2 research outputs found
Isochoric thermal conductivity of solid nitrogen
The isochoric thermal conductivity of solid nitrogen has been investigated on
four samples of different densities in the temperature interval from 20 K to
the onset of melting. In alfa-N2 the isochoric thermal conductivity exhibits a
dependence weaker than 1/T; in beta-N2 it increases slightly with temperature.
The experimental results are discussed within a model in which the heat is
transported by low-frequency phonons or by "diffusive" modes above the mobility
boundary. The growth of the thermal conductivity in beta-N2 is attributed to
the decreasing "rotational" component of the total thermal resistance, which
occurs as the rotational correlations between the neighboring molecules become
weaker.Comment: Postscript 12 pages, 3 figures, 1 table. To be published in 200