8 research outputs found
Femtosecond Laser LiftâOff with SubâBand Gap Excitation for Production of FreeâStanding GaN LED Chips
Laser liftâoff (LLO) is commonly applied to separate functional thin films from the underlying substrate, in particular lightâemitting diodes (LEDs) on a gallium nitride (GaN) basis from sapphire. By transferring the LED layer stack to foreign carriers with tailored characteristics, for example, highly reflective surfaces, the performance of optoelectronic devices can be drastically improved. Conventionally, LLO is conducted with UV laser pulses in the nanosecond regime. When directed to the sapphire side of the wafer, absorption of the pulses in the first GaN layers at the sapphire/GaN interface leads to detachment. In this work, a novel approach towards LLO based on femtosecond pulses at 520ânm wavelength is demonstrated for the first time. Despite relying on twoâphoton absorption with subâbandgap excitation, the ultrashort pulse widths may reduce structural damage in comparison to conventional LLO. Based on a detailed study of the laser impact as a function of process parameters, a twoâstep process scheme is developed to create freestanding InGaN/GaN LED chips with up to 1.2âmm edge length and â5âÎŒm thickness. The detached chips are assessed by scanning electron microscopy and cathodoluminescence, revealing similar emission properties before and after LLO
Plasma Profiling Time-of-Flight Mass Spectrometry for Fast Elemental Analysis of Semiconductor Structures with Depth Resolution in the Nanometer Range
Plasma profiling time of flight mass spectrometry (PP-TOFMS) has recently
gained interest, as it enables the elemental profiling of semiconductor
structures with high depth resolution in short acquisition times. As recently
shown by Tempez et al., PP-TOFMS can be used to obtain the composition in the
structures for modern field effect transistors [1]. There, the results were
compared to conventional SIMS measurements. In the present study, we compare
PP-TOFMS measurements of an Al-/In-/GaN quantum well multi stack to established
micro- and nano-analysis techniques like cathodoluminescence (CL), scanning
transmission electron microscopy (STEM), energy dispersive X-ray spectroscopy
(EDX) and X-ray diffraction (XRD). We show that PP-TOFMS is able to resolve the
layer structure of the sample even more than 500 nm deep into the sample and
allows the determination of a relative elemental composition with an accuracy
of about 10 rel. %. Therefore, it is an extremely rapid alternative method to
obtain semiconductor elemental depth profiles without expensive and time
consuming sample preparation as it is needed for TEM. Besides, PP-TOFMS offers
better depth resolution and more elemental information than for example
electrochemical capacitance-voltage (ECV), as the acquisition of all elements
occurs in parallel and not only electrically (ECV) or optically (CL) active
elements are observed
Size-Dependent Electroluminescence and Current-Voltage Measurements of Blue InGaN/GaN ”LEDs down to the Submicron Scale
Besides high-power light-emitting diodes (LEDs) with dimensions in the range of mm, micro-LEDs (ÎŒLEDs) are increasingly gaining interest today, motivated by the future applications of ÎŒLEDs in augmented reality displays or for nanometrology and sensor technology. A key aspect of this miniaturization is the influence of the structure size on the electrical and optical properties of ÎŒLEDs. Thus, in this article, investigations of the size dependence of the electro-optical properties of ÎŒLEDs, with diameters in the range of 20 to 0.65 ÎŒm, by current-voltage and electroluminescence measurements are described. The measurements indicated that with decreasing size leakage currents in the forward direction decrease. To take advantage of these benefits, the surface has to be treated properly, as otherwise sidewall damages induced by dry etching will impair the optical properties. A possible countermeasure is surface treatment with a potassium hydroxide based solution that can reduce such defects
Size-Dependent Electroluminescence and Current-Voltage Measurements of Blue InGaN/GaN micro-LEDs Down to the Submicron Scale
Besides high-power light-emitting diodes with dimensions in the range of mm, micro-LEDs are increasingly gaining interest today, motivated by the future applications of micro-LEDs in augmented reality displays or for nanometrology and sensor technology. A key aspect of this miniaturization is the influence of the structure size, more precisely the surface region, on the electrical and optical properties of micro-LEDs, as the surface-to-volume ratio increases drastically with decreasing size. With this in mind, this data set was generated to investigate the effect of size on the electro-optical properties. The data set contains current-voltage (IV) and electroluminescence (EL) measurements and also secondary electron images of the investigated structures
