1,875 research outputs found
Chemical evolution in the early phases of massive star formation. I
Understanding the chemical evolution of young (high-mass) star-forming
regions is a central topic in star formation research. Chemistry is employed as
a unique tool 1) to investigate the underlying physical processes and 2) to
characterize the evolution of the chemical composition. We observed a sample of
59 high-mass star-forming regions at different evolutionary stages varying from
the early starless phase of infrared dark clouds to high-mass protostellar
objects to hot molecular cores and, finally, ultra-compact HII regions at 1mm
and 3mm with the IRAM 30m telescope. We determined their large-scale chemical
abundances and found that the chemical composition evolves along with the
evolutionary stages. On average, the molecular abundances increase with time.
We modeled the chemical evolution, using a 1D physical model where density and
temperature vary from stage to stage coupled with an advanced gas-grain
chemical model and derived the best-fit chi^2 values of all relevant
parameters. A satisfying overall agreement between observed and modeled column
densities for most of the molecules was obtained. With the best-fit model we
also derived a chemical age for each stage, which gives the timescales for the
transformation between two consecutive stages. The best-fit chemical ages are
~10,000 years for the IRDC stage, ~60,000 years for the HMPO stage, ~40,000
years for the HMC stage, and ~10,000 years for the UCHII stage. The total
chemical timescale for the entire evolutionary sequence of the high-mass star
formation process is on the order of 10^5 years, which is consistent with
theoretical estimates. Furthermore, based on the approach of a multiple-line
survey of unresolved data, we were able to constrain an intuitive and
reasonable physical and chemical model. The results of this study can be used
as chemical templates for the different evolutionary stages in high-mass star
formation.Comment: 31 pages, 11 figures, 21 tables, accepted by A&A; typos adde
Correlates of quality of life in overweight or obese breast cancer survivors at enrollment into a weight loss trial
OBJECTIVE: To examine the correlates of the physical and psychosocial domains of quality of life (QOL) in a cohort of breast cancer survivors participating in a weight loss intervention trial. Available data included information on weight and physical activity, as well as demographic and medical characteristics. METHODS: Correlates of QOL and psychosocial functioning were examined in 692 overweight/obese breast cancer survivors at entry into a weight loss trial. QOL was explored with three measures: Short-form 36 (SF-36); Impact of Cancer Scale (IOCv2); and the Breast Cancer Prevention Trial (BCPT) Symptom Scales. Bivariate and multivariate analyses were used to identify correlates and associations adjusted for other characteristics. RESULTS: In multivariate analysis, younger age was associated with higher negative impact scores (p<0.01). Hispanic, African-American and Asian women had higher IOC positive impact scores compared to white non-Hispanic women (p<0.01). Higher education was associated with lower scores on mental QOL and the IOC positive impact scale (p<0.01). BMI was not independently associated with QOL measures. Physical activity was directly associated with physical and mental QOL and IOC positive impact, and inversely related to IOC negative impact and BCPT symptom scales. CONCLUSIONS: QOL measures in breast cancer survivors are differentially associated with demographic and other characteristics. When adjusted for these characteristics, degree of adiposity among overweight/obese women does not appear to be independently associated with QOL. Among overweight/obese breast cancer survivors, higher level of physical activity is associated with higher QOL across various scales and dimensions
Exciton spectroscopy of hexagonal boron nitride using non-resonant x-ray Raman scattering
We report non-resonant x-ray Raman scattering (XRS) measurements from
hexagonal boron nitride for transferred momentum from 2 to 9
along directions both in and out of the basal plane. A
symmetry-based argument, together with real-space full multiple scattering
calculations of the projected density of states in the spherical harmonics
basis, reveals that a strong pre-edge feature is a dominantly -type
Frenkel exciton with no other \textit{s}-, \textit{p}-, or \textit{d}-
components. This conclusion is supported by a second, independent calculation
of the \textbf{q}-dependent XRS cross-section based on the Bethe-Salpeter
equation
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