1 research outputs found
Structure and Dynamics of Molecular Hydrogen in the Interlayer Pores of a Swelling 2:1 Clay by Neutron Scattering
Neutron
scattering has been used to reveal the structure and dynamics
of molecular H<sub>2</sub> physisorbed into the two-dimensional pores
of sparingly hydrated Ca-laponite clay. Thermal pretreatment of the
clay at 415 K under vacuum yielded an interlayer composition in the
1.0–1.5 water molecules per Ca<sup>2+</sup> cation range and
provided a vacant gallery height of 2.82 Ã…. This value is very
well matched to the diameter of molecular hydrogen and allows intercalation
of H<sub>2</sub> up to the point where a liquid-like monolayer is
formed within the clay. At a low coverage of 0.1 H<sub>2</sub> per
cation the isosteric heat of adsorption is 9.2 kJ mol<sup>–1</sup>. Quasielastic neutron scattering experiments conducted at 40–100
K reveal two populations of H<sub>2</sub> within the clay. First,
we find molecules that are localized close to the partially hydrated
Ca<sup>2+</sup> cations. Second, we identify a more mobile liquid-like
population whose motion is captured by jump diffusion. At 40 K, the
H<sub>2</sub> diffusion coefficient is 2.3 ± 0.5 × 10<sup>–5</sup> cm<sup>2</sup> s<sup>–1</sup>. This
is an order of magnitude slower than the value extrapolated from bulk
liquid H<sub>2</sub>