Electroless Copper Plating of Inkjet-Printed Polydopamine Nanoparticles: a Facile Method to Fabricate Highly Conductive Patterns at Near Room Temperature

Aqueous dispersions of artificially synthesized, mussel-inspired poly­(dopamine) nanoparticles were inkjet printed on flexible polyethylene terephthalate (PET) substrates. Narrow line patterns (4 μm in width) of poly­(dopamine) resulted due to evaporatively driven transport (coffee ring effect). The printed patterns were metallized via a site-selective Cu electroless plating process at a controlled temperature (30 °C) for varied bath times. The lowest electrical resistivity value of the plated Cu lines was about 6 times greater than the bulk resistivity of Cu. This process presents an industrially viable way to fabricate Cu conductive fine patterns for flexible electronics at low temperature, low cost, and without need of sophisticated equipment

Flexible-to-Stretchable Mechanical and Electrical Interconnects

Stretchable electronic devices that maintain electrical function when subjected to stress or strain are useful for enabling new applications for electronics, such as wearable devices, human–machine interfaces, and components for soft robotics. Powering and communicating with these devices is a challenge. NFC (near-field communication) coils solve this challenge but only work efficiently when they are in close proximity to the device. Alternatively, electrical signals and power can arrive via physical connections between the stretchable device and an external source, such as a battery. The ability to create a robust physical and electrical connection between mechanically disparate components may enable new types of hybrid devices in which at least a portion is stretchable or deformable, such as hinges. This paper presents a simple method to make mechanical and electrical connections between elastomeric conductors and flexible (or rigid) conductors. The adhesion at the interface between these disparate materials arises from surface chemistry that forms strong covalent bonds. The utilization of liquid metals as the conductor provides stretchable interconnects between stretchable and non-stretchable electrical traces. The liquid metal can be printed or injected into vias to create interconnects. We characterized the mechanical and electrical properties of these hybrid devices to demonstrate the concept and identify geometric design criteria to maximize mechanical strength. The work here provides a simple and general strategy for creating mechanical and electrical connections that may find use in a variety of stretchable and soft electronic devices

Flexible-to-Stretchable Mechanical and Electrical Interconnects

Stretchable electronic devices that maintain electrical function when subjected to stress or strain are useful for enabling new applications for electronics, such as wearable devices, human–machine interfaces, and components for soft robotics. Powering and communicating with these devices is a challenge. NFC (near-field communication) coils solve this challenge but only work efficiently when they are in close proximity to the device. Alternatively, electrical signals and power can arrive via physical connections between the stretchable device and an external source, such as a battery. The ability to create a robust physical and electrical connection between mechanically disparate components may enable new types of hybrid devices in which at least a portion is stretchable or deformable, such as hinges. This paper presents a simple method to make mechanical and electrical connections between elastomeric conductors and flexible (or rigid) conductors. The adhesion at the interface between these disparate materials arises from surface chemistry that forms strong covalent bonds. The utilization of liquid metals as the conductor provides stretchable interconnects between stretchable and non-stretchable electrical traces. The liquid metal can be printed or injected into vias to create interconnects. We characterized the mechanical and electrical properties of these hybrid devices to demonstrate the concept and identify geometric design criteria to maximize mechanical strength. The work here provides a simple and general strategy for creating mechanical and electrical connections that may find use in a variety of stretchable and soft electronic devices

Flexible-to-Stretchable Mechanical and Electrical Interconnects

Stretchable electronic devices that maintain electrical function when subjected to stress or strain are useful for enabling new applications for electronics, such as wearable devices, human–machine interfaces, and components for soft robotics. Powering and communicating with these devices is a challenge. NFC (near-field communication) coils solve this challenge but only work efficiently when they are in close proximity to the device. Alternatively, electrical signals and power can arrive via physical connections between the stretchable device and an external source, such as a battery. The ability to create a robust physical and electrical connection between mechanically disparate components may enable new types of hybrid devices in which at least a portion is stretchable or deformable, such as hinges. This paper presents a simple method to make mechanical and electrical connections between elastomeric conductors and flexible (or rigid) conductors. The adhesion at the interface between these disparate materials arises from surface chemistry that forms strong covalent bonds. The utilization of liquid metals as the conductor provides stretchable interconnects between stretchable and non-stretchable electrical traces. The liquid metal can be printed or injected into vias to create interconnects. We characterized the mechanical and electrical properties of these hybrid devices to demonstrate the concept and identify geometric design criteria to maximize mechanical strength. The work here provides a simple and general strategy for creating mechanical and electrical connections that may find use in a variety of stretchable and soft electronic devices

