Bose-Einstein condensation of metastable helium: some experimental aspects

We describe our recent realization of BEC using metastable helium. All detection is done with a micruchannel plate which detects the metastables or ions coming from the trapped atom cloud. This discussion emphasizes some of the diagnostic experiments which were necessary to quantitatively analyse our results.Comment: 5 pages, 3 figure

Extension of the composite CBS-QB3 method to singlet diradical calculations

The composite CBS-QB3 method is widely used to obtain accurate energies of molecules and radicals although its use in the case of singlet diradicals gives rise to some difficulties. The problem is related to the parameterized correction this method introduces to account for spin-contamination. We report a new term specifically designed to describe singlet diradicals separated by at least one CH2 unit. As a test case, we have computed the formation enthalpy of a series of diradicals that includes hydrocarbons as well as systems involving heteroatoms (nitrogen, oxygen). The resulting CBS-QB3 energies are very close to experiment

The autoignition of cyclopentane and cyclohexane in a shock tube

Ignition delay times of cyclohexane-oxygen-argon and cyclopentane-oxygen-argon mixtures have been measured in a shock tube, the onset of ignition being detected by OH radical emission. Mixtures contained 0.5 or 1 % of hydrocarbon for equivalence ratios ranging from 0.5 to 2. Reflected shock waves allowed temperatures from 1230 to 1800 K and pressures from 7.3 to 9.5 atm to be obtained. These measurements have shown that cyclopentane is much less reactive than cyclohexane, as for a given temperature the observed autoignition delay times were about ten times higher for the C5 compound compared to the C6. Detailed mechanisms for the combustion of cyclohexane and cyclopentane have been proposed to reproduce these results. The elementary steps included in the kinetic models of the oxidation of cyclanes are close to those proposed to describe the oxidation of acyclic alkanes and alkenes. Consequently, it has been possible to obtain these models by using an improved version of software EXGAS, a computer package developed to perform the automatic generation of detailed kinetic models for the gas-phase oxidation and combustion of linear and branched alkanes and alkenes. Nevertheless, the modelling of the oxidation of cyclanes requires to consider new types of generic reactions, and especially to define new correlations for the estimation of the rate constants. Ab initio calculations have been used to better know some of the rate constants used in the case of cyclopentane. The main reaction pathways have been derived from flow rate and sensitivity analyses

Ionization rates in a Bose-Einstein condensate of metastable Helium

We have studied ionizing collisions in a BEC of He*. Measurements of the ion production rate combined with measurements of the density and number of atoms for the same sample allow us to estimate both the 2 and 3-body contributions to this rate. A comparison with the decay of the number of condensed atoms in our magnetic trap, in the presence of an rf-shield, indicates that ionizing collisions are largely or wholly responsible for the loss. Quantum depletion makes a substantial correction to the 3-body rate constant.Comment: 4 pages, 3 figure

Getting the elastic scattering length by observing inelastic collisions in ultracold metastable helium atoms

We report an experiment measuring simultaneously the temperatureand the flux of ions produced by a cloud of triplet metastablehelium atoms at the Bose-Einstein critical temperature. The onsetof condensation is revealed by a sharp increase of the ion fluxduring evaporative cooling. Combining our measurements withprevious measurements of ionization in a pure BEC,we extract an improved value of the scattering length$a=11.3^{+2}_{-1}$ nm. The analysis includes corrections takinginto accountthe effect of atomic interactions on the criticaltemperature, and thus an independent measurement of the scatteringlength would allow a new test of these calculations

Thermal decomposition of norbornane (bicyclo[2.2.1]heptane) dissolved in benzene. Experimental study and mechanism investigation

The thermal decomposition of norbornane (dissolved in benzene) has been studied in a jet stirred reactor at temperatures between 873 and 973 K, at residence times ranging from 1 to 4 s and at atmospheric pressure, leading to conversions from 0.04 to 22.6%. 25 reaction products were identified and quantified by gas chromatography, amongst which the main ones are hydrogen, ethylene and 1,3-cyclopentadiene. A mechanism investigation of the thermal decomposition of the norbornane - benzene binary mixture has been performed. Reactions involved in the mechanism have been reviewed: unimolecular initiations 1 by C-C bond scission of norbornane, fate of the generated diradicals, reactions of transfer and propagation of norbornyl radicals, reactions of benzene and cross-coupling reactions