Chronometry and formation pathways of gypsum using Electron Spin Resonance and Fourier Transform Infrared Spectroscopy

Gypsum is an authigenic precipitate that forms under periods of accentuated aridity and occurs widely in arid zones. However its use in quantitative paleoclimatology has been limited due to the absence of a method to determine the timing of its formation. We present here the results of a feasibility study that demonstrates that the timing of the formation event of gypsum can be estimated using Electron Spin Resonance (ESR) analysis. We used well documented samples from White Sands in New Mexico, USA, the Thar Desert, India and lakes in the Simpson Desert and Mallee Region, Australia and found that ESR ages could be obtained using radiation sensitive SO4-, SO3- radicals and a photobleachable signal O3-. ESR signals were consistent with control ages based on contextual information. These suggest that the dating signals (SO4-, SO3-) are stable over time scales >100 ka. We propose that this stability of the SO4- signals over geological time scales arises due to hydrogen bonding between the water proton and the SO4- radical and that the suitability of these radiation-induced radicals comes from their being a part of the host matrix. Further, ESR along with Fourier Transform Infrared (FT-IR) Spectroscopy methods additionally inform on the geochemical pathways for gypsum formation and help elucidate complex formation processes even in samples that appeared unambiguous gypsum precipitates. Thus, the presence of Hannebachite (CaSO3.1/2H2O) and Mn2+ in Thar and Australian samples suggested a reducing environment such that low valence sulfur reacted with CaCO3 to form hannebachite and eventually gypsum. The presence of sulfur, partially as sulfite in Thar gypsum samples suggested that redox cycles were mediated by microbial activity. Absence of these features in White Sands samples suggested oxic conditions during gypsum precipitation

Estimation of cooling rates during close-coupled gas atomization using secondary dendrite arm spacing measurement

Al-4 wt pct Cu alloy has been gas atomized using a commercial close-coupled gas-atomization system. The resulting metal powders have been sieved into six size fractions, and the SDAS has been determined using electron microscopy. Cooling rates for the powders have been estimated using a range of published conversion factors for Al-Cu alloy, with reasonable agreement being found between sources. We find that cooling rates are very low relative to those often quoted for gas-atomized powders, of the order of 10 K s for sub-38 μm powders. We believe that a number of numerical studies of gas atomization have overestimated the cooling rate during solidification, probably as a consequence of overestimating the differential velocity between the gas and the particles. From the cooling rates measured in the current study, we estimate that such velocities are unlikely to exceed 20 m s

Concentration Techniques: Exploring Various Dimensions

Concentration is one of the most vital aspectsin shaping the effectiveness of learning. It is the application of mind on a subject of any nature upon which we wish to have complete control and direct it the way we wish to. The fundamental question is how we shape our mind and train it in a systematic manner to enhance the power of concentration. If we look at the available books on the subject and different other resource materials on the techniques of developing it, we see that systematic research on scheming the level of concentration is far from satisfactory.But at the same time, great knowledge of Yoga, discovered and practised in ancient Bharata gives not onlya ray of hope but complete assurance in developing the highest level of concentration. The practice of Yoga as a means havebeenstudied along with the effect of an external factor that plays its role inour concentration.In present time, anxiety, worry, and mental tensions have become nearly unavoidable companions of students in general that result into negative impact. Thelack of concentration affectsperformance adversely; Ithas a lot to do inacquiring knowledge or expertise in any given field.Present paper focuses on the various ways and techniques which are essential inimproving concentration level</jats:p