Effect of Yttrium-Incorporated TiO₂ Electron Transport Layer on the Photovoltaic Performance of Triple-Cation Perovskite Solar Cells

Achieving an excellent electron transport layer is significant for high-performance perovskite solar cells. A TiO2 compact film is extensively applied as an electron transport layer. However, some limiting issues, such as unfavorable band offset, unsatisfactory electrical conductivity, low electron mobility, and high-density defects, remain in the TiO2 electron transport layer. In this work, yttrium (Y) is proposed as a dopant in the TiO2 electron transport layer. It is revealed that the incorporation of Y promotes the Fermi energy level of TiO2 shift upward, bringing about more favorable energy-level alignment for the transport of photogenerated carriers. In addition, the device assembled with a Y-TiO2 electron transport layer exhibits an increased built-in potential, suggesting a more powerful driving force for charge separation and transport. Eventually, the triple-cation perovskite solar cell equipped with a Y-TiO2 electron transport layer acquires an efficiency of 20.09%. It is superior to that of the TiO2-based device (17.28%). The results indicate that Y-ion doping is a promising method to fabricate highly efficient perovskite solar cells

Regulation of the Deposition Morphology of Inkjet-Printed Crystalline Materials via Polydopamine Functional Coatings for Highly Uniform and Electrically Conductive Patterns

We report a method to achieve highly uniform inkjet-printed silver nitrate (AgNO₃) and a reactive silver precursor patterns on rigid and flexible substrates functionalized with polydopamine (PDA) coatings. The printed AgNO₃ patterns on PDA-coated substrates (glass and polyethylene terephthalate (PET)) exhibit a narrow thickness distribution ranging between 0.9 and 1 μm in the line transverse direction and uniform deposition profiles in the line axial direction. The deposited reactive silver precursor patterns on PDA-functionalized substrates also show “dome-shaped” morphology without “edge-thickened” structure due to “coffee-stain” effect. We posit that the highly uniform functional ink deposits formed on PDA-coated substrates are attributable to the strong binding interaction between the abundant catecholamine moieties at the PDA surface and the metallic silver cations (Ag⁺ or Ag­(NH₃)²⁺) in the solutal inks. During printing of the ink rivulet and solvent evaporation, the substrate–liquid ink (S–L) interface is enriched with the silver-based cations and a solidification at the S/L interface is induced. The preferential solidification initiated at the S–L interface is further verified by the in situ visualization of the dynamic solidification process during solvent evaporation, and results suggest an enhanced crystal nucleation and growth localized at the S–L interface on PDA functionalized substrates. This interfacial interaction mediates solute transport in the liquid phase, resulting in the controlled enrichment of solute at the S–L interface and mitigated solute precipitation in both the contact line region and the liquid ink–vapor (L–V) interface due to evaporation. This mediated transport contributes to the final uniform solid deposition for both types of ink systems. This technique provides a complementary strategy for achieving highly uniform inkjet-printed crystalline structures, and can serve as an innovative foundation for high-precision additive delivery of functional materials

Flexible-to-Stretchable Mechanical and Electrical Interconnects

Stretchable electronic devices that maintain electrical function when subjected to stress or strain are useful for enabling new applications for electronics, such as wearable devices, human–machine interfaces, and components for soft robotics. Powering and communicating with these devices is a challenge. NFC (near-field communication) coils solve this challenge but only work efficiently when they are in close proximity to the device. Alternatively, electrical signals and power can arrive via physical connections between the stretchable device and an external source, such as a battery. The ability to create a robust physical and electrical connection between mechanically disparate components may enable new types of hybrid devices in which at least a portion is stretchable or deformable, such as hinges. This paper presents a simple method to make mechanical and electrical connections between elastomeric conductors and flexible (or rigid) conductors. The adhesion at the interface between these disparate materials arises from surface chemistry that forms strong covalent bonds. The utilization of liquid metals as the conductor provides stretchable interconnects between stretchable and non-stretchable electrical traces. The liquid metal can be printed or injected into vias to create interconnects. We characterized the mechanical and electrical properties of these hybrid devices to demonstrate the concept and identify geometric design criteria to maximize mechanical strength. The work here provides a simple and general strategy for creating mechanical and electrical connections that may find use in a variety of stretchable and soft electronic devices

