference in the presence of momentum-exchange mediated decoherence.Comment: 8 pages, 2 figures; published versio

Integrated Atom Detector Based on Field Ionization near Carbon Nanotubes

We demonstrate an atom detector based on field ionization and subsequent ion counting. We make use of field enhancement near tips of carbon nanotubes to reach extreme electrostatic field values of up to 9x10^9 V/m, which ionize ground state rubidium atoms. The detector is based on a carpet of multiwall carbon nanotubes grown on a substrate and used for field ionization, and a channel electron multiplier used for ion counting. We measure the field enhancement at the tips of carbon nanotubes by field emission of electrons. We demonstrate the operation of the field ionization detector by counting atoms from a thermal beam of a rubidium dispenser source. By measuring the ionization rate of rubidium as a function of the applied detector voltage we identify the field ionization distance, which is below a few tens of nanometers in front of nanotube tips. We deduce from the experimental data that field ionization of rubidium near nanotube tips takes place on a time scale faster than 10^(-10)s. This property is particularly interesting for the development of fast atom detectors suitable for measuring correlations in ultracold quantum gases. We also describe an application of the detector as partial pressure gauge.Comment: 7 pages, 8 figure

Calibration of a single atom detector for atomic micro chips

We experimentally investigate a scheme for detecting single atoms magnetically trapped on an atom chip. The detector is based on the photoionization of atoms and the subsequent detection of the generated ions. We describe the characterization of the ion detector with emphasis on its calibration via the correlation of ions with simultaneously generated electrons. A detection efficiency of 47.8% (+-2.6%) is measured, which is useful for single atom detection, and close to the limit allowing atom counting with sub-Poissonian uncertainty

Colloquium: Quantum interference of clusters and molecules

We review recent progress and future prospects of matter wave interferometry with complex organic molecules and inorganic clusters. Three variants of a near-field interference effect, based on diffraction by material nanostructures, at optical phase gratings, and at ionizing laser fields are considered. We discuss the theoretical concepts underlying these experiments and the experimental challenges. This includes optimizing interferometer designs as well as understanding the role of decoherence. The high sensitivity of matter wave interference experiments to external perturbations is demonstrated to be useful for accurately measuring internal properties of delocalized nanoparticles. We conclude by investigating the prospects for probing the quantum superposition principle in the limit of high particle mass and complexity.Comment: 19 pages, 13 figures; v2: corresponds to published versio

Calix[4]arene based α-aminophosphonates: Novel carriers for Zwitterionic amino acids transport

A series of calix[4]arene based α-aminophosphonates were synthesized by the Kabachnik-Fields reaction of the calixarene-diamine (either at lower or upper rim), diethyl phosphite and a carbonyl compound (acetone or cyclohexanone). These compounds exhibited remarkable selectivity as carriers for the membrane transport of the zwitterionic form of aromatic amino acids