702 research outputs found

    Reporting suicide: the experts in debate

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    Polis has hosted a seminar in partnership with the Press Complaints Commission with a panel of experts who addressed concerns associated with suicide reporting in the media. The recent death of 25 youths by suicide in and around the town of Bridgend has highlighted the need for such a deliberate discussion. Press Gazette’s report of the event here. The PCC’s report here

    Reporting suicide in the media

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    Anna Siegel's report about the the POLIS and PCC event, 'Reporting Sucide in the Media'

    Reduced complexity models for water management and anode purge scheduling in DEA operation of PEMFCs

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    In this work, the dynamic behavior of Fuel Cell operation under Dead-Ended Anode conditions is shown. A DEA can be fed with dry hydrogen, since water crossing through the membrane is sufficient to humidify the fuel. The reduced requirements for inlet humidification yield a system with lower cost and weight compared to FCs with flow-through or recirculated anodes. The accumulation of water and nitrogen in the anode channel is first observed near the outlet. A stratified pattern develops in the channel where a hydrogen-rich area sits above a depleted region and is stabilized by the effect of gravity. A model is presented which describes the dynamic evolution of a blanketing N2 front in the anode channel and a hydrogen starved region. Understanding, modeling, and predicting the front evolution can reduce the H2 wasted during purges, avoid over drying the membrane, and mitigate degradation associated with hydrogen starved areas

    Experimental validation of equilibria in fuel cells with dead-ended anodes

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    This paper investigates the nitrogen blanketing front during the dead-ended anode (DEA) operation of a PEM fuel cell. Surprisingly the dynamic evolution of nitrogen and water accumulation in the dead-ended anode (DEA) of a PEM fuel cell arrives to a steady-state suggesting the existence of equilibrium behavior. We use a multi-component model of the two-phase one-dimensional (along-the-channel) system behavior to analyze and exploit this phenomenon. Specifically, the model is first verified with experimental observations, and then utilized for showing the evolution towards equilibrium. The full order model is reduced to a second-order ordinary differential equation (ODE) with one state, which can be used to predict and amalyse the surprising but experimentally observed steady state DEA behavior

    Nitrogen front evolution in purged polymer electrolyte membrane fuel cell with dead-ended anode

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    In this paper, we model and experimentally verify the evolution of liquid water and nitrogen fronts along the length of the anode channel in a proton exchange membrane fuel cell operating with a dead-ended anode that is fed by dry hydrogen. The accumulation of inert nitrogen and liquid water in the anode causes a voltage drop, which is recoverable by purging the anode. Experiments were designed to clarify the effect of N-2 blanketing, water plugging of the channels, and flooding of the gas diffusion layer. The observation of each phenomenon is facilitated by simultaneous gas chromatography measurements on samples extracted from the anode channel to measure the nitrogen content and neutron imaging to measure the liquid water distribution. A model of the accumulation is presented, which describes the dynamic evolution of a N-2 blanketing front in the anode channel leading to the development of a hydrogen starved region. The prediction of the voltage drop between purge cycles during nonwater plugging channel conditions is shown. The model is capable of describing both the two-sloped behavior of the voltage decay and the time at which the steeper slope begins by capturing the effect of H-2 concentration loss and the area of the H-2 starved region along the anode channel

    Measurement of Liquid Water Accumulation in a Proton Exchange Membrane Fuel Cell with Dead-Ended Anode

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    The operation and accumulation of liquid water within the cell structure of a polymer electrolyte membrane fuel cell (PEMFC) with a dead-ended anode is observed using neutron imaging. The measurements are performed on a single cell with 53 square centimeter active area, Nafion 111-IP membrane and carbon cloth Gas Diffusion Layer (GDL). Even though dry hydrogen is supplied to the anode via pressure regulation, accumulation of liquid water in the anode gas distribution channels was observed for all current densities up to 566 mA cm-2 and 100% cathode humidification. The accumulation of liquid water in the anode channels is followed by a significant voltage drop even if there is no buildup of water in the cathode channels. Anode purges and cathode surges are also used as a diagnostic tool for differentiating between anode and cathode water flooding. The rate of accumulation of anode liquid water, and its impact on the rate of cell voltage drop is shown for a range of temperature, current density, cathode relative humidity and air stoichiometric conditions. Neutron imaging of the water while operating the fuel cell under dead-ended anode conditions offers the opportunity to observe water dynamics and measured cell voltage during large and repeatable transients
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