27 research outputs found
Analysis of bis(trifluoromethylsulfonyl)imide-doped paramagnetic graphite intercalation compound using F-19 very fast magic angle spinning nuclear magnetic resonance
F atoms bonding to paramagnetic/conductive graphene layers in accepter-type graphite intercalation compounds (GICs) are analyzed using very fast magic angle spinning nuclear magnetic resonance, which is applied for the first time on F-19 nuclei to investigate paramagnetic materials. In the bis(trifluoromethylsulfonyl)imide(TFSI)-doped GIC, C-F bonds between fluorine atoms and graphene layers conform to a weak bonding of F to the graphene sheets. TFSI anions intercalated in the GIC do not show overall molecular motion; even at room temperature only the CF3 groups rotate
Triethylammonium hydrogen chloranilate
In the crystal structure of the title compound (systematic name: triethylammonium 2,5-dichloro-4-hydroxy-3,6-dioxocyclohexa-1,4-dien-1-olate), C6H16N+·C6HCl2O4−, two hydrogen chloranilate anions are connected by a pair of bifurcated O—H...O hydrogen bonds into a dimeric unit. The triethylammonium cations are linked on both sides of the dimer via bifurcated N—H...O hydrogen bonds into a centrosymmetric 2:2 aggregate. The 2:2 aggregates are further linked by intermolecular C—H...O hydrogen bonds
Bis(triethylammonium) chloranilate
In the crystal structure of the title compound [systematic name: bis(triethylammonium) 2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-diolate], 2C6H16N+·C6Cl2O42−, the chloranilate anion lies on an inversion center. The triethylammonium cations are linked on both sides of the anion via bifurcated N—H...(O,O) and weak C—H...O hydrogen bonds to give a centrosymmetric 2:1 aggregate. The 2:1 aggregates are further linked by C—H...O hydrogen bonds into a zigzag chain running along [01-1]