3 research outputs found
Quantum spill-out in nanometer-thin gold slabs: Effect on plasmon mode index and plasmonic absorption
A quantum mechanical approach and local response theory are applied to study
plasmons propagating in nanometer-thin gold slabs sandwiched between different
dielectrics. The metal slab supports two different kinds of modes, classified
as long-range and short-range plasmons. Quantum spill-out is found to
significantly increase the imaginary part of their mode indices, and,
surprisingly, even for slabs wide enough to approach bulk the increase is 20%.
This is explained in terms of enhanced plasmonic absorption, which mainly takes
place at narrow peaks located near the slab surface
Quantum spill out in few-nanometer metal gaps: Effect on gap plasmons and reflectance from ultrasharp groove arrays
Plasmons in ultranarrow metal gaps are highly sensitive to the electron
density profile at the metal surfaces. Using a fully quantum mechanical
approach, we study the effects of electron spill-out on gap plasmons and
reflectance from ultrasharp metal grooves. We demonstrate that the mode index
of ultranarrow gap plasmons converges to the bulk refractive index in the limit
of vanishing gap and, thereby, rectify the unphysical divergence found in
classical models. Surprisingly, spill-out also significantly increases the
plasmonic absorption for few-nanometer gaps and lowers the reflectance from
arrays of ultrasharp metal grooves. These findings are explained in terms of
enhanced gap plasmon absorption taking place inside the gap 1-2 {\AA} from the
walls and delocalization near the groove bottom. Reflectance calculations
taking spill-out into account are shown to be in much better agreement with
measurements compared with classical models