Laser-sub-cycle two-dimensional electron momentum mapping using orthogonal two-color fields

The two-dimensional sub-cycle-time to electron momentum mapping provided by orthogonal two-color laser fields is applied to photoelectron spectroscopy. Using neon as the example we gain experimental access to the dynamics of emitted electron wave packets in electron momenta spectra measured by coincidence momentum imaging. We demonstrate the opportunities provided by this time-to-momentum mapping by investigating the influence of the parent ion on the emitted electrons on laser-sub-cycle times. It is found that depending on their sub-cycle birth time the trajectories of photoelectrons are affected differently by the ion's Coulomb field

Role of proton dynamics in efficient photoionization of hydrocarbon molecules

We experimentally investigate the ionizationmechanism behind the formation of remarkably high charge states observed in the laser-pulse-induced fragmentation of different hydrocarbon molecules by Roither et al. [Phys. Rev. Lett. 106, 163001 (2011)], who suggested enhanced ionization occurring at multiple C-H bonds as the underlying ionization mechanism. Using multiparticle coincidence momentum imaging we measure the yield of multiply charged fragmenting ethylene and acetylene molecules at several intensities and pulse durations ranging from the few-cycle regime to 25 fs. We observe, at constant intensity, a strong increase of the proton energy with increasing laser pulse duration. It is shown that this is caused by a strong increase in the yield of highly charged parent molecular ions with pulse duration. Based on experimental evidence we explain this increase by the necessary population of precursor states in the parent ion that feature fast C-H stretch dynamics to the critical internuclear distance, where efficient ionization via enhanced ionization takes place. For increasing pulse duration these precursor ionic states are more efficiently populated, which leads in turn to a higher enhanced-ionization probability for longer pulses. Our work provides experimental evidence for the existence of a multiple-bond version of enhanced ionization in polyatomic molecule

Role of proton dynamics in efficient photoionization of hydrocarbon molecules

We experimentally investigate the ionizationmechanism behind the formation of remarkably high charge states observed in the laser-pulse-induced fragmentation of different hydrocarbon molecules by Roither et al. [Phys. Rev. Lett. 106, 163001 (2011)], who suggested enhanced ionization occurring at multiple C-H bonds as the underlying ionization mechanism. Using multiparticle coincidence momentum imaging we measure the yield of multiply charged fragmenting ethylene and acetylene molecules at several intensities and pulse durations ranging from the few-cycle regime to 25 fs. We observe, at constant intensity, a strong increase of the proton energy with increasing laser pulse duration. It is shown that this is caused by a strong increase in the yield of highly charged parent molecular ions with pulse duration. Based on experimental evidence we explain this increase by the necessary population of precursor states in the parent ion that feature fast C-H stretch dynamics to the critical internuclear distance, where efficient ionization via enhanced ionization takes place. For increasing pulse duration these precursor ionic states are more efficiently populated, which leads in turn to a higher enhanced-ionization probability for longer pulses. Our work provides experimental evidence for the existence of a multiple-bond version of enhanced ionization in polyatomic molecule

Spatial control of electronic wave packets with attosecond precision

Atomic single- and double- ionization using orthogonally polarized two-color laser fields was investigated via COLTRILMS technique. We prove that the electronic wave packets can be spatially controlled with attosecond precision.Peer reviewed: YesNRC publication: Ye

Attosecond probe of valence electron wavepackets by sub-cycle sculpted laser fields

We experimentally and theoretically demonstrate a self-referenced wave-function retrieval of a valence-electron wave packet during its creation by strong-field ionization with a sculpted laser field. Key is the control over interferences arising at different time scales. Our work shows that the measurement of subcycle electron wave-packet interference patterns can serve as a tool to retrieve the structure and dynamics of the valence-electron cloud in atoms on a sub-10-as time scale.Fil: Xie, Xinhua. Vienna University of Technology; AustriaFil: Roither, Stefan. Vienna University of Technology; AustriaFil: Kartashov, Daniil. Vienna University of Technology; AustriaFil: Persson, Emil. Vienna University of Technology; AustriaFil: Arbo, Diego. Consejo Nacional de Investigaciónes Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Astronomía y Física del Espacio. - Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Astronomía y Física del Espacio; Argentina. Vienna University of Technology; AustriaFil: Zhang, Li. Vienna University of Technology; AustriaFil: Gräfe, Stefanie. Vienna University of Technology; AustriaFil: Schöffler, Markus S.. Vienna University of Technology; AustriaFil: Burgdörfer, Joachim. Vienna University of Technology; AustriaFil: Baltuska, Andrius. Vienna University of Technology; AustriaFil: Kitzler, Markus. Vienna University of Technology; Austri