Clay mineralogy and provenance modeling of the Paleoproterozoic Kaladgi shales, Dharwar Craton, Southern India: Implications on paleoweathering and source rock compositions

Proterozoic clastic sediments reveal vast information regarding provenance, depositional conditions, and environmental evolutions. Peninsular India comprising Archean cratons, also have numerous intracratonic Proterozoic sedimentary basins along their margins. The Archean Dharwar Craton in southern India has many Proterozoic successions, namely Cuddapah, Kurnool towards the East, and Kaladgi, Badami, and Bhima towards the northern margin. The Paleoproterozoic Kaladgi Basin (∼1.85 Ga) consists of siliciclastic sedimentary rocks with stromatolitic carbonate formations. XRD analysis of shale layers of the Lower Lokapur and Upper Simikere subgroups have been carried out to understand the primary clay mineral assemblages, weathering history, and provenance. The Lower and Upper shale layers of Lokapur and Simikere subgroups show a dominance of montmorillonite and kaolinite, respectively. The geochemical affinities and the clay mineral assemblages indicate a more mafic source to the lower shales (Manoli and Hebbal formations) and increased felsic contribution to the upper shales (Govindakoppa and Daddanhatti formations). Illite is ubiquitous in all the shales of the Kaladgi Supergroup possibly representing the diagenetic transformation of montmorillonite and kaolinite to illite. Geochemical modeling of provenance has been carried out using (Eu/Eu*)N, (La/Yb)N, (Gd/Yb)N, and (La/Sm)N of all the plausible source rocks and the average compositions of lower and upper shales. The modeling results suggest that the lower shales are derived from a source of mafic rocks – 45 %, K-rich granite – 35 %, and TTG – 20 %. While the upper shales are derived from source characterized by K-rich granites – 61 % and intermediate volcanic rocks – 39 %. These results signify the classical unroofing of TTG-greenstone belts exposing K-rich granites with the progression of sedimentation. Further, a good correlation between K-enrichment (a measure of % difference between CIA and pre-metasomatic CIA) and ƩLREE is attributed to the abundance of kaolinites that fractionate more LREE

A new cache of Eoarchaean detrital zircons from the Singhbhum craton, eastern India and constraints on early Earth geodynamics

The dominant geodynamic processes that underpin the formation and evolution of Earth's early crust remain enigmatic calling for new information from less studied ancient cratonic nuclei. Here, we present U–Pb ages and Hf isotopic compositions of detrital zircon grains from ∼2.9 Ga old quartzites and magmatic zircon from a 3.505 Ga old dacite from the Iron Ore Group of the Singhbhum craton, eastern India. The detrital zircon grains range in age between 3.95 Ga and 2.91 Ga. Together with the recently reported Hadean, Eoarchean xenocrystic (up to 4.24 Ga) and modern detritus zircon grains from the Singhbhum craton, our results suggest that the Eoarchean detrital zircons represent crust generated by recycling of Hadean felsic crust formed at ∼4.3–4.2 Ga and ∼3.95 Ga. We observe a prominent shift in Hf isotope compositions at ∼3.6–3.5 Ga towards super-chondritic values, which signify an increased role for depleted mantle and the relevance of plate tectonics. The Paleo-, Mesoarchean zircon Hf isotopic record in the craton indicates crust generation involving the role of both depleted and enriched mantle sources. We infer a short-lived suprasubduction setting around ∼3.6–3.5 Ga followed by mantle plume activity during the Paleo-, Mesoarchean crust formation in the Singhbhum craton. The Singhbhum craton provides an additional repository for Earth's oldest materials.Financial support from the Ministry of Earth Sciences, New Delhi for Excimer 193 nm LA system at CSIR-NGRI MoES/P.O.(Seismo)/1(245)/2014 and for the project on Singhbhum craton to S. D., E. V. S. S. K. B., B. S. and T. V. K (No. MoES/ P.O.(Geosci)45/2015; GAP-738-28EVB). This work forms part of the CSIR-NGRI projects INDEX (PSC0204) and GEOMET. Support from Australian Scientific Instruments and Geoscience Australia in providing access to the SHRIMP IIe, and The ANU for SEM imaging, is acknowledged. Y. J. B. thanks the DAE-Raja Ramanna Fellowship

Claypool continued: Extending the isotopic record of sedimentary sulfate

© 2019 Elsevier B.V. The Proterozoic Eon spans Earth\u27s middle age during which many important transitions occurred. These transitions include the oxygenation of the atmosphere, emergence of eukaryotic organisms and growth of continents. Since the sulfur and oxygen cycles are intricately linked to most surface biogeochemical processes, these transitions should be recorded in changes to the isotopic composition of marine and terrestrial sulfate minerals. Here we present oxygen (∆ 17 O, δ 18 O) and sulfur (∆ 33 S, δ 34 S) isotope records of Proterozoic sulfate from currently available data together with new measurements of 313 samples from 33 different formations bearing Earth\u27s earliest unambiguous evaporites at 2.4 Ga through to Ediacaran aged deposits. This record depicts distinct intervals with respect to the expression of sulfate isotopes that are not completely captured by established intervals in the geologic timescale. The most salient pattern is the muted ∆ 17 O signatures across the GOE, late Proterozoic and Ediacaran with values that are only slightly more negative than modern marine sulfate, contrasting with highly negative values across the mid-Proterozoic and Cryogenian. We combine these results with estimates of atmospheric composition to produce a gross primary production (GPP) curve for the Proterozoic. Through these results we argue that changes in GPP across Earth history likely help account for many of the changes in the Proterozoic Earth surface environment such as rising atmospheric oxygen, large fluctuations in the size of the marine sulfate reservoir and variations in the isotopic composition of sedimentary sulfate