ESR study of the spin ladder with uniform Dzyaloshinskii-Moria interaction

Evolution of the ESR absorption in a strong-leg spin ladder magnet (C$_7$H$_{10}$N$_2$)$_2$CuBr$_4$ (abbreviated as DIMPY) is studied from 300K to 400mK. Temperature dependence of the ESR relaxation follows a staircase of crossovers between different relaxation regimes. We ague that the main mechanism of ESR line broadening in DIMPY is uniform Dzyaloshinskii-Moria interaction ($|\vec{D}|=0.20$K) with an effective longitudinal component along an exchange bond of Cu ions within the legs resulting from the low crystal symmetry of DIMPY and nontrivial orbital ordering. The same Dzyaloshinskii-Moriya interaction results in the lifting of the triplet excitation degeneracy, revealed through the weak splitting of the ESR absorption at low temperatures.Comment: 13 pages, submitted to PRB, Fig.3 update

Public political narratives: developing a neglected source through the exploratory case of Russia in the Putin-Medvedev era

The place of narrative in political science is an issue that resurfaces with regularity, usually focusing on the questions of generalisability, evidence and causality which lie at the heart of the discipline. Most such debate concerns the use of narrative by political scientists. Far less attention has been devoted to the use of narrative by political actors, despite its relative ubiquity. Even where such attention has been given, it concentrates less on the narrative per se, and more on its performance and impact. However, the nature of public political narratives means that analysis of them facilitates a holistic understanding of their narrators' politics. A public political narrative consists of a sequential account given by political actors connecting selected, specific developments so as to impose a desired order on them. Taking contemporary Russia as an exploratory case, narrative analysis draws out the motivations, world view and inconsistencies within the Putin-Medvedev regime. Recurring motifs and symbols identify the regime's political priorities, explaining policy choices and revealing future concerns. Narrative has a predictive aspect, identifying likely policy responses to unexpected events. Narratives capture time, and shifts in their temporalities indicate changes in self-conceptualisation and political priorities. Temporal appropriations include or exclude particular agential and causal explanations. The relationship between their plots and subplots represents a political signalling process. Public political narratives provide temporally and spatially specific exceptionalist accounts, but their combinatory quality also facilitates comparative analysis. The approach essayed here provides methodological generalisability, arguing that the neglect of public political narratives merits correcting

ESR study of the spin ladder with uniform Dzyaloshinskii-Moriya interaction

©2015 American Physical Society. Evolution of the ESR absorption in a strong-leg spin ladder magnet (C7H10N)2CuBr4 (abbreviated as DIMPY) is studied from 300 K to 400 mK. Temperature dependence of the ESR relaxation follows a staircase of crossovers between different relaxation regimes. We argue that the main mechanism of ESR line broadening in DIMPY is uniform Dzyaloshinskii-Moriya interaction (|D|=0.31 K) with an effective longitudinal component along an exchange bond of Cu ions within the legs resulting from the low crystal symmetry of DIMPY and nontrivial orbital ordering. The same Dzyaloshinskii-Moriya interaction along with other weaker anisotropic spin-spin interactions results in the lifting of the triplet excitation degeneracy, revealed through the weak splitting of the ESR absorption at low temperatures

ESR study of the spin ladder with uniform Dzyaloshinskii-Moriya interaction

©2015 American Physical Society. Evolution of the ESR absorption in a strong-leg spin ladder magnet (C7H10N)2CuBr4 (abbreviated as DIMPY) is studied from 300 K to 400 mK. Temperature dependence of the ESR relaxation follows a staircase of crossovers between different relaxation regimes. We argue that the main mechanism of ESR line broadening in DIMPY is uniform Dzyaloshinskii-Moriya interaction (|D|=0.31 K) with an effective longitudinal component along an exchange bond of Cu ions within the legs resulting from the low crystal symmetry of DIMPY and nontrivial orbital ordering. The same Dzyaloshinskii-Moriya interaction along with other weaker anisotropic spin-spin interactions results in the lifting of the triplet excitation degeneracy, revealed through the weak splitting of the ESR absorption at low temperatures

ESR study of the spin ladder with uniform Dzyaloshinskii-Moriya interaction

©2015 American Physical Society. Evolution of the ESR absorption in a strong-leg spin ladder magnet (C7H10N)2CuBr4 (abbreviated as DIMPY) is studied from 300 K to 400 mK. Temperature dependence of the ESR relaxation follows a staircase of crossovers between different relaxation regimes. We argue that the main mechanism of ESR line broadening in DIMPY is uniform Dzyaloshinskii-Moriya interaction (|D|=0.31 K) with an effective longitudinal component along an exchange bond of Cu ions within the legs resulting from the low crystal symmetry of DIMPY and nontrivial orbital ordering. The same Dzyaloshinskii-Moriya interaction along with other weaker anisotropic spin-spin interactions results in the lifting of the triplet excitation degeneracy, revealed through the weak splitting of the ESR absorption at low temperatures

Twisting of Fibers Balancing the Gel–Sol Transition in Cellulose Aqueous Suspensions

Cellulose hydrogels and films are advantageous materials that are applied in modern industry and medicine. Cellulose hydrogels have a stable scaffold and never form films upon drying, while viscous cellulose hydrosols are liquids that could be used for film production. So, stabilizing either a gel or sol state in cellulose suspensions is a worthwhile challenge, significant for the practical applications. However, there is no theory describing the cellulose fibers’ behavior and processes underlying cellulose-gel-scaffold stabilizing. In this work, we provide a phenomenological mechanism explaining the transition between the stable-gel and shapeless-sol states in a cellulose suspension. We suppose that cellulose macromolecules and nanofibrils under strong dispersing treatment (such as sonication) partially untwist and dissociate, and then reassemble in a 3D scaffold having the individual elements twisted in the nodes. The latter leads to an exponential increase in friction forces between the fibers and to the corresponding fastening of the scaffold. We confirm our theory by the data on the circular dichroism of the cellulose suspensions, as well as by the direct scanning electron microscope (SEM) observations and theoretical assessments