Methane bursts as a trigger for intermittent lake-forming climates on post-Noachian Mars

Lakes existed on Mars later than 3.6 billion years ago, according to sedimentary evidence for deltaic deposition. The observed fluviolacustrine deposits suggest that individual lake-forming climates persisted for at least several thousand years (assuming dilute flow). But the lake watersheds’ little-weathered soils indicate a largely dry climate history, with intermittent runoff events. Here we show that these observational constraints, although inconsistent with many previously proposed triggers for lake-forming climates, are consistent with a methane burst scenario. In this scenario, chaotic transitions in mean obliquity drive latitudinal shifts in temperature and ice loading that destabilize methane clathrate. Using numerical simulations, we find that outgassed methane can build up to atmospheric levels sufficient for lake-forming climates, if methane clathrate initially occupies more than 4% of the total volume in which it is thermodynamically stable. Such occupancy fractions are consistent with methane production by water–rock reactions due to hydrothermal circulation on early Mars. We further estimate that photochemical destruction of atmospheric methane curtails the duration of individual lake-forming climates to less than a million years, consistent with observations. We conclude that methane bursts represent a potential pathway for intermittent excursions to a warm, wet climate state on early Mars

Geologic overview of the Mars Science Laboratory rover mission at the Kimberley, Gale crater, Mars

The Mars Science Laboratory (MSL) Curiosity rover completed a detailed investigation at the Kimberley waypoint within Gale crater from sols 571–634 using its full science instrument payload. From orbital images examined early in the Curiosity mission, the Kimberley region had been identified as a high-priority science target based on its clear stratigraphic relationships in a layered sedimentary sequence that had been exposed by differential erosion. Observations of the stratigraphic sequence at the Kimberley made by Curiosity are consistent with deposition in a prograding, fluvio-deltaic system during the late Noachian to early Hesperian, prior to the existence of most of Mount Sharp. Geochemical and mineralogic analyses suggest that sediment deposition likely took place under cold conditions with relatively low water-to-rock ratios. Based on elevated K2O abundances throughout the Kimberley formation, an alkali feldspar protolith is likely one of several igneous sources from which the sediments were derived. After deposition, the rocks underwent multiple episodes of diagenetic alteration with different aqueous chemistries and redox conditions, as evidenced by the presence of Ca-sulfate veins, Mn-oxide fracture fills, and erosion-resistant nodules. More recently, the Kimberley has been subject to significant aeolian abrasion and removal of sediments to create modern topography that slopes away from Mount Sharp, a process that has continued to the present day

Redox stratification of an ancient lake in Gale crater, Mars

Gale crater on Mars was once a lake fed by rivers and groundwater. Hurowitz et al. analyzed 3.5 years of data from the Curiosity rover’s exploration of Gale crater to determine the chemical conditions in the ancient lake. Close to the surface, there were plenty of oxidizing agents and rocks formed from large, dense grains, whereas the deeper layers had more reducing agents and were formed from finer material. This redox stratification led to very different environments in different layers, which provides evidence for Martian climate change. The results will aid our understanding of where and when Mars was once habitable

Mars Science Laboratory CheMin Data From the Glen Torridon Region and the Significance of Lake-Groundwater Interactions in Interpreting Mineralogy and Sedimentary History

The Glen Torridon (GT) region in Gale crater, Mars is a region with strong clay mineral signatures inferred from orbital spectroscopy. The CheMin X‐ray diffraction (XRD) instrument onboard the Mars Science Laboratory rover, Curiosity, measured some of the highest clay mineral abundances to date within GT, complementing the orbital detections. GT may also be unique because in the XRD patterns of some samples, CheMin identified new phases, including: (a) Fe‐carbonates, and (b) a phase with a novel peak at 9.2 Å. Fe‐carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of Fe‐carbonate. This new phase with a 9.2 Å reflection has never been observed in Gale crater and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account for all of the GT mineralogical, geochemical, and sedimentological constraints. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite‐minnesotaite, as a reasonable candidate. The coexistence of Fe‐carbonate and Fe‐rich clay minerals in the GT samples supports a conceptual model of a lacustrine groundwater mixing environment. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone may have controlled the secondary minerals preserved in sedimentary rocks exposed in GT

Mars Science Laboratory CheMin Data From the Glen Torridon Region and the Significance of Lake-Groundwater Interactions in Interpreting Mineralogy and Sedimentary History

The Glen Torridon (GT) region in Gale crater, Mars is a region with strong clay mineral signatures inferred from orbital spectroscopy. The CheMin X-ray diffraction (XRD) instrument onboard the Mars Science Laboratory rover, Curiosity, measured some of the highest clay mineral abundances to date within GT, complementing the orbital detections. GT may also be unique because in the XRD patterns of some samples, CheMin identified new phases, including: (a) Fe-carbonates, and (b) a phase with a novel peak at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of Fe-carbonate. This new phase with a 9.2 Å reflection has never been observed in Gale crater and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account for all of the GT mineralogical, geochemical, and sedimentological constraints. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite, as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples supports a conceptual model of a lacustrine groundwater mixing environment. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone may have controlled the secondary minerals preserved in sedimentary rocks exposed in GT

An olivine cumulate outcrop on the floor of Jezero crater, Mars.

The geological units on the floor of Jezero crater, Mars, are part of a wider regional stratigraphy of olivine-rich rocks, which extends well beyond the crater. We investigated the petrology of olivine and carbonate-bearing rocks of the Séítah formation in the floor of Jezero. Using multispectral images and x-ray fluorescence data, acquired by the Perseverance rover, we performed a petrographic analysis of the Bastide and Brac outcrops within this unit. We found that these outcrops are composed of igneous rock, moderately altered by aqueous fluid. The igneous rocks are mainly made of coarse-grained olivine, similar to some martian meteorites. We interpret them as an olivine cumulate, formed by settling and enrichment of olivine through multistage cooling of a thick magma body