Fabrication of Novel Transparent Touch Sensing Device via Drop-on-Demand Inkjet Printing Technique

A novel transparent touch sensor was fabricated with a drop-on-demand inkjet printing technique on borosilicate glass and flexible polyethylene terephthalate (PET) substrates. Conductive poly­(3,4-ethylenedioxythiophene):poly­(styrenesulfonate) (PEDOT:PSS) and dielectric poly­(methylsiloxane) were deposited on a desired area to form a capacitive touch sensor structure. The properties of the printed sensors (optical transparency, electrical resistance and touch sensing performance) were investigated with varying PEDOT: PSS printing passes. A novel transparent touch sensor fabricated with an all-inkjet-printing method is demonstrated for the first time. This process holds industrially viable potential to fabricate transparent touch sensors with an inkjet printing technique on both rigid and flexible substrates for a wide range of applications

Regenerable Fluorescent Nanosensors for Monitoring and Recovering Metal Ions Based on Photoactivatable Monolayer Self-Assembly and Host–Guest Interactions

Efficient detection, removal, and recovery of heavy metal ions from aqueous environments represents a technologically challenging and ecologically urgent question in the face of increasing metal-related pollution and poisoning across the globe. Although small-molecule and entrapment-based nanoparticle sensors have been extensively explored for metal detection, neither of these extant strategies satisfies the critical needs for high-performance sensors that are inexpensive, efficient, and recyclable. Here we first report the development of a regenerable fluorescent nanosensor system for the selective and sensitive detection of multiple heavy metal ions, based on light-switchable monolayer self-assembly and host–guest interactions. The system exploits photocontrolled inclusion and exclusion responses of an α-cyclodextrin (CD)-containing surface conjugated with photoisomerizable azobenzene as a supramolecular system that undergoes reversible assembly and disassembly. The metal nanosensors can be facilely fabricated and photochemically switched between three chemically distinct entities, each having an excellent capacity for selective detecting specific metal ions (namely, Cu²⁺, Fe³⁺, Hg²⁺) in a chemical system and in assays on actual water samples with interfering contaminants

Silicones for Stretchable and Durable Soft Devices: Beyond Sylgard-184

This paper identifies and characterizes silicone elastomers that are well-suited for fabricating highly stretchable and tear-resistant devices that require interfacial bonding by plasma or UV ozone treatment. The ability to bond two or more pieces of molded silicone is important for creating microfluidic channels, chambers for pneumatically driven soft robotics, and other soft and stretchable devices. Sylgard-184 is a popular silicone, particularly for microfluidic applications. However, its low elongation at break (∼100% strain) and moderate tear strength (∼3 N/mm) make it unsuitable for emerging, mechanically demanding applications of silicone. In contrast, commercial silicones, such as Dragon Skin, have excellent mechanical properties yet are difficult to plasma-bond, likely because of the presence of silicone oils that soften the network yet migrate to the surface and interfere with plasma bonding. We found that extracting silicone oligomers from these soft networks allows these materials to bond but only when the Shore hardness exceeds a value of 15 A. It is also possible to mix highly stretchable silicones (Dragon Skin and Ecoflex) with Sylgard-184 to create silicones with intermediate mechanical properties; interestingly, these blends also only bond when the hardness exceeds 15 A. Eight different Pt-cured silicones were also screened; again, only those with Shore hardness above 15 A plasma-bond. The most promising silicones from this study are Sylgard-186 and Elastosil-M4130 and M4630, which exhibit a large deformation (>200% elongation at break), high tear strength (>12 N/mm), and strong plasma bonding. To illustrate the utility of these silicones, we created stretchable electrodes by injecting a liquid metal into microchannels created using such silicones, which may find use in soft robotics, electronic skin, and stretchable energy storage devices