Synthesis, Characterization, and Photochemical Properties of a New Square Mn(I)-Ru(II) Complex Using Pyrazine as Bridge Ligand

The photochemical properties of the complexes cis,fac-[Ru(phen)(2)(pz)(2)-Mn(CO)(3)Br](2)(4+) (I), cis-[Ru(phen)(2)(pz)(2)](2+) (II), and fac-Mn(CO)(3)(pz)(2)Br (III) where phen is phenanthroline and pz is pyrazine in acetonitrile solution are reported. the three complexes were characterized using H-1 NMR, UV-vis and FTIR spectroscopy and electrochemical (cyclic voltammetry and spectroelectrochemical) techniques. the complexes show intense absorption in the visible region assigned to the population of MLCT excited states. the absorption spectrum of I is the sum of the spectra of the mononuclear species II and III, and the two oxidation potentials at +1.10 and +1.56V versus Ag/AGCl observed in I are ascribed to the different coordination environments of metal centers. the photolysis in the acetonitrile solution resulted in the pz dissociation to give the monoacetonitrile complexes for I, II, and III, respectively.Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, BrazilFundacao Univ Fed Grande Dourados, Fac Ciencias Exatas & Tecnol, BR-79804970 Dourados, MS, BrazilUniversidade Federal de São Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Ciencias Farmaceut, BR-14040901 Ribeirao Preto, SP, BrazilUniversidade Federal de São Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Ciencias Farmaceut, BR-14040901 Ribeirao Preto, SP, BrazilWeb of Scienc