229 research outputs found
Re-appearance of antiferromagnetic ordering with Zn and Ni substitution in La_{2-x}Sr_xCuO_4
The effects of nonmagnetic Zn and magnetic Ni substitution for Cu site on
magnetism are studied by measurements of uniform magnetic susceptibility for
lightly doped La_{2-x}Sr_xCu_{1-z}M_zO_4 (M=Zn or Ni) polycrystalline samples.
For the parent x=0, Zn doping suppresses the N\'{e}el temperature T_N whereas
Ni doping hardly changes T_N up to z=0.3. For the lightly doped samples with
T_N~0, the Ni doping recovers T_N. For the superconducting samples, the Ni
doping induces the superconductivity-to-antiferromagnetic transition (or
crossover). All the heavily Ni doped samples indicate a spin glass behavior at
\~15 K.Comment: 2 pages including 3 figures, to be published in Physica C (LT23,
Hiroshima 2002
VOLTAMMETRIC DETERMINATION OF DESLORATADINE IN PHARMACEUTICAL AND HUMAN URINE SAMPLES USING GLASSY CARBON ELECTRODE
Objective: The electrochemical behaviour of Desloratadine (DLTD) in pharmaceutical and human urine samples at glassy carbon electrode was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV).
Methods: A well defined reduction peak was observed at potential -1.55V in phosphate buffer solution (PBS) in basic medium. The reduction process was observed to be irreversible over the pH range from pH 2.0 to pH 10.0. The influence of different parameters such as the effect of pH, scan rate and concentration of the drug was studied. The probable reaction mechanism involved in the reduction of DLTD was also proposed. A SWV method with good recovery and accuracy was obtained for the determination of DLTD in pharmaceutical formulations and urine samples.
Results: The peak currents were found to be linearly dependent on the concentration range of 2.55x10-5to 1.5x10-3M of DLTD. The limit of detection (LOD) and limit of quantification (LOQ) were found to be 2.75x 10-9M, 3.20x 10-7 M respectively.
Conclusion: The proposed method was successfully applied for determination of DLTD in pharmaceutical and human urine samples
A modified sensitive palladium-copper oxide and multiwalled carbon nanotubes electrochemical sensor for detection of ametridione pesticide
Glassy carbon electrode modified sensitive Pd-CuO/MWCNTs electrochemical nanosensor was used for detection of ametridione pesticide in water samples. The morphology characteristics of Pd-CuO/MWCNTs are examined by scanning electron microscopy and EDX. The ametridione pesticide under voltammetric investigation involves irreversible, 4e? electron reduction based on the protonation of the two carbonyl groups (>C=O). The voltammetric method was applied for the detection of ametridione in BR buffer solution at pH 5.0 as a supporting electrolyte. The detection limit, limit of quantification and concentration ranges of the proposed method were 0.0796 ?g?mL?1 (signal/noise=3), 0.5560 ?g?mL?1 and 0.1 to 10.0 ?g?mL?1, respectively. The electrochemical sensor was successfully applied for the detection of ametridione in tap, agricultural run-off and river water samples showing >98% mean recoveries.
 
Anomalous Spin Dynamics observed by High Frequency ESR in Honeycomb Lattice Antiferromagnet InCu2/3V1/3O3
High-frequency ESR results on the S=1/2 Heisenberg hexagonal antiferromagnet
InCu2/3V1/3O3 are reported. This compound appears to be a rare model substance
for the honeycomb lattice antiferromagnet with very weak interlayer couplings.
The high-temperature magnetic susceptibility can be interpreted by the S=1/2
honeycomb lattice antiferromagnet, and it shows a magnetic-order-like anomaly
at TN=38 K. Although, the resonance field of our high-frequency ESR shows the
typical behavior of the antiferromagnetic resonance, the linewidth of our
high-frequency ESR continues to increase below TN, while it tends to decrease
as the temperature in a conventional three-dimensional antiferromagnet
decreases. In general, a honeycomb lattice antiferromagnet is expected to show
a simple antiferromagnetic order similar to that of a square lattice
antiferromagnet theoretically because both antiferromagnets are bipartite
lattices. However, we suggest that the observed anomalous spin dynamics below
TN is the peculiar feature of the honeycomb lattice antiferromagnet that is not
observed in the square lattice antiferromagnet.Comment: 5 pages, 5 figure
Oscillatory Exchange Coupling and Positive Magnetoresistance in Epitaxial Oxide Heterostructures
Oscillations in the exchange coupling between ferromagnetic
layers with paramagnetic spacer layer
thickness has been observed in epitaxial heterostructures of the two oxides.
