3,901 research outputs found

    Persistence to high temperatures of interlayer coherence in an organic superconductor

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    The interlayer magnetoresistance ρzz\rho_{zz} of the organic metal \cuscn is studied in fields of up to 45 T and at temperatures TT from 0.5 K to 30 K. The peak in ρzz\rho_{zz} seen in in-plane fields, a definitive signature of interlayer coherence, remains to TTs exceeding the Anderson criterion for incoherent transport by a factor 30\sim 30. Angle-dependent magnetoresistance oscillations are modeled using an approach based on field-induced quasiparticle paths on a 3D Fermi surface, to yield the TT dependence of the scattering rate τ1\tau^{-1}. The results suggest that τ1\tau^{-1} does not vary strongly over the Fermi surface, and that it has a T2T^2 dependence due to electron-electron scattering

    A statistical model for the intrinsically broad superconducting to normal transition in quasi-two-dimensional crystalline organic metals

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    Although quasi-two-dimensional organic superconductors such as κ\kappa-(BEDT-TTF)2_2Cu(NCS)2_2 seem to be very clean systems, with apparent quasiparticle mean-free paths of several thousand \AA, the superconducting transition is intrinsically broad (e.g 1\sim 1 K wide for Tc10T_c \approx 10 K). We propose that this is due to the extreme anisotropy of these materials, which greatly exacerbates the statistical effects of spatial variations in the potential experienced by the quasiparticles. Using a statistical model, we are able to account for the experimental observations. A parameter xˉ\bar{x}, which characterises the spatial potential variations, may be derived from Shubnikov-de Haas oscillation experiments. Using this value, we are able to predict a transition width which is in good agreement with that observed in MHz penetration-depth measurements on the same sample.Comment: 8 pages, 2 figures, submitted to J. Phys. Condens. Matte

    Comparison of the Fermi-surface topologies of kappa-(BEDT-TTF)_2 Cu(NCS)_2 and its deuterated analogue

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    We have measured details of the quasi one-dimensional Fermi-surface sections in the organic superconductor kappa-(BEDT-TTF)_2 Cu(NCS)_2 and its deuterated analogue using angle-dependent millimetre-wave techniques. There are significant differences in the corrugations of the Fermi surfaces in the deuterated and undeuterated salts. We suggest that this is important in understanding the inverse isotope effect, where the superconducting transition temperature rises on deuteration. The data support models for superconductivity which invoke electron-electron interactions depending on the topological properties of the Fermi surface

    Cyclotron resonance of the quasi-two-dimensional electron gas at Hg1-xCdxTe grain boundaries

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    The magnetotransmission of a p-type Hg0.766Cd0.234Te bicrystal containing a single grain boundary with an inversion layer has been investigated in the submillimetre wavelength range. For the first time the cyclotron resonance lines belonging to the various electric subbands of a quasi-two-dimensional carrier system at a grain boundary could be detected. The measured cyclotron masses and the subband densities determined from Shubnikov-de Haas experiments are compared with theoretical predictions and it is found that the data can be explained very well within the framework of a triangular well approximation model which allows for non-parabolic effects

    Opening of DNA double strands by helicases. Active versus passive opening

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    Helicase opening of double-stranded nucleic acids may be "active" (the helicase directly destabilizes the dsNA to promote opening) or "passive" (the helicase binds ssNA available due to a thermal fluctuation which opens part of the dsNA). We describe helicase opening of dsNA, based on helicases which bind single NA strands and move towards the double-stranded region, using a discrete ``hopping'' model. The interaction between the helicase and the junction where the double strand opens is characterized by an interaction potential. The form of the potential determines whether the opening is active or passive. We calculate the rate of passive opening for the helicase PcrA, and show that the rate increases when the opening is active. Finally, we examine how to choose the interaction potential to optimize the rate of strand separation. One important result is our finding that active opening can increase the unwinding rate by 7 fold compared to passive opening.Comment: 13 pages, 3 figure

    Landau quantization effects in the charge-density-wave system (Per)2M_2M(mnt)2_2 (where M=M=Au and Pt)

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    A finite transfer integral tat_a orthogonal to the conducting chains of a highly one-dimensional metal gives rise to empty and filled bands that simulate an indirect-gap semiconductor upon formation of a commensurate charge-density-wave (CDW). In contrast to semiconductors such as Ge and Si with bandgaps 1\sim 1 eV, the CDW system possesses an indirect gap with a greatly reduced energy scale, enabling moderate laboratory magnetic fields to have a major effect. The consequent variation of the thermodynamic gap with magnetic field due to Zeeman splitting and Landau quantization enables the electronic bandstructure parameters (transfer integrals, Fermi velocity) to be determined accurately. These parameters reveal the orbital quantization limit to be reached at 20\sim 20 T in (Per)2M_2M(mnt)2_2 salts, making them highly unlikely candidates for a recently-proposed cascade of field-induced charge-density wave states

    Quantifying the Effects of Hyperthermal Atomic Oxygen and Thermal Fatigue Environments on Carbon Nanotube Sheets for Space-Based Applications

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    The effects of atomic oxygen and thermal fatigue on two different types of carbon nanotube sheets were studied. One set was treated with nitric acid, while the other set was left untreated. Monotonic tensile tests were performed before and after exposure to determine the effects of either exposure type on the sheets’ mechanical properties. Electrical conductivity and electromagnetic interference measurements were recorded to determine the effects of AO-exposure and thermal cycling on the sheets’ electrical properties. Neither exposure type affected the sheets’ specific strengths. Both exposure types increased the sheets’ specific stiffnesses and decreased the sheets’ strains at failure. The electrical conductivity of both sheets decreased due to the different exposure types, while the EMI shielding effectiveness was unaffected. Scanning electron microscopy was used to observe any changes in the sheets’ surface morphologies, while energy-dispersive X-ray spectroscopy was used to determine the effects of AO on the sheets’ chemical makeup

    d0 Perovskite-Semiconductor Electronic Structure

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    We address the low-energy effective Hamiltonian of electron doped d0 perovskite semiconductors in cubic and tetragonal phases using the k*p method. The Hamiltonian depends on the spin-orbit interaction strength, on the temperature-dependent tetragonal distortion, and on a set of effective-mass parameters whose number is determined by the symmetry of the crystal. We explain how these parameters can be extracted from angle resolved photo-emission, Raman spectroscopy, and magneto-transport measurements and estimate their values in SrTiO3
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