404 research outputs found
Electronic structure and bond competition in the polar magnet PbVO
Density functional electronic structure studies of tetragonal PbVO are
reported. The results show a an important role for both Pb 6 - O 2 and V
- O bonding, with an interplay between these. This is discussed in
relation to the possibility of obtaining magnetoelectric behavior.Comment: 5 page
Poling effect on distribution of quenched random fields in a uniaxial relaxor ferroelectric
The frequency dependence of the dielectric permitivity's maximum has been
studied for poled and unpoled doped relaxor strontium barium niobate
(SBN-61:Cr). In both cases the maximum
found is broad and the frequency dispersion is strong. The present view of
random fields compensation in the unpoled sample is not suitable for explaining
this experimental result. We propose a new mechanism where the dispersion of
quenched random electric fields, affecting the nanodomains, is minimized after
poling. We test our proposal by numerical simulations on a random field Ising
model. Results obtained are in agreement with the polarization's measurements
presented by Granzow et al. [Phys. Rev. Lett {\bf 92}, 065701 (2004)].Comment: 7 pages, 4 figure
Magnetic control of large room-temperature polarization
Numerous authors have referred to room-temperature magnetic switching of
large electric polarizations as The Holy Grail of magnetoelectricity.We report
this long-sought effect using a new physical process of coupling between
magnetic and ferroelectric relaxor nano-regions. Here we report magnetic
switching between the normal ferroelectric state and the ferroelectric relaxor
state. This gives both a new room-temperature, single-phase, multiferroic
magnetoelectric, PbZr0.46Ti0.34Fe0.13W0.07O3, with polarization, loss (<4%),
and resistivity (typically 108 -109 ohm.cm) equal to or superior to BiFeO3, and
also a new and very large magnetoelectric effect: switching not from +Pr to
negative Pr with applied H, but from Pr to zero with applied H of less than a
Tesla. This switching of the polarization occurs not because of a conventional
magnetically induced phase transition, but because of dynamic effects:
Increasing H lengthens the relaxation time by x500 from 100 ?s, and
it couples strongly the polarization relaxation and spin relaxations. The
diverging polarization relaxation time accurately fits a modified Vogel-Fulcher
Equation in which the freezing temperature Tf is replaced by a critical
freezing field Hf that is 0.92 positive/negative 0.07 Tesla. This field
dependence and the critical field Hc are derived analytically from the
spherical random bond random field (SRBRF) model with no adjustable parameters
and an E2H2 coupling. This device permits 3-state logic (+Pr,0,negative Pr) and
a condenser with >5000% magnetic field change in its capacitance.Comment: 20 pages, 5 figure
Tetragonal tungsten bronze compounds: relaxor vs mixed ferroelectric - dipole glass behavior
We demonstrate that recent experimental data (E. Castel et al J.Phys. Cond.
Mat. {\bf 21} (2009), 452201) on tungsten bronze compound (TBC)
BaPrNdFeNbO can be well explained in our model
predicting a crossover from ferroelectric () to orientational (dipole)
glass (), rather then relaxor, behavior. We show, that since a "classical"
perovskite relaxor like Pb(Mn Nb)O is never a
ferroelectric, the presence of ferroelectric hysteresis loops in TBC shows that
this substance actually transits from ferroelectric to orientational glass
phase with growth. To describe the above crossover theoretically, we use
the simple replica-symmetric solution for disordered Ising model.Comment: 5 two-column pages, 4 figure
Landau Theory of Domain Wall Magnetoelectricity
We calculate the exact analytical solution to the domain wall properties in a
multiferroic system with two order parameters that are coupled
bi-quadratically. This is then adapted to the case of a magnetoelectric
multiferroic material such as BiFeO3, with a view to examine critically whether
the domain walls can account for the enhancement of magnetization reported for
thin films fo this material, in view of the correlation between increasing
magnetization and increasing volume fraction of domain walls as films become
thinner. The present analysis can be generalized to describe a class of
magnetoelectric devices based upon domain walls rather than bulk properties.Comment: 9 pages, 4 figure
Raman and Infrared-Active Phonons in Hexagonal HoMnO Single Crystals: Magnetic Ordering Effects
Polarized Raman scattering and infrared reflection spectra of hexagonal
HoMnO single crystals in the temperature range 10-300 K are reported.
