Raman scattering gain in DOO-PPV films

Optical Science, Engineering and Instrumentation '97, 1997, San Diego, CA, United StatesMaxim N. Shkunov, Werner Gellermann, Akihiko Fujii, Katsumi Yoshino, and Z. Valy Vardeny "Raman scattering gain in DOO-PPV films", Proc. SPIE 3145, Optical Probes of Conjugated Polymers, (1 December 1997). DOI: https://doi.org/10.1117/12.29552

Laser action in conducting polymers

We discuss both cooperative radiation and stimulated emission and consider their role in spectral narrowing of luminescent conducting polymers. We argue that cooperative radiation is favored in films with poor optical confinement. On the other hand, directional stimulated emission can be observed in dilute solution and thin films with superior optical confinement. Spectral narrowing in this case can be achieved by increasing either the excitation length or excitation intensity. The optical gain and loss coefficients are measured. Narrow line (approximately 1.5 cm-1) laser emission is observed in cylindrical microcavities formed by thin polymer films coated around glass fibers in the red and green spectral ranges. The cavity quality factors of these plastic lasers are mainly determined by selfabsorption and estimated to be about 5000.Optical Scnce, Engineering and Instrumentation '97, 1997, San Diego, CA, United StatesSergey V. Frolov, Maxim N. Shkunov, Z. Valy Vardeny, Masanori Ozaki, and Katsumi Yoshino "Laser action in conducting polymers", Proc. SPIE 3145, Optical Probes of Conjugated Polymers, (1 December 1997). DOI: https://doi.org/10.1117/12.29552

Studies of Raman scattering in novel disubstituted acetylene polymers

We have studied resonant and non-resonant Raman scattering spectra in thin films of novel disubstituted acetylene polymers such as poly(1-ethyl-2-phenylacetylene) (PEtPA), poly(1-n-hexyl-2-phenylacetylene) (PHxPA) and poly(1-phenyl- 2-p-n-butylphenylacetylene) (PDPA-nBu), which possess high photoluminescence (PL) quantum efficiency. We found that the Raman scattering frequency dispersion is smaller in disubstituted acetylene polymers than in other acetylene polymers, in agreement with many other strongly luminescent polymers. Assuming the model of short polyene conjugation length in these acetylene polymers, we can obtain the conjugation length (N) for each polymer from the respective phonon frequency of the carbon-carbon double bond; we obtained N equals 7 for PDPA-nBu, and N equals 5 or 6 for PHxPA and PEtPA. The related energies of 11Bu and 21Ag can be estimated from these N and are in good agreement with the respective absorption and PL spectra of the various disubstituted polymers.Optical Science, Engineering and Instrumentation '97, 1997, San Diego, CA, United StatesAkihiko Fujii, Maxim N. Shkunov, Z. Valy Vardeny, Kazuya Tada, Katsumi Yoshino, Masahiro Teraguchi, and Toshio Masuda "Studies of Raman scattering in novel disubstituted acetylene polymers", Proc. SPIE 3145, Optical Probes of Conjugated Polymers, (1 December 1997). DOI: https://doi.org/10.1117/12.29554

Spray Printing of Organic Semiconducting Single Crystals

Single-crystal semiconductors have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt using time-consuming and energy-intensive processes. Organic semiconductor single crystals, however, can be grown using solution-based methods at room temperature in air, opening up the possibility of large-scale production of inexpensive electronics targeting applications ranging from field-effect transistors and light-emitting diodes to medical X-ray detectors. Here we demonstrate a low-cost, scalable spray-printing process to fabricate high-quality organic single crystals, based on various semiconducting small molecules on virtually any substrate by combining the advantages of antisolvent crystallization and solution shearing. The crystals’ size, shape and orientation are controlled by the sheer force generated by the spray droplets’ impact onto the antisolvent’s surface. This method demonstrates the feasibility of a spray-on single-crystal organic electronics

Stimulated emission and lasing in π-conjugated polymer films, microstructures and opal photonic crystals

SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, 1999, Denver, CO, United StatesZ. Valy Vardeny, Sergey V. Frolov, Douglas Chinn, Maxim N. Shkunov, Werner Gellermann, Katsumi Yoshino, Akihiko Fujii, Richard V. Gregory, Ray H. Baughman, and Anvar A. Zakhidov "Stimulated emission and lasing in π-conjugated polymer films, microstructures, and opal photonic crystals", Proc. SPIE 3797, Organic Light-Emitting Materials and Devices III, (17 December 1999). DOI: https://doi.org/10.1117/12.37269