63 research outputs found
NMR Time Reversal Experiments in Highly Polarised Liquid 3He-4He Mixtures
Long-range magnetic interactions in highly magnetised liquids
(laser-polarised 3He-4He dilute mixtures at 1 K in our experiment) introduce a
significant non-linear and non-local contribution to the evolution of nuclear
magnetisation that leads to instabilities during free precession. We recently
demonstrated that a multi-echo NMR sequence, based on the magic sandwich pulse
scheme developed for solid-state NMR, can be used to stabilise the
magnetisation against the effect of distant dipolar fields. Here, we report
investigations of echo attenuation in an applied field gradient that show the
potential of this NMR sequence for spin diffusion measurements at high
magnetisation densities.Comment: Accepted for publication in the Journal of Low Temperature Physic
Molecular velocity auto-correlation of simple liquids observed by NMR MGSE method
The velocity auto-correlation spectra of simple liquids obtained by the NMR
method of modulated gradient spin echo show features in the low frequency range
up to a few kHz, which can be explained reasonably well by a long
time tail decay only for non-polar liquid toluene, while the spectra of polar
liquids, such as ethanol, water and glycerol, are more congruent with the model
of diffusion of particles temporarily trapped in potential wells created by
their neighbors. As the method provides the spectrum averaged over ensemble of
particle trajectories, the initial non-exponential decay of spin echoes is
attributed to a spatial heterogeneity of molecular motion in a bulk of liquid,
reflected in distribution of the echo decays for short trajectories. While at
longer time intervals, and thus with longer trajectories, heterogeneity is
averaged out, giving rise to a spectrum which is explained as a combination of
molecular self-diffusion and eddy diffusion within the vortexes of hydrodynamic
fluctuations.Comment: 8 pages, 6 figur
Diffusion measurements using oscillating gradients
A novel method for the measurement of self-diffusion coefficients employing oscillating gradients is presented. The method used has advantages over conventional techniques and will allow measurements to be made at very short diffusion times (<1ms) and should prove particularly useful for short T-2 materials
Measurement Tensors in Diffusion MRI: Generalizing the Concept of Diffusion Encoding
In traditional diffusion MRI, short pulsed field gradients (PFG) are used for the diffusion encoding. The standard Stejskal-Tanner sequence uses one single pair of such gradients, known as single-PFG (sPFG). In this work we describe how trajectories in q-space can be used for diffusion encoding. We discuss how such encoding enables the extension of the well-known scalar b-value to a tensor-valued entity we call the diffusion measurement tensor. The new measurements contain information about higher order diffusion propagator covariances not present in sPFG. As an example analysis, we use this new information to estimate a Gaussian distribution over diffusion tensors in each voxel, described by its mean (a diffusion tensor) and its covariance (a 4th order tensor)
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