Revisiting waterlike network-forming lattice models

In a previous paper [J. Chem. Phys. 129, 024506 (2008)] we studied a 3 dimensional lattice model of a network-forming fluid, recently proposed in order to investigate water anomalies. Our semi-analytical calculation, based on a cluster-variation technique, turned out to reproduce almost quantitatively several Monte Carlo results and allowed us to clarify the structure of the phase diagram, including different kinds of orientationally ordered phases. Here, we extend the calculation to different parameter values and to other similar models, known in the literature. We observe that analogous ordered phases occur in all these models. Moreover, we show that certain "waterlike" thermodynamic anomalies, claimed by previous studies, are indeed artifacts of a homogeneity assumption made in the analytical treatment. We argue that such a difficulty is common to a whole class of lattice models for water, and suggest a possible way to overcome the problem.Comment: 13 pages, 12 figure

Cluster-variation approximation for a network-forming lattice-fluid model

We consider a 3-dimensional lattice model of a network-forming fluid, which has been recently investigated by Girardi and coworkers by means of Monte Carlo simulations [J. Chem. Phys. \textbf{126}, 064503 (2007)], with the aim of describing water anomalies. We develop an approximate semi-analytical calculation, based on a cluster-variation technique, which turns out to reproduce almost quantitatively different thermodynamic properties and phase transitions determined by the Monte Carlo method. Nevertheless, our calculation points out the existence of two different phases characterized by long-range orientational order, and of critical transitions between them and to a high-temperature orientationally-disordered phase. Also, the existence of such critical lines allows us to explain certain ``kinks'' in the isotherms and isobars determined by the Monte Carlo analysis. The picture of the phase diagram becomes much more complex and richer, though unfortunately less suitable to describe real water.Comment: 10 pages, 9 figures, submitted to J. Chem. Phy

Hydration of an apolar solute in a two-dimensional waterlike lattice fluid

In a previous work, we investigated a two-dimensional lattice-fluid model, displaying some waterlike thermodynamic anomalies. The model, defined on a triangular lattice, is now extended to aqueous solutions with apolar species. Water molecules are of the "Mercedes Benz" type, i.e., they possess a D3 (equilateral triangle) symmetry, with three equivalent bonding arms. Bond formation depends both on orientation and local density. The insertion of inert molecules displays typical signatures of hydrophobic hydration: large positive transfer free energy, large negative transfer entropy (at low temperature), strong temperature dependence of the transfer enthalpy and entropy, i.e., large (positive) transfer heat capacity. Model properties are derived by a generalized first order approximation on a triangle cluster.Comment: 9 pages, 5 figures, 1 table; submitted to Phys. Rev.

Perturbative power Q^2-corrections to the structure function g(1)

We prove that regulating infrared divergencies generates power (~1/(Q^2)^k) corrections to the spin structure function g_1 at small x and large Q^2. At the same time it leads to the corrections ~(Q^2)^k at small Q^2. We present the explicit series of such terms as well as the formulae for their resummation. These contributions are not included in the standard analysis of the experimental data. We argue that accounting for such terms can sizably change the impact of the other power corrections conventionally attributed to the higher twists.Comment: Theoretical grounds for our approach are considered in much more detailed way than in the previous version; 10 pages, 2 figure

The gluon content of the η\eta and η′\eta^{\prime} mesons and the ηγ\eta\gamma, η′γ\eta^{\prime}\gamma electromagnetic transition form factors

We compute power-suppressed corrections to the \eta\gamma and \eta^{\prime}\gamma transition form factors Q^2F_{\eta(\eta^{\prime})\gamma}(Q^2) arising from the end point regions x \to 0,1 by employing the infrared-renormalon approach. The contribution to the form factors from the quark and gluon content of the \eta,\eta^{\prime} mesons is taken into account using for the \eta-\eta^{\prime} mixing the SU_f(3) singlet \eta_1 and octet \eta_8 basis. The theoretical predictions obtained this way are compared with the corresponding CLEO data and restrictions on the input parameters (Gegenbauer coefficients) B_2^q(\eta_1), B_2^g(\eta_1), and B_2^q(\eta_8) in the distribution amplitudes for the \eta_1,\eta_8 states with one nonasymptotic term are deduced. Comparison is made with the results from QCD perturbation theory.Comment: 25 pages, RevTeX4 used. 9 figures as EPS files. Text significantly changed to include variation of theoretical parameters. Figures modified. Corrected typo in equation (34) and trivial mistake in $\beta_1$-coefficient. References added. Conclusions unchange

