Structure/permeability relationships of silicon-containing polyimides

The permeability to H2, O2, N2, CO2 and CH4 of three silicone-polyimide random copolymers and two polyimides containing silicon atoms in their backbone chains, was determined at 35.0 C and at pressures up to about 120 psig (approximately 8.2 atm). The copolymers contained different amounts of BPADA-m-PDA and amine-terminated poly (dimethyl siloxane) and also had different numbers of siloxane linkages in their silicone component. The polyimides containing silicon atoms (silicon-modified polyimides) were SiDA-4,4'-ODA and SiDA-p-PDA. The gas permeability and selectivity of the copolymers are more similar to those of their silicone component than of the polyimide component. By contrast, the permeability and selectivity of the silicon-modified polyimides are more similar to those of their parent polyimides, PMDA-4,4'-ODA and SiDA-p-PDA. The substitution of SiDA for the PMDA moiety in a polyimide appears to result in a significant increase in gas permeability, without a correspondingly large decrease in selectivity. The potential usefulness of the above polymers and copolymers as gas separation membranes is discussed

Observations of fast anisotropic ion heating, ion cooling, and ion recycling in large-amplitude drift waves

Large-amplitude drift wave fluctuations are observed to cause severe ion temperature oscillations in plasmas of the Caltech Encore tokamak [J. M. McChesney, P. M. Bellan, and R. A. Stern, Phys. Fluids B 3, 3370 (1991)]. Experimental investigations of the complete ion dynamical behavior in these waves are presented. The wave electric field excites stochastic ion orbits in the plane normal (perpendicular to) to B, resulting in rapid perpendicular to heating. Ion-ion collisions impart energy along (parallel to) B, relaxing the perpendicular to-parallel to temperature anisotropy. Hot ions with large orbit radii escape confinement, reaching the chamber wall and cooling the distribution. Cold ions from the plasma edge convect back into the plasma (i.e., recycle), causing further cooling and significantly replenishing the density depleted by orbit losses. The ion-ion collision period tau(ii)similar to Tau(3/2)/n fluctuates strongly with the drift wave phase, due to intense (approximate to 50%) fluctuations in n and Tau. Evidence for particle recycling is given by observations of bimodal ion velocity distributions near the plasma edge, indicating the presence of cold ions (0.4 eV) superposed atop the hot (4-8 eV) plasma background. These appear periodically, synchronous with the drift wave phase at which ion fluid flow from the wall toward the plasma center peaks. Evidence is presented that such a periodic heat/loss/recycle/cool process is expected in plasmas with strong stochastic heating

Real-time phase-selective data acquisition system for measurement of wave phenomena in pulsed plasma discharges

A novel data acquisition system and methodology have been developed for the study of wave phenomena in pulsed plasma discharges. The method effectively reduces experimental uncertainty due to shot-to-shot fluctuations in high repetition rate experiments. Real-time analysis of each wave form allows classification of discharges by wave amplitude, phase, or other features. Measurements can then be constructed from subsets of discharges having similar wave properties. The method clarifies the trade-offs between experimental uncertainty reduction and increased demand for data storage capacity and acquisition time. Finally, this data acquisition system is simple to implement and requires relatively little equipment: only a wave form digitizer and a moderately fast computer

NMR evidence for a strong modulation of the Bose-Einstein Condensate in BaCuSi2_2O6_6

We present a $^{63,65}$Cu and $^{29}$Si NMR study of the quasi-2D coupled spin 1/2 dimer compound BaCuSi$_2$O$_6$ in the magnetic field range 13-26 T and at temperatures as low as 50 mK. NMR data in the gapped phase reveal that below 90 K different intra-dimer exchange couplings and different gaps ($\Delta_{\rm{B}}/\Delta_{\rm{A}}$ = 1.16) exist in every second plane along the c-axis, in addition to a planar incommensurate (IC) modulation. $^{29}$Si spectra in the field induced magnetic ordered phase reveal that close to the quantum critical point at $H_{\rm{c1}}$ = 23.35 T the average boson density $\bar{n}$ of the Bose-Einstein condensate is strongly modulated along the c-axis with a density ratio for every second plane $\bar{n}_{\rm{A}}/\bar{n}_{\rm{B}} \simeq 5$. An IC modulation of the local density is also present in each plane. This adds new constraints for the understanding of the 2D value $\phi$ = 1 of the critical exponent describing the phase boundary