InGaN/GaN nanoLED Arrays as a Novel Illumination Source for Biomedical Imaging and Sensing Applications
Guidelines for the fabrication of nanoscale light-emitting diode arrays (i.e., nanoLED arrays) based on patterned gallium nitride (GaN) with very small dimensions and pitches have been derived in this work. Several challenges during top-down LED array processing have been tackled involving hybrid etching and polymer-based planarization to yield completely insulated highaspect-ratio LED fin structures and support the creation of p-GaN crossing line contacts, respectively. Furthermore, simulations of the light emission patterns were also performed providing hints for enhancing the device designs. As a result, regardless of the required device processing optimization, the developed nanoLED arrays are expected to offer high potential as novel illumination sources in biomedical imaging and sensing applications (e.g., mini compact microscopes and wearable biological/chemical nanoparticle counters
Directly addressable GaN-based nano-LED arrays: fabrication and electro-optical characterization
The rapid development of display technologies has raised interest in arrays of self-emitting, individually controlled light sources atthe microscale. Gallium nitride (GaN) micro-light-emitting diode (LED) technology meets this demand. However, the current technology is not suitable for the fabrication of arrays of submicron light sources that can be controlled individually. Our approach is based on nanoLED arrays that can directly address each array element and a self-pitch with dimensions below the wavelength of light. The design and fabrication processes are explained in detail and possess two geometries: a 6 Ă 6 array with 400ânm LEDs and a 2 Ă 32 line array with 200ânm LEDs. These nanoLEDs are developed as core elements of a novel on-chip super-resolution microscope. GaN technology, based on its physical properties, is an ideal platform for such nanoLEDs
3D GaN Fins as a Versatile Platform for aâPlaneâBased Devices
GaN fins on GaN-on-sapphire templates are fabricated by continuous mode selective area metalorganic vapor phase epitaxy. The fins exhibit high aspect ratios and smooth nonpolar a-plane sidewalls with an ultra-low threading dislocation density of a few 105 cm^-2 making them ideally suited for optoelectronic to electronic applications. A detailed analysis of the inner structure of GaN fins is provided by the help of marker layer experiments and correlation of results from fins fabricated under different growth conditions, leading to the development of a growth model to explain the final geometry and optical as well as electrical properties of these high aspect ratio fins. Distinctly different material properties for the central and outer parts of the fins are detected. Whereas the outer sidewalls represent high quality GaN surfaces with
very low defect densities, a strong quenching of near band edge emission (NBE) in the central part of the fins is accompanied by heavy compensation of free electrons. A possible explanation is the incorporation of excessive point defects, like intrinsic defects or carbon impurity. The sidewall regions, however, prove to be highly suitable for device applications due to their strong NBE emission, low dislocation density and high free carrier concentration
Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures
The combination of inorganic semiconductors with organic thin films promises new strategies for the realization of complex hybrid optoelectronic devices. Oxidative chemical vapor deposition (oCVD) of conductive polymers offers a flexible and scalable path towards high-quality three-dimensional inorganic/organic optoelectronic structures. Here, hole-conductive poly(3,4-ethylenedioxythiophene) (PEDOT) grown by oxidative chemical vapor deposition is used to fabricate transparent and conformal wrap-around p-type contacts on three-dimensional microLEDs with large aspect ratios, a yet unsolved challenge in three-dimensional gallium nitride technology. The electrical characteristics of two-dimensional reference structures confirm the quasi-metallic state of the polymer, show high rectification ratios, and exhibit excellent thermal and temporal stability. We analyze the electroluminescence from a three-dimensional hybrid microrod/polymer LED array and demonstrate its improved optical properties compared with a purely inorganic microrod LED. The findings highlight a way towards the fabrication of hybrid three-dimensional optoelectronics on the sub-micron scale