Group-theoretical analysis is performed and scattering selection rules for the
second order scattering processes are presented. Based on the results of
lattice dynamics calculations, performed within the shell model, the observed
lines in the spectra are assigned to definite lattice vibrations. The magnetic
ordering of Mn ions, which occurs below T=76 K, is shown to effect both
Raman- and infrared-active phonons, which modulate Mn-O-Mn bonds and,
consequently, Mn exchange interaction.Comment: 8 pages, 6 figure
Polarization Relaxation Induced by Depolarization Field in Ultrathin Ferroelectric BaTiO Capacitors
Time-dependent polarization relaxation behaviors induced by a depolarization
field were investigated on high-quality ultrathin
SrRuO/BaTiO/SrRuO capacitors. The values were
determined experimentally from an applied external field to stop the net
polarization relaxation. These values agree with those from the electrostatic
calculations, demonstrating that a large inside the ultrathin
ferroelectric layer could cause severe polarization relaxation. For numerous
ferroelectric devices of capacitor configuration, this effect will set a
stricter size limit than the critical thickness issue
Giant Magnetoelectric Effect in a Multiferroic Material with a High Ferroelectric Transition Temperature
We present a unique example of giant magnetoelectric effect in a conventional
multiferroic HoMnO3, where polarization is very large (~56 mC/m2) and the
ferroelectric transition temperature is higher than the magnetic ordering
temperature by an order. We attribute the uniqueness of the giant
magnetoelectric effect to the ferroelectricity induced entirely by the
off-center displacement of rare earth ions with large magnetic moments. This
finding suggests a new avenue to design multiferroics with large polarization
and higher ferroelectric transition temperature as well as large
magnetoelectric effects
On the phase identity and its thermal evolution of lead free (Bi1/2Na1/2)TiO3-6 mol% BaTiO3
Temperature-dependent dielectric permittivity of 0.94(Bi1/2Na1/2) TiO3-0.06BaTiO(3) (BNT-6BT) lead-free piezoceramics was studied to disentangle the existing unclear issues over the crystallographic aspects and phase stability of the system. Application of existing phenomenological relaxor models enabled the relaxor contribution to the entire dielectric permittivity spectra to be deconvoluted. The deconvoluted data in comparison with the temperature-dependent dielectric permittivity of a classical perovskite relaxor, La-modified lead zirconate titanate, clearly suggest that BNT-6BT belongs to the same relaxor category, which was also confirmed by a comparative study on the temperature-dependent polarization hysteresis loops of both materials. Based on these results, we propose that the low-temperature dielectric anomaly does not involve any phase transition such as ferroelectric-toantiferroelectric. Supported by transmission electron microscopy and X-ray diffraction experiments at ambient temperature, we propose that the commonly observed two dielectric anomalies are attributed to thermal evolution of ferroelectric polar nanoregions of R3c and P4bm symmetry, which coexist nearly throughout the entire temperature range and reversibly transform into each other with temperature.open1128
State transition and electrocaloric effect of BaZrTiO: simulation and experiment
The electrocaloric effect (ECE) of BaZrTiO (BZT) is closely
related to the relaxor state transition of the materials. This work presents a
systematic study on the ECE and the state transition of the BZT, using a
combined canonical and microcanonical Monte Carlo simulations based a
lattice-based on a Ginzburg-Landau-type Hamiltonian. For comparison and
verification, experimental measurements have been carried on BTO and BZT
( and ) samples, including the ECE at various temperatures, domain
patterns by Piezoresponse Force Microscopy at room temperature, and the P-E
loops at various temperatures. Results show that the dependency of BZT behavior
of the Zr-concentration can be classified into three different stages. In the
composition range of , ferroelectric domains are visible,
but ECE peak drops with increasing Zr-concentration harshly. In the range of , relaxor features become prominent, and the decrease of
ECE with Zr-concentration is moderate. In the high concentration range of , the material is almost nonpolar, and there is no ECE peak visible.
Results suggest that BZT with certain low range of Zr-concentration around
can be a good candidate with relatively high ECE and
simutaneously wide temperature application range at rather low temperature
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