Characterization of soil and postlaunch pad debris from Cape Canaveral launch complex and analysis of soil interaction with aqueous HCl

Soil samples were fractionated and analyzed in order to assess the physical and chemical interactions of entrained soil with solid-rocket exhaust clouds. The sandy soil consisted primarily of quartz (silica) particles, 30 to 500 microns in diameter, and also contained seashell fragments. Differential and cumulative soil-mass size distributions are presented along with mineralogy, elemental compositions, and solution pH histories. About 90 percent of the soil mass consisted of particles 165 microns in diameter. Characteristic reaction times in aqueous HC1 slurries varied from a few minutes to several days, and capacities for reaction under acidic conditions varied from 10 to 40 g HCl/kg soil, depending on particle size. Airborne lifetimes of particles 165 microns are conservatively 30 min, and this major grouping is predicted to represent a small short-term chemical sink for up to 5% of the total HC1. The smaller and more minor fractions, below a 165 micron diameter, may act as giant cloud condensation nuclei over much longer airborne lifetimes. Finally, the demonstrated time dependency of neutralization is a complicating factor; it can influence the ability to deduce in-cloud HCl scavenging with reaction and can affect the accuracy of measured chemical compositions of near-field wet deposition

Computer Simulation of Cytoskeleton-Induced Blebbing in Lipid Membranes

Blebs are balloon-shaped membrane protrusions that form during many physiological processes. Using computer simulation of a particle-based model for self-assembled lipid bilayers coupled to an elastic meshwork, we investigated the phase behavior and kinetics of blebbing. We found that blebs form for large values of the ratio between the areas of the bilayer and the cytoskeleton. We also found that blebbing can be induced when the cytoskeleton is subject to a localized ablation or a uniform compression. The results obtained are qualitatively in agreement with the experimental evidence and the model opens up the possibility to study the kinetics of bleb formation in detail.Comment: To appear in Physical Review

Interstellar Scintillation Observations of 146 Extragalactic Radio Sources

From 1979--1996 the Green Bank Interferometer was used by the Naval Research Laboratory to monitor the flux density from 146 compact radio sources at frequencies near 2 and 8 GHz. We filter the ``light curves'' to separate intrinsic variations on times of a year or more from more rapid interstellar scintilation (ISS) on times of 5--50 d. Whereas the intrinsic variation at 2 GHz is similar to that at 8 GHz (though diminished in amplitude), the ISS variation is much stronger at 2 than at 8 GHz. We characterize the ISS variation by an rms amplitude and a timescale and examine the statistics of these parameters for the 121 sources with significant ISS at 2 GHz. We model the scintillations using the NE2001 Galactic electron model assuming the sources are brightness-limited. We find the observed rms amplitude to be in general agreement with the model, provided that the compact components of the sources have about 50% of their flux density in a component with maximum brightness temperatures $10^{11}$--$10^{12}$K. Thus our results are consistent with cm-wavelength VLBI studies of compact AGNs, in that the maximum brightness temperatures found are consistent with the inverse synchrotron limit at $3 \times 10^{11}$ K, boosted in jet configurations by Doppler factors up to about 20. The average of the observed 2 GHz ISS timescales is in reasonable agreement with the model at Galactic latitudes above about 10\de. At lower latitudes the observed timescales are too fast, suggesting that the transverse plasma velocity increases more than expected beyond about 1 kpc.Comment: 32 pages, 16 figures. Submitted to Ap

Biomineralization of PbS and PbS-CdS core-shell nanocrystals and their application in quantum dot sensitized solar cells