IR Kuiper Belt Constraints

We compute the temperature and IR signal of particles of radius $a$ and albedo $\alpha$ at heliocentric distance $R$, taking into account the emissivity effect, and give an interpolating formula for the result. We compare with analyses of COBE DIRBE data by others (including recent detection of the cosmic IR background) for various values of heliocentric distance, $R$, particle radius, $a$, and particle albedo, $\alpha$. We then apply these results to a recently-developed picture of the Kuiper belt as a two-sector disk with a nearby, low-density sector (40<R<50-90 AU) and a more distant sector with a higher density. We consider the case in which passage through a molecular cloud essentially cleans the Solar System of dust. We apply a simple model of dust production by comet collisions and removal by the Poynting-Robertson effect to find limits on total and dust masses in the near and far sectors as a function of time since such a passage. Finally we compare Kuiper belt IR spectra for various parameter values.Comment: 34 pages, LaTeX, uses aasms4.sty, 11 PostScript figures not embedded. A number of substantive comments by a particularly thoughtful referee have been addresse

NICMOS Imaging of the Dusty Microjansky Radio Source VLA J123642+621331 at z = 4.424

We present the discovery of a radio galaxy at a likely redshift of z = 4.424 in one of the flanking fields of the Hubble Deep Field. Radio observations with the VLA and MERLIN centered on the HDF yielded a complete sample of microjansky radio sources, of which about 20% have no optical counterpart to I < 25 mag. In this Letter, we address the possible nature of one of these sources, through deep HST NICMOS images in the F110W (J) and F160W (H) filters. VLA J123642+621331 has a single emission line at 6595-A, which we identify with Lyman-alpha at z = 4.424. We argue that this faint (H = 23.9 mag), compact (r = 0.2 arcsec), red (I - K = 2.0) object is most likely a dusty, star-forming galaxy with an embedded active nucleus.Comment: Accepted for publication in Astrophysical Journal Letters. 11 pages, 4 figures, uses aastex v5.0 and psfi

The Discovery of Argon in Comet C/1995 O1 (Hale-Bopp)

On 30.14 March 1997 we observed the EUV spectrum of the bright comet C/1995 O1 (Hale-Bopp) at the time of its perihelion, using our EUVS sounding rocket telescope/spectrometer. The spectra reveal the presence H Ly beta, O+, and, most notably, Argon. Modelling of the retrieved Ar production rates indicates that comet Hale-Bopp is enriched in Ar relative to cosmogonic expectations. This in turn indicates that Hale-Bopp's deep interior has never been exposed to the 35-40 K temperatures necessary to deplete the comet's primordial argon supply.Comment: 9 pages, 2 figures. ApJ, 545, in press (2000

A Complexity-Brightness Correlation in Gamma Ray Bursts

We observe strong correlations between the temporal properties of gamma ray bursts (GRBs) and their apparent peak brightness. The strongest effect (with a significance level of 10^{-6}) is the difference between the brightness distributions of simple bursts (dominated by a single smooth pulse) and complex bursts (consisting of overlapping pulses). The latter has a break at a peak flux of 1.5 ph/cm^2/s, while the distribution of simple bursts is smooth down to the BATSE threshold. We also observe brightness dependent variations in the shape of the average peak aligned time profile (ATP) of GRBs. The decaying slope of the ATP shows time dilation when comparing bright and dim bursts while the rising slope hardly changes. Both slopes of the ATP are deformed for weak bursts as compared to strong bursts. The interpretation of these effects is simple: a complex burst where a number of independent pulses overlap in time appears intrinsically stronger than a simple burst. Then the BATSE sample of complex bursts covers larger redshifts where some cosmological factor causes the break in the peak brightness distribution. This break could correspond to the peak in the star formation rate that was recently shown to occur at a redshift of z~1.5.Comment: 13 pages; 11 figures; replaced with the published versio

Composite Fermions in Modulated Structures: Transport and Surface Acoustic Waves

Motivated by a recent experiment of Willett et al. [Phys. Rev. Lett. 78, 4478 (1997)], we employ semiclassical composite-fermion theory to study the effect of a periodic density modulation on a quantum Hall system near Landau level filling factor nu=1/2. We show that even a weak density modulation leads to dramatic changes in surface-acoustic-wave (SAW) propagation, and propose an explanation for several key features of the experimental observations. We predict that properly arranged dc transport measurements would show a structure similar to that seen in SAW measurements.Comment: Version published in Phys. Rev. Lett. Figures changed to show SAW velocity shift. LaTeX, 5 pages, two included postscript figure