A new genus of Rhinotragini for \u3ci\u3eMolorchus laticornis\u3c/i\u3e Klug, 1825 (Coleoptera, Cerambycidae)

Klugiatragus gen. nov. is described for Epimelitta laticornis (Klug, 1825) because this species has closed procoxal cavities, a crucial diagnostic incompatible with Epimelitta Bates, 1870, which has open procoxal cavities. Both sexes of this species are illustrated

A new genus of Rhinotragini for \u3ci\u3eMolorchus laticornis\u3c/i\u3e Klug, 1825 (Coleoptera, Cerambycidae)

Klugiatragus gen. nov. is described for Epimelitta laticornis (Klug, 1825) because this species has closed procoxal cavities, a crucial diagnostic incompatible with Epimelitta Bates, 1870, which has open procoxal cavities. Both sexes of this species are illustrated

Y₂Ti₂O₅S₂ – a promising n-type oxysulphide for thermoelectric applications

Thermoelectric materials offer an unambiguous solution to the ever-increasing global demand for energy by harnessing the Seebeck effect to convert waste heat to electrical energy. Mixed-anion materials are ideal candidate thermoelectric materials due to their thermal stability and potential for “phonon-glass, electron-crystal” behaviour. In this study, we use density-functional theory (DFT) calculations to investigate Y2Ti2O5S2, a cation-deficient Ruddlesden-Popper system, as a potential thermoelectric. We use hybrid DFT to calculate the electronic structure and band alignment, which indicate a preference for n-type doping with highly anisotropic in-plane and the out-of-plane charge-carrier mobilities as a result of the anisotropy in the crystal structure. We compute phonon spectra and calculate the lattice thermal conductivity within the single-mode relaxation-time approximation using lifetimes obtained by considering three-phonon interactions. We also calculate the transport properties using the momentum relaxation-time approximation to solve the electronic Boltzmann transport equations. The predicted transport properties and lattice thermal conductivity suggest a maximum in-plane ZT of 1.18 at 1000 K with a carrier concentration of 2.37 × 1020 cm−3. Finally, we discuss further the origins of the low lattice thermal conductivity, in particular exploring the possibility of nanostructuring to lower the phonon mean free path, reduce the thermal conductivity, and further enhance the ZT. Given the experimentally-evidenced high thermal stability and the favourable band alignment found in this work, Y2Ti2O5S2 has the potential to be a promising high-temperature n-type thermoelectric

Sr2Sb2O7: a novel earth abundant oxide thermoelectric

Here we calculate the thermoelectric properties of Sr2Sb2O7 with high-level theory including hybrid DFT and MRTA electronic scattering calculations. We obtain a maximum ZT of 0.71, in excess of other state-of-the-art oxide thermoelectrics

Band Degeneracy and Anisotropy Enhances Thermoelectric Performance from Sb2Si2Te6 to Sc2Si2Te6

The complex interrelationships among thermoelectric parameters mean that a priori design of high-performing materials is difficult. However, band engineering can allow the power factor to be optimized through enhancement of the Seebeck coefficient. Herein, using layered Sb2Si2Te6 and Sc2Si2Te6 as model systems, we comprehensively investigate and compare their thermoelectric properties by employing density functional theory combined with semiclassical Boltzmann transport theory. Our simulations reveal that Sb2Si2Te6 exhibits superior electrical conductivity compared to Sc2Si2Te6 due to lower scattering rates and more pronounced band dispersion. Remarkably, despite Sb2Si2Te6 exhibiting a lower lattice thermal conductivity and superior electrical conductivity, Sc2Si2Te6 is predicted to achieve an extraordinary dimensionless figure of merit (ZT) of 3.51 at 1000 K, which significantly surpasses the predicted maximum ZT of 2.76 for Sb2Si2Te6 at 900 K. We find the origin of this behavior to be a combined increase in band (valley) degeneracy and anisotropy upon switching the conduction band orbital character from Sb p to Sc d, yielding a significantly improved Seebeck coefficient. This work suggests that enhancing band degeneracy and anisotropy (complexity) through compositional variation is an effective strategy for improving the thermoelectric performance of layered materials.</p

Increased intraventricular velocities An unrecognized cause of systolic murmur in adults

AbstractObjectives. The purpose of this study was to determine the frequency, clinical features and echocardiographic characteristics of increased intraventricular velocities (IIVs) in patients referred to the echocardiography laboratory for systolic murmur.Background. A subset of patients referred to the echocardiography laboratory for evaluation of a systolic murmur have IIVs in the absence of other recognized causes of systolic murmur.Methods. We prospectively studied echocardiograms from 108 consecutive patients referred for evaluation of a systolic murmur. Clinical data were obtained from patient examinations and medical records.Results. The sole explanation for systolic murmur was IIVs in 16.7% of referred patients. Compared with those without IIVs, patients with IIVs had a higher ejection fraction (EF) (58.7 ± 7.8% vs. 51.1 ± 12.5%, p < 0.001), percent fractional shortening (42.3 ± 9.7% vs. 31.0 ± 11.4%, p < 0.0001), left ventricular (LV) mass index (181 ± 70 vs. 152 ± 48 g/m2, p = 0.046) and prevalence of hypertension (73.3% vs. 51.7%, p = 0.043) and a lower prevalence of segmental wall motion abnormalities (2.2% vs. 39.3%, p < 0.001).Conclusions. Increased intraventricular velocities are a common cause of systolic murmur in this group of patients and should be included in the differential diagnosis of systolic murmurs in adults. The association of IIVs with LV hypertrophy should be a clinical consideration when these murmurs are identified

Perfect Zero-Knowledge PCPs for #P

We construct perfect zero-knowledge probabilistically checkable proofs (PZK-PCPs) for every language in #P. This is the first construction of a PZK-PCP for any language outside BPP. Furthermore, unlike previous constructions of (statistical) zero-knowledge PCPs, our construction simultaneously achieves non-adaptivity and zero knowledge against arbitrary (adaptive) polynomial-time malicious verifiers. Our construction consists of a novel masked sumcheck PCP, which uses the combinatorial nullstellensatz to obtain antisymmetric structure within the hypercube and randomness outside of it. To prove zero knowledge, we introduce the notion of locally simulatable encodings: randomised encodings in which every local view of the encoding can be efficiently sampled given a local view of the message. We show that the code arising from the sumcheck protocol (the Reed--Muller code augmented with subcube sums) admits a locally simulatable encoding. This reduces the algebraic problem of simulating our masked sumcheck to a combinatorial property of antisymmetric functions