Biomineralization utilizes biological systems to synthesize functional inorganic materials for application in diverse fields. In the current work, we enable biomineralization of quantum confined PbS and PbS–CdS core–shell nanocrystals and demonstrate their application in quantum dot sensitized solar cells (QDSSCs). An engineered strain of Stenotrophomonas maltophilia is utilized to generate a cystathionine γ-lyase that is active for the biomineralization of metal sulfide nanocrystals from a buffered aqueous solution of metal salts and L-cysteine. In the presence of lead acetate, this enzymatic route generates rock salt structured PbS nanocrystals. Controlling the growth conditions yields ∼4 nm PbS crystals with absorption and photoluminescence peaks at 910 nm and 1080 nm, respectively, consistent with the expected strong quantum confinement of PbS at this size. Quantum yields (QY) of the biomineralized PbS quantum dots, determined after phase transfer to the organic phase, range between 16 and 45%. These are the highest reported QY values for any biomineralized quantum dot materials to date and are comparable with QYs reported for chemically synthesized materials. Subsequent exposure to cadmium acetate results in the biomineralization of a thin CdS shell on the PbS core with a resultant blue-shift in optical properties. The photoluminescence peak shifts to 980 nm, consistent with the expected decrease in band gap energy of a PbS–CdS core–shell heterostructured quantum dot. HAADF-STEM imaging confirms the crystalline structure and size of the particles with complimentary XEDS analysis confirming the presence of Cd, Pb, and S in individual nanocrystals. Integration of these QDs into QDSSCs yields open circuit potentials of 0.43 V and 0.59 V for PbS and PbS–CdS, respectively, consistent with expectations for these materials and previously reported values for chemically synthesized QDs

Models of OH Maser Variations in U Her

Arecibo spectra of the mainline OH maser emission from U Her over more than a decade show variations of the OH emission over these time scales. These observations are combined with high spatial resolution VLBA maps to investigate the causes of the variations in the velocities of the maser components. Global properties of the dust shell, such as accelerations, variations in the pump and shell-wide magnetic field changes are examined as possibilities, and eliminated. A possible solution to the problem involving plasma turbulence and the local magnetic field is introduced, and the relevant time scales of the turbulence are calculated. The turbulent velocity field yields time scales of the turbulence are calculated. The turbulent velocity field yields time scales that are too long (of order centuries), while the turbulent magnetic field produces variations on appropriate time scales of a few years. A line-of-sight model of the turbulence is developed and investigated. The complete exploration of this solution requires extensive theoretical and observational work. Possible avenues of investigation of the plasma turbulence model are presented.Comment: 23 pages, 17 figures, ApJ: accepted Sept, 199

Enzymatic biomineralization of biocompatible CuInS2, (CuInZn)S2 and CuInS2/ZnS core/shell nanocrystals for bioimaging

This work demonstrates a bioenabled, aqueous phase, room temperature route to synthesize CuInS2/ZnS quantum dots conjugated to IgG antibodies for fluorescent tagging of THP-1 leukemia cells.</p

Ursinus College Bulletin Vol. 10, No. 1, October 1893

A digitized copy of the October 1893 Ursinus College Bulletin.https://digitalcommons.ursinus.edu/ucbulletin/1088/thumbnail.jp

Ursinus College Bulletin Vol. 9, No. 5, February 1893

A digitized copy of the February 1893 Ursinus College Bulletin.https://digitalcommons.ursinus.edu/ucbulletin/1083/thumbnail.jp

A nonextensive entropy approach to solar wind intermittency

The probability distributions (PDFs) of the differences of any physical variable in the intermittent, turbulent interplanetary medium are scale dependent. Strong non-Gaussianity of solar wind fluctuations applies for short time-lag spacecraft observations, corresponding to small-scale spatial separations, whereas for large scales the differences turn into a Gaussian normal distribution. These characteristics were hitherto described in the context of the log-normal, the Castaing distribution or the shell model. On the other hand, a possible explanation for nonlocality in turbulence is offered within the context of nonextensive entropy generalization by a recently introduced bi-kappa distribution, generating through a convolution of a negative-kappa core and positive-kappa halo pronounced non-Gaussian structures. The PDFs of solar wind scalar field differences are computed from WIND and ACE data for different time lags and compared with the characteristics of the theoretical bi-kappa functional, well representing the overall scale dependence of the spatial solar wind intermittency. The observed PDF characteristics for increased spatial scales are manifest in the theoretical distribution functional by enhancing the only tuning parameter $\kappa$, measuring the degree of nonextensivity where the large-scale Gaussian is approached for $\kappa \to \infty$. The nonextensive approach assures for experimental studies of solar wind intermittency independence from influence of a priori model assumptions. It is argued that the intermittency of the turbulent fluctuations should be related physically to the nonextensive character of the interplanetary medium counting for nonlocal interactions via the entropy generalization.Comment: 17 pages, 7 figures, accepted for publication in Astrophys.