TiO2/PDMS nanocomposites for use on self-cleaning surfaces

AbstractIn this study, polydimethylsiloxane (PDMS)/TiO2 nanocomposite was processed by the spray method. TiO2 nanoparticles were synthesized by microwave-assisted hydrothermal method. Varying the proportion of nanoparticles in 0%, 0.5% and 1% by weight, commercial TiO2 (P25) was used for comparison purposes. The photocatalytic activity of nanocomposites impregnated with methylene blue was assessed by means of UV–visible spectroscopy. Changes in contact angle were analyzed before and after UV degradation tests. The effect of ultraviolet radiation on the chemical structure of the PDMS matrix was evaluated by Fourier transform infrared spectroscopy (FTIR). The results indicated that the addition of TiO2 nanoparticles in PDMS provides good photocatalytic properties in the decomposition of methylene blue, which is an important characteristic for the development of coatings for self-cleaning. For comparison purposes, commercial P25 was also used to investigate the photocatalytic activity

Thermal performance of a solar hybrid dryer for Conilon coffee (Coffea canephora)

The study was aimed at design and development of an energy efficient hybrid solar dryer suitable for drying of organic Conilon coffee placed in the town of Seropédica, Rio de Janeiro, Brazil. The energy efficiency and the drying efficiency were the evaluation criteria for thermal performance of the hybrid solar dryer during the coffee drying. Temperature and relative humidity (RH) of the drying and ambient air, solar radiation intensity and coffee weight loss were monitored during the drying process. The process occurred over six consecutive days; the drying time was from 07:00 to 17:00 h, totalling 120 h of operation with an intermittent period (at night) of 14 h. During intermittence, the exhaust system kept off and solar collector and drying chamber sealed. The effective drying period took 60 h, with temperature and RH, respectively, of 38.3 °C and 60.6% outlet of the solar collector, 32.7 °C and 72.2% outlet drying chamber and 27.8 °C and 74.5% ambient air. The maximum temperature in the solar collector and drying chamber reached 54 and 47.7 °C, respectively, with an ambient air temperature of 32 °C at 12:00 h. These values showing temperature increase 22.2 °C in solar collector and 10 ºC drying chamber. The mean variation for the reduction in RH between the drying air inside the solar collector and the ambient air was 28%, while in the chamber obtained in a range of 10.5% at 13:00 h. The solar collector and dryer chamber efficiency were 29.1 and 40.8%, respectively, while the overall dryer efficiency 39.7%