This behavior is explained within the RKKY model employing an {\it ab initio}
calculated band structure of , taking into account strong electron
scattering in the spacer. Antiferromagnetically coupled superlattices exhibit a
positive current-in-plane magnetoresistance.Comment: 4 pages (RevTeX), 5 figures (EPS
Absence of strong magnetic fluctuations or interactions in the normal state of LaNiGa
We present nuclear magnetic (NMR) and qudrupole (NQR) resonance and
magnetization data in the normal state of the topological crystalline
superconductor LaNiGa. We find no evidence of magnetic fluctuations or
enhanced paramagnetism. These results suggest that the time-reversal symmetry
breaking previously reported in the superconducting state of this material is
not driven by strong electron correlations.Comment: 9 pages, 7 figure
Optical properties of an effective one-band Hubbard model for the cuprates
We study the Cu and O spectral density of states and the optical conductivity
of CuO_2 planes using an effective generalized one-band Hubbard model derived
from the extended three-band Hubbard model. We solve exactly a square cluster
of 10 unit cells and average the results over all possible boundary conditions,
what leads to smooth functions of frequency. Upon doping, the Fermi energy
jumps to Zhang-Rice states which are connected to the rest of the valence band
(in contrast to an isolated new band in the middle of the gap). The transfer of
spectral weight depends on the parameters of the original three-band model not
only through the one-band effective parameters but also through the relevant
matrix elements. We discuss the evolution of the gap upon doping. The optical
conductivity of the doped system shows a mid-infrared peak due to intraband
transitions, a pseudogap and a high frequency part related to interband
transitions. Its shape and integrated weight up to a given frequency (including
the Drude weight) agree qualitatively with experiments in the cuprates for low
to moderate doping levels, but significant deviations exist for doping .Comment: 11 pages (tex), 14 figures (ps
Nanostructured AgBr loaded TiO2: An efficient sunlight active photocatalyst for degradation of Reactive Red 120
The AgBr loaded TiO2 catalyst was prepared by a feasible approach with AgBr and tetraisopropyl orthotitanate and characterized by BET surface area measurement, diffuse reflectance spectra (DRS), scanning electron microscope (SEM), energy dispersive spectra (EDS), X-ray diffraction (XRD), transmission electron microscope (TEM) and atomic force microscope (AFM) analysis. The results of characterization reveal that AgBr loaded TiO2 has a nanostructure. Formation of the nanostructure in AgBr loaded TiO2 results in substantial shifting of the absorption edge of TiO2 to red and enhancement of visible light absorption. Electrochemical impedance spectroscopy measurements reveal that AgBr loaded TiO2 has a higher photoconductivity than prepared TiO2 due to higher separation efficiency of electron-hole pairs. Cyclic voltammetric studies reveal enhanced conductivity in AgBr loaded TiO2, which causes an increase in its photocatalytic activity. AgBr loaded TiO2 exhibited a higher photocatalytic activity than TiO2-P25 and prepared TiO2 in the photodegradation of Reactive Red 120 (RR 120)
Magnetic properties of the extended periodic Anderson model
We study magnetic properties of the extended periodic Anderson model, which
includes electron correlations within and between itinerant and localized
bands. By combining dynamical mean-field theory with the numerical
renormalization group we calculate the sublattice magnetization and the
staggered susceptibility to determine the phase diagram in the particle-hole
symmetric case. We find that two kinds of magnetically ordered states compete
with the Kondo insulating state at zero temperature, which induces
non-monotonic behavior in the temperature-dependent magnetization. It is
furthermore clarified that a novel magnetic metallic state is stabilized at
half filling by the competition between Hund's coupling and the hybridization.Comment: 4 pages, 4 figures, accepted for publication in JPS
Heat shock proteins in stabilization of spontaneously restored sinus rhythm in permanent atrial fibrillation patients after mitral valve surgery
A spontaneously restored sinus rhythm in permanent atrial fibrillation patients has been often observed after mitral valve (MV) surgery, but persisting duration in sinus rhythm varies from patient to patient. Heat shock proteins (Hsps) may be involved in pathogenesis of atrial fibrillation. We hypothesized that stabilization of restored sinus rhythm is associated with expression of Hsps in the atria. To test this hypothesis, clinical data, biopsies of right atrial appendage, and blood samples were collected from 135 atrial fibrillation patients who spontaneously restored sinus rhythm after conventional isolated MV replacement. Comparison was made between patients who had recurrence of atrial fibrillation within 7 days (AF) vs. patients with persisted sinus rhythm for more than 7 days (SR). Results showed that SR patients had higher activity of heat shock transcription factor 1 (HSF1) as well as upregulated expressions of heat shock cognate 70, Hsp70, and Hsp27 in the tissues. The activation of HSF1–Hsps pathway was associated with less-aggressive pathogenesis as reflected by lower rates of myolysis, apoptosis, interstitial fibrosis, and inflammation in SR patients. However, Hsp60 was lower in both tissue and plasma in SR patients, and was positively correlated with apoptosis, interstitial fibrosis, and inflammation. These findings suggest that the Hsps play important roles in stabilization of restored sinus rhythm after MV surgery by inhibiting AF-related atrial remodeling and arrhythmogenic substrates in atrial fibrillation patients. Low circulating Hsp60 levels preoperatively might predict a stable spontaneously restored sinus rhythm postoperatively
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