6 research outputs found
Full Polarization Control of Optical Planar Waveguides with Chiral Material
Circularly
polarized (CP) light is attracting growing interest in photonics,
however it is not possible to use regular planar waveguides for the
transmission of such CP light. While keeping the planar geometry,
we conceived devices where the chirality of the propagation medium
overcomes the planar symmetry. Thus, we report on the fabrication
of chirowaveguides arising from the stacking of three layers of a
new hybrid chiral organic modified silica (OrMoSil). A flexible strategy
allows the control of the two main parameters impacting the ellipticity
of the propagated waves. First, the high chirality of the transparent
material is based on cheap and easy to access binaphthyl precursors
simply shaped as films by dip-coating. Second, the refractive index
(RI) contrast between the layers is finely tuned by TriEthOxySilane
(TEOS) doping. The polarization of the two fundamental guided modes
is measured on 2 cm long waveguides. We demonstrated that the polarization
can be modulated from linear to nearly circular (80% ellipticity)
depending on the RI contrast and the core thickness. These unprecedented
achievements in the area of both optical materials and guided optics,
open the way to fully integrated photonic devices dealing with CP
light propagation
Efficient Dibenzo[<i>c</i>]acridine Helicene-like Synthesis and Resolution: Scaleup, Structural Control, and High Chiroptical Properties
Herein, we describe our recent expeditious synthesis of dibenzo[<i>c</i>]acridine helicene-like compounds on a large scale in pure enantiomeric form. This flexible synthesis allows for variation at several positions on the skeleton. Geometrical parameters related to these compounds have been obtained from monocrystal X-ray structure resolution. Additionally, chiroptical parameters have been recorded, highlighting the versatility of this family showing for example optical rotation at 589 nm varying between 135 and 150 deg g<sup>–1</sup>cm<sup>2</sup>
Efficient Dibenzo[<i>c</i>]acridine Helicene-like Synthesis and Resolution: Scaleup, Structural Control, and High Chiroptical Properties
Herein, we describe our recent expeditious synthesis of dibenzo[<i>c</i>]acridine helicene-like compounds on a large scale in pure enantiomeric form. This flexible synthesis allows for variation at several positions on the skeleton. Geometrical parameters related to these compounds have been obtained from monocrystal X-ray structure resolution. Additionally, chiroptical parameters have been recorded, highlighting the versatility of this family showing for example optical rotation at 589 nm varying between 135 and 150 deg g<sup>–1</sup>cm<sup>2</sup>
Efficient Dibenzo[<i>c</i>]acridine Helicene-like Synthesis and Resolution: Scaleup, Structural Control, and High Chiroptical Properties
Herein, we describe our recent expeditious synthesis of dibenzo[<i>c</i>]acridine helicene-like compounds on a large scale in pure enantiomeric form. This flexible synthesis allows for variation at several positions on the skeleton. Geometrical parameters related to these compounds have been obtained from monocrystal X-ray structure resolution. Additionally, chiroptical parameters have been recorded, highlighting the versatility of this family showing for example optical rotation at 589 nm varying between 135 and 150 deg g<sup>–1</sup>cm<sup>2</sup>
Efficient Dibenzo[<i>c</i>]acridine Helicene-like Synthesis and Resolution: Scaleup, Structural Control, and High Chiroptical Properties
Herein, we describe our recent expeditious synthesis of dibenzo[<i>c</i>]acridine helicene-like compounds on a large scale in pure enantiomeric form. This flexible synthesis allows for variation at several positions on the skeleton. Geometrical parameters related to these compounds have been obtained from monocrystal X-ray structure resolution. Additionally, chiroptical parameters have been recorded, highlighting the versatility of this family showing for example optical rotation at 589 nm varying between 135 and 150 deg g<sup>–1</sup>cm<sup>2</sup>
Efficient Dibenzo[<i>c</i>]acridine Helicene-like Synthesis and Resolution: Scaleup, Structural Control, and High Chiroptical Properties
Herein, we describe our recent expeditious synthesis of dibenzo[<i>c</i>]acridine helicene-like compounds on a large scale in pure enantiomeric form. This flexible synthesis allows for variation at several positions on the skeleton. Geometrical parameters related to these compounds have been obtained from monocrystal X-ray structure resolution. Additionally, chiroptical parameters have been recorded, highlighting the versatility of this family showing for example optical rotation at 589 nm varying between 135 and 150 deg g<sup>–1</sup>cm<sup>2</sup>