2 research outputs found
Magnetic anisotropy and superspin glass behaviour of Fe nanoparticles embedded in Cr and Ag matrices
Static and dynamical magnetic
properties of
Fe
nanoparticles
(NPs)
embedded
in non
-
magnetic
(Ag) and antiferromagnetic (Cr) matrices
with a volume filling fraction
(VFF)
of 10%
have been
investigated
. In both
Fe@Ag and Fe@Cr nanocomposites
, the Fe nanoparticles have a narrow size
distribution, with
a
mean particle diameter
around
2 nm. In both
samples
, the saturation
magnetization reaches that of
Fe
bulk bcc, suggesting
the absence
of
alloying
with the matrices.
The
coercivity
at 5 K
is
much larger in Fe@Cr
than in Fe@Ag
as a result of
the
strong interaction
between
the
Fe NPs and
the
Cr matrix. Temperature
-
dependent magnetization and ac
-
susceptibility
measurements
point out
further
evidence
of
the
enhanced
inter
-
particle interaction in
the
Fe@Cr
system
. While
the
behavior
of Fe@Ag
indicates the presence of weakly interacting magnetic
monodomain particles
with a wide distribution of
blocking temperatures
, Fe@Cr
behaves like a
superspin glass
produced
by the
magnetic
interaction
between
nanoparticles
Exchange Bias in Fe@Cr Core-Shell Nanoparticles
We have used X-ray magnetic circular dichroism and magnetometry to study isolated Fe@Cr core−shell nanoparticles with an Fe core diameter of 2.7 nm (850 atoms) and a Cr shell thickness varying between 1 and 2 monolayers. The addition of Cr shells significantly reduces the spin moment but does not change the orbital moment. At least two Cr atomic layers are required to stabilize a ferromagnetic/antiferromagnetic interface and generate the associated exchange bias and increase in coercivity