Effects of genetic and agronomic factors on grain composition in oats

The effects of genetic variability and agronomic practises on the chemical compounds of the grain were evaluated in a set of oat cultivars (16 naked and four husked) grown in different experiments in the years 2004–2008. In the first experiment, carried out for two years, β-glucan and Total Dietary Fibre (TDF) from eight oat cultivars, grown under three different levels of nitrogen fertilization and two seed doses, were considered. The second experiment, involving 12 cultivars for two years, explored the variation of β-glucan solubility and further characterized six cultivars for the content of TDF and arabinoxylans. In both experiments, genotype was found to exert the largest effect on the grain composition; nitrogen levels and seed doses had positive significant effects on protein and β-glucan contents, but did not affect fibre content. Among the naked cultivars, Irina, Abel, Luna, Hendon and Expression showed a good ability to accumulate the examined grain compounds. However, in general, the highest contents of protein and β-glucan were found in the groats of husked cultivars, suggesting that specific breeding programs are a crucial step to identify the suitable naked oat genotypes to produce foods of high nutritional value

Baryon wave function in large-Nc QCD: Universality, nonlinear evolution equation and asymptotic limit

The 1/Nc expansion is formulated for the baryon wave function in terms of a specially constructed generating functional. The leading order of this 1/Nc expansion is universal for all low-lying baryons [including the O(1/Nc) and O(Nc^0) excited resonances] and for baryon-meson scattering states. A nonlinear evolution equation of Hamilton-Jacobi type is derived for the generating functional describing the baryon distribution amplitude in the large-Nc limit. In the asymptotic regime this nonlinear equation is solved analytically. The anomalous dimensions of the leading-twist baryon operators diagonalizing the evolution are computed analytically up to the next-to-leading order of the 1/Nc expansion.Comment: 44 page

On the Nucleon Distribution Amplitude: The Heterotic Solution

We present a new nucleon distribution amplitude which amalgamates features of the Chernyak-Ogloblin-Zhitnitsky model with those of the Gari-Stefanis model. This "heterotic" solution provides the possibility to have asymptotically a small ratio \hbox{$\vert G_{M}^{n}\vert/G_{M}^{p}\le 0.1$}, while fulfilling most of the sum-rule requirements up to the third order. Using this nucleon distribution amplitude we calculate the electromagnetic and weak nucleon form factors, the transition form factor $\gamma p \Delta^{+}$ and the decay widths of the charmonium levels $^3S_{1}$, $^3P_{1}$, and $^3P_{2}$ into $p\bar p$. The agreement with the available data is remarkable in all cases.Comment: 15 pages, RUB-TPII-21/92 Preprin

Endpoint behavior of the pion distribution amplitude in QCD sum rules with nonlocal condensates

Starting from the QCD sum rules with nonlocal condensates for the pion distribution amplitude, we derive another sum rule for its derivative and its "integral" derivatives---defined in this work. We use this new sum rule to analyze the fine details of the pion distribution amplitude in the endpoint region $x\sim 0$. The results for endpoint-suppressed and flat-top (or flat-like) pion distribution amplitudes are compared with those we obtained with differential sum rules by employing two different models for the distribution of vacuum-quark virtualities. We determine the range of values of the derivatives of the pion distribution amplitude and show that endpoint-suppressed distribution amplitudes lie within this range, while those with endpoint enhancement---flat-type or CZ-like---yield values outside this range.Comment: 20 pages, 10 figures, 1 table, conclusions update