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A dramatic isotope effect in the reaction of ClSiH with trimethylsilane-1-d: experimental evidence for intermediate complexes in silylene Si-H(D) insertion reactions
Get PDFA kinetic isotope effect (kD/kH) of 7.4 has been found for the reaction of chlorosilylene with trimethysilane (Me3SiD vs Me3SiH). Such a value can be accounted for by theoretical modelling, but only if an internal rearrangement of the initially form complex is included in the mechanism. This provides the first concrete evidence for such complexes
Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons
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Stereochemistry of the Free-Radical Addition of Methyl Mercaptan to 1-Chloro-4-t-butylcyclohexene
No full textStereochemical Course of the Free-Radical Addition of Hydrogen Bromide to 1-Chloro-4-t-butylcyclohexene
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Reactions of Atoms and Free Radicals in Solution. XII. The Addition of Bromo Esters to Olefins
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