140 research outputs found
Screening by symmetry of long-range hydrodynamic interactions of polymers confined in sheets
Hydrodynamic forces may significantly affect the motion of polymers. In
sheet-like cavities, such as the cell's cytoplasm and microfluidic channels,
the hydrodynamic forces are long-range. It is therefore expected that that
hydrodynamic interactions will dominate the motion of polymers in sheets and
will be manifested by Zimm-like scaling. Quite the opposite, we note here that
although the hydrodynamic forces are long-range their overall effect on the
motion of polymers vanishes due to the symmetry of the two-dimensional flow. As
a result, the predicted scaling of experimental observables such as the
diffusion coefficient or the rotational diffusion time is Rouse-like, in accord
with recent experiments. The effective screening validates the use of the
non-interacting blobs picture for polymers confined in a sheet.Comment: http://www.weizmann.ac.il/complex/tlusty/papers/Macromolecules2006.pdf
http://pubs.acs.org/doi/abs/10.1021/ma060251
Direct Carbocyclization of Aldehydes with Alkynes: Combining Gold Catalysis with Aminocatalysis
Leveraging the Pre-DFG Residue Thr-406 To Obtain High Kinase Selectivity in an Aminopyrazole-Type PAK1 Inhibitor Series
Cyclization of Nonterminal Alkynic ÎČ-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand
Two allelic genes responsible for vegetative incompatibility in the fungus Podospora anserina are not essential for cell viability
Intramolecular Cyclization of Alkynyl α-Ketoanilide Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Phosphazene Base
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