Perspectives on the viscoelasticity and flow behavior of entangled linear and branched polymers

We briefly review the recent advances in the rheology of entangled polymers and identify emerging research trends and outstanding challenges, especially with respect to branched polymers. Emphasis is placed on the role of well-characterized model systems, as well as the synergy of synthesis-characterization, rheometry and modeling/simulations. The theoretical framework for understanding the observed linear and nonlinear rheological phenomena is the tube model which is critically assessed in view of its successes and shortcomings, whereas alternative approaches are briefly discussed. Finally, intriguing experimental findings and controversial issues that merit consistent explanation, such as shear banding instabilities, multiple stress overshoots in transient simple shear and enhanced steady-state elongational viscosity in polymer solutions, are discussed, whereas future directions such as branch point dynamics and anisotropic monomeric friction are outlined.Comment: 25 pages, accepted for publication in Journal of Physics Condensed Matter (August 2015

Thick films of YSZ electrolytes by dip-coating process

Yttria stabilized zirconia (YSZ, 8% Y2O3) thick films were coated on porous Ni-YSZ substrates using the dip-coating process and a suspension with a new formulation. The suspension was obtained by addition of a polymeric matrix in a stable suspension of a commercial YSZ (Tosoh) powders dispersed in an azeotropic MEK-EtOH mixture. The green layers were densified after an optimization of the suspension composition. YSZ Tosoh particles encapsulated by a zirconium alkoxide sol and added with colloidal alkoxide precursor are used to load the suspension. The in situ growth of these colloids increases significantly the layers density after an appropriated heat treatment. The obtained films are continuous, homogeneous and 20 μm thick. Different microstructures are obtained depending on the synthesis parameters of the suspension