The Relationship between Power, Sense of Power, and Cognitive Flexibility: An Analysis of Parallel Mediating Effects Based on Reward and Punishment Sensitivity

This study utilized a sample of 2052 participants from government and enterprise sectors to explore the distinct effects of power and sense of power on cognitive flexibility. It also delves into how the three dimensions of reward sensitivity and the comprehensive measure of punishment sensitivity mediate this relationship. The key findings are as follows: (1) There is no significant direct correlation between power and sense of power. (2) Both power and sense of power are substantial positive predictors of cognitive flexibility, with middle- and upper-level employees demonstrating significantly greater cognitive flexibility than their lower-level counterparts, and sense of power having a more pronounced positive influence than objective power. (3) Drive and fun-seeking mediate the relationship between sense of power and cognitive flexibility, yet only when sense of power is the independent variable. (4) No mediating effects are observed for the dimensions of reward sensitivity or punishment sensitivity when power is the independent variable. Exploring reward and punishment sensitivity in the context of power’s influence on cognitive flexibility in real organizational settings is of paramount importance. This enhances our understanding of the intricate ways in which power dynamics shape individual behaviors and cognition across diverse cultural landscapes and provides actionable insights for refining organizational management and leadership strategies

Influence of Energy State of Montmorillonite Interlayer Cations on Organic Intercalation

It is well known that the intercalation of montmorillonite (Mt) with organic cations is a fast process. During the intercalation, the interaction between the original cations and the structure layer of Mt keeps changing, and the basal spacing of Mt keeps increasing until an organic environment has been built in the interlayer. Many properties of Mt also change during the intercalation, such as hydrophobic or hydrophilic property and thermal stability. In this research, the impact of intercalation on the properties of Mt was studied by investigating the change in basal spacing and energy that coordinates the interlayer cations during the intercalation of Mt with organic cations. The interaction between interlayer cations and the layers in the Mt structure and the change in the system energy were obtained by using molecular dynamics simulation. All the experiment and calculation results provide a theoretical proof in organic intercalation mechanism

Modification of a single-molecule AFM probe with highly defined surface functionality

Single-molecule force spectroscopy with an atomic force microscope has been widely used to study inter- and intramolecular interactions. To obtain data consistent with single molecular events, a well-defined method is critical to limit the number of molecules at the apex of an AFM probe to one or to a few. In this paper, we demonstrate an easy method for single-molecule probe modification by using the Cu-catalyzed alkyne–azide cycloaddition reaction. Excess terminal alkynes were covalently attached to the probe, and a bi-functional molecule containing an azide at one end and a carboxylic acid at the other was dissolved in the reaction solution. By simply contacting the probe and the Cu substrate, controlled carboxylation on the probe apex could be achieved, since the ‘click’ reaction requires the co-exist of alkyne, azide and Cu(I). The finite contact area would result in a highly defined surface functionality of the probe down to single molecule level with high reproducibility

Modification of a single-molecule AFM probe with highly defined surface functionality

Single-molecule force spectroscopy with an atomic force microscope has been widely used to study inter- and intramolecular interactions. To obtain data consistent with single molecular events, a well-defined method is critical to limit the number of molecules at the apex of an AFM probe to one or to a few. In this paper, we demonstrate an easy method for single-molecule probe modification by using the Cu-catalyzed alkyne–azide cycloaddition reaction. Excess terminal alkynes were covalently attached to the probe, and a bi-functional molecule containing an azide at one end and a carboxylic acid at the other was dissolved in the reaction solution. By simply contacting the probe and the Cu substrate, controlled carboxylation on the probe apex could be achieved, since the ‘click’ reaction requires the co-exist of alkyne, azide and Cu(I). The finite contact area would result in a highly defined surface functionality of the probe down to single molecule level with high reproducibility

Evidence of Splitting 1,2,3-Triazole into an Alkyne and Azide by Low Mechanical Force in the Presence of Other Covalent Bonds

The cycloaddition reaction of an alkyne and azide to form a 1,2,3-triazole is widely used in many areas. However, the stability of the triazole moiety under mechanical stress is unclear. To see if a triazole could be selectively split into an alkyne and azide in the presence of other typical covalent bonds, a mica surface functionalized with a molecule containing a triazole moiety in the middle and an activated ester at the end was prepared. An atomic force microscope (AFM) tip with amino groups on its surface was ramped over the mica surface at predefined locations, which could temporarily link the tip to the surface through amide bond formation. During retraction, the triazole or another bond in the linkage broke, and a force was recorded. The forces varied widely at different ramps from close to 0 pN to 860 pN due to nonspecific adhesions and to the inherent inconsistency of single bond rupture. If some of the forces were from triazole cycloreversion, there would be alkynes at the predefined ramping locations. The surface was reacted with an azide carboxylic acid followed by labeling with amino Au nanoparticles (AuNPs). AFM imaging revealed AuNPs at the predicted locations, which provided evidence that under certain conditions triazole could be split selectively in the presence of other bonds at forces below 860 pN

Superior Clone Selection in a <i>Eucalyptus</i> Trial Using Forest Phenotyping Technology via UAV-Based DAP Point Clouds and Multispectral Images

The quantitative, accurate and efficient acquisition of tree phenotypes is the basis for forest “gene-phenotype-environment” studies. It also offers significant support for clarifying the genetic control mechanisms of tree traits. The application of unmanned aerial vehicle (UAV) remote sensing technology to the collection of phenotypic traits at an individual tree level quantitatively analyses tree phenology and directionally evaluates tree growth, as well as accelerating the process of forest genetics and breeding. In this study, with the help of high-resolution, high-overlap, multispectral images obtained by an UAV, combined with digital elevation models (DEMs) extracted from point clouds acquired by a backpack LiDAR, a high-throughput tree structure and spectral phenotypic traits extraction and a genetic selection were conducted in a trial of Eucalyptus clones in the State-owned Dongmen Forest Farm in the Guangxi Zhuang Autonomous Region. Firstly, we validated the accuracy of extracting the phenotypic parameters of individual tree growth based on aerial stereo photogrammetry point clouds. Secondly, on this basis, the repeatability of the tree growth traits and vegetation indices (VIs), the genetic correlation coefficients between the traits were calculated. Finally, the eucalypt clones were ranked by integrating a selection index of traits, and the superior genotypes were selected and their genetic gain predicted. The results showed a high accuracy of the tree height (H) extracted from the digital aerial photogrammetry (DAP) point cloud based on UAV images (R2 = 0.91, and RMSE = 0.56 m), and the accuracy of estimating the diameter at breast height (DBH) was R2 = 0.71, and RMSE = 0.75 cm. All the extracted traits were significantly different within the tree species and among the clones. Except for the crown width (CW), the clonal repeatability (Rc) of the traits were all above 0.9, and the individual repeatability values (Ri) were all above 0.5. The genetic correlation coefficient between the tree growth traits and VIs fluctuated from 0.3 to 0.5, while the best clones were EA14-15, EA14-09, EC184, and EC183 when the selection proportion was 10%. The purpose of this study was to construct a technical framework for phenotypic traits extraction and genetic analysis of trees based on unmanned aerial stereo photography point clouds and high-resolution multispectral images, while also exploring the application potential of this approach in the selective breeding of eucalypt clones