Laser fluorescence studies of the chemical interactions of sodium species with sulfur bearing fuels

By using a large matrix of fuel rich and fuel lean H2/O2/N2 and fuel rich C2H2/O2/N2 flames, the behavior of sodium and its interactions with sulfur at high temperatures was extensively characterized. OH concentrations were measured for each flame using the previously validated laser induced fluorescence technique. Sodium atomic concentrations were obtained by the saturated laser fluorescence method. Measurements were made in the absence and presence of up to 2% sulfur. In oxygen rich systems sodium is depleted by NaO2 and NaOH formation. The relative amounts of each are controlled by the degree of nonequilibration of the flame radicals and by the temperature. The bond strength of NaO2 was established. For the first time, a complete understanding of the complex behavior of sodium in fuel lean H2/O2 flames has emerged and computer modeling has permitted various rate constants of Na, NaO2 and NaOH reactions to be approximately fixed

Extracting joint weak values with local, single-particle measurements

Weak measurement is a new technique which allows one to describe the evolution of postselected quantum systems. It appears to be useful for resolving a variety of thorny quantum paradoxes, particularly when used to study properties of pairs of particles. Unfortunately, such nonlocal or joint observables often prove difficult to measure weakly in practice (for instance, in optics -- a common testing ground for this technique -- strong photon-photon interactions would be needed). Here we derive a general, experimentally feasible, method for extracting these values from correlations between single-particle observables.Comment: 6 page

Nonlinear optics with less than one photon

We demonstrate suppression and enhancement of spontaneous parametric down- conversion via quantum interference with two weak fields from a local oscillator (LO). Pairs of LO photons are observed to upconvert with high efficiency for appropriate phase settings, exhibiting an effective nonlinearity enhanced by at least 10 orders of magnitude. This constitutes a two-photon switch, and promises to be useful for a variety of nonlinear optical effects at the quantum level.Comment: 8 pages, 5 figure

Phase Space Tomography of Classical and Nonclassical Vibrational States of Atoms in an Optical Lattice

Atoms trapped in optical lattice have long been a system of interest in the AMO community, and in recent years much study has been devoted to both short- and long-range coherence in this system, as well as to its possible applications to quantum information processing. Here we demonstrate for the first time complete determination of the quantum phase space distributions for an ensemble of $^{85}Rb$ atoms in such a lattice, including a negative Wigner function for atoms in an inverted state.Comment: Submitted to Journal of Optics B: Quantum and Semiclassical Optics. Special issue in connection with the 9th International Conference on Squeezed States and Uncertainty Relations, to be held in Besancon, France, on 2-6 May 200

Comment on "A linear optics implementation of weak values in Hardy's paradox"

A recent experimental proposal by Ahnert and Payne [S.E. Ahnert and M.C. Payne, Phys. Rev. A 70, 042102 (2004)] outlines a method to measure the weak value predictions of Aharonov in Hardy's paradox. This proposal contains flaws such as the state preparation method and the procedure for carrying out the requisite weak measurements. We identify previously published solutions to some of the flaws.Comment: To be published in Physical Review

Sub-femtosecond determination of transmission delay times for a dielectric mirror (photonic bandgap) as a function of angle of incidence

Using a two-photon interference technique, we measure the delay for single-photon wavepackets to be transmitted through a multilayer dielectric mirror, which functions as a ``photonic bandgap'' medium. By varying the angle of incidence, we are able to confirm the behavior predicted by the group delay (stationary phase approximation), including a variation of the delay time from superluminal to subluminal as the band edge is tuned towards to the wavelength of our photons. The agreement with theory is better than 0.5 femtoseconds (less than one quarter of an optical period) except at large angles of incidence. The source of the remaining discrepancy is not yet fully understood.Comment: 5 pages and 5 figure

Diagnosis, prescription and prognosis of a Bell-state filter by quantum process tomography

Using a Hong-Ou-Mandel interferometer, we apply the techniques of quantum process tomography to characterize errors and decoherence in a prototypical two-photon operation, a singlet-state filter. The quantum process tomography results indicate a large asymmetry in the process and also the required operation to correct for this asymmetry. Finally, we quantify errors and decoherence of the filtering operation after this modification.Comment: 4 pages, 4 figure