A Spectroscopic Study of Some Cyclic Polycarbonyls And Related Compounds.

The object of this work was to investigate the structures of some monocyclic polycarbonyl compounds and their condensation products. Methods employed in this study include infrared, ultraviolet-visible, 'H and 14N magnetic resonance spectroscopy and mass spectrometry. The electronic spectra of tetrahydroxy-p-benzoquinone, rhodizonic acid, croconic acid and squaric acid are interpreted on the basis of Pariser-Parr-Pople LCAO-SCF-MO calculations. The mass spectral fragmentation of the oxocarbons is characterised by the elimination of carbon monoxide followed by ring closure to yield the next lower member of the series. These measurements also indicate a gem-diol structure for rhodizonic acid dihydrate. The isolation and both the spectroscopic and mass spectrometric studies of some oxocarbon condensation products is reported. These studies confirm the structural features of the compounds 1,2,3,4-tetrahydroxy-phenazines, 2,3-dihydroxy-phenazine-1,4-quinones, phenazine-1,2,3,4-tetrones and polycondensation products. Pariser-Parr-Pople LCAO-SCF-MO calculations on 1,2,3,4-tetrahydroxy-phenazine and 2,3-dihydroxy-phenazine-1,4-quinone provide a satisfactory basis for the interpretation of their electronic spectra. Squaric acid condensation products have been isolated and studied. These compounds are shown to have the 1,2,3,8-tetrahydro-1,2-dioxo-cyclobuta-(b)-quinoxaline structure. Squaric acid also gives a salt with o-phenylenediamine from which octahedral copper and nickel complexes have been isolated and characterized

Enzyme activity in terrestrial soil in relation to exploration of the Martian surface Semiannual progress report, 1 Jul. - 31 Dec. 1967

Enzyme behavior in nonclassical systems, surface pH estimation in soils, and enzymatic activities in stored and geologically preserved soil

Enzyme Activity in Terrestrial Soil in Relation to Exploration of the Martian Surface Third Semiannual Progress Report, 1 Jul. - 31 Dec. 1965

Qualitative and quantitative test for enzyme activities in terrestrial soil adapted to Mars probe telemetry procedure

Reduced-Order Modeling of Hypersonic Vehicle Unsteady Aerodynamics

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/83648/1/AIAA-2010-8127-858.pd

Reduced-Order Modeling of Unsteady Aerodynamics Across Multiple Mach Regimes.

The accurate prediction of unsteady aerodynamic loads is of utmost importance in an aeroelastic simulation framework. Inaccurate prediction of these loads may result in inaccurate control design and evaluation, which, in a worst-case scenario, could cause loss of control of the vehicle. In addition to accuracy, these simulations require that the aerodynamic calculations be computationally efficient, so this often eliminates the use of full-order computational fluid dynamics (CFD) simulations, which can be quite computationally-intensive. Reduced-order models (ROMs) offer a solution to these competing demands of accuracy and efficiency by extracting pertinent data from a limited number of full-order CFD simulations and using that data to construct computationally-efficient models that retain a high amount of the accuracy of the full order solution while running orders of magnitude faster computationally. This dissertation focuses on the development of a reduced-order modeling methodology for unsteady aerodynamics based on linear convolution combined with a nonlinear correction factor. Rather than being limited to a specific Mach regime, the ROM formulation is general enough such that it can be applied over a wide range of Mach regimes, from subsonic to hypersonic flight. The correction factor term allows the ROM to be accurate over a range of vehicle elastic modal deformation amplitudes as well as flight conditions representing off-design conditions. This generality is important because it permits a single form of the equations for aerodynamic loads to be used throughout all simulations in a controls framework, further increasing the efficiency. The evaluation of the ROM is accomplished through the comparison of ROM results with full-order CFD simulations for test-case geometries in the subsonic, transonic, and super/hypersonic regimes. Additionally, methods for ROM construction are explored, including the development of a simplified aerodynamic model in the transonic regime for use in aiding ROM construction. Overall, good agreement is obtained between the ROM and CFD results, generally improving as Mach number increases. The potential of the ROM is illustrated by following a single example case from low subsonic up through supersonic flight, thus demonstrating the usefulness of the approach over a wide range of conditions.PHDAerospace EngineeringUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib.umich.edu/bitstream/2027.42/97977/1/tskujins_1.pd

Six-Degree-of-Freedom Simulation of Hypersonic Vehicles

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/77268/1/AIAA-2009-5601-114.pd