Formation of pseudo[3]rotaxanes containing calix-bis-crowns and secondary ammonium ions and their thermodynamic stabilities in a solution: preorganization by second macrocycle and nonallosteric behavior exhibited by large crown cavities

This paper describes the formation of pseudo[3]rotaxanes containing calix[4]-bis-crowns, exhibiting a 1,3-alternate conformation and large crown cavities, and secondary ammonium ions. The first and second association constants of pseudo[3]rotaxane formation are moderate (K1 = 175, K2 = 100 M−1) and are higher than that of the corresponding pseudo[2]rotaxane (K = 24 M−1), consisting of a calix[4]-mono-crown and the same secondary ammonium ion

Solvent-dependent isomerization of a chromogenic trefoil-shaped salicylaldehyde azine derivative

A chromogenic trefoil-shaped salicylaldehyde azine derivative displayed solvent-dependent isomerism of the C3h and CS symmetries. An azine derivative was prepared from triformylphloroglucinol and 3,5-di-tert-butylsalicylaldehyde hydrazone. The trefoil structure was established using single-crystal X-ray diffraction. UV–vis absorption spectroscopy revealed that solvent-dependent isomerization was accompanied by a bathochromic shift. Isomerization was controlled by adjusting the strength of the intramolecular hydrogen bonding of the azine derivative by solvent polarity. This unusual solvent-dependent isomerization can be utilized for creation azine-based new solvatochromic materials

Proposal for maintenance optimization scheme based on system based code concept

To develop rationalized maintenance plans for nuclear power plants, the characteristics of each plant must be considered. For sodium-cooled fast reactor (SFR) plants, constraints on inspections exist due to the specialty that equipment retaining sodium must be handled, which is one of the important points that must be considered in maintenance rationalization. In this study, we propose a maintenance optimization scheme, which is a design support tool, using risk information to develop a maintenance strategy based on the system based code (SBC) concept. The SBC concept intends to provide a theoretical procedure to optimize the reliability of structure, system and components (SSCs) by administrating every related engineering requirements throughout the life of the SSCs from design to decommissioning. “The American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code, Code Case, N-875, Alternative In-service Inspection Requirements for Liquid-Metal Reactor Passive Components” was developed based on the SBC concept. The basic procedure of the Code Case has also been implemented in “The ASME Boiler and Pressure Vessel Code, Section XI, Division 2,” which provides requirements for Reliability and Integrity Management programs for nuclear power plants, including advanced reactors. The purpose of this study is to establish detailed procedures for the maintenance optimization scheme based on the procedure in Code Case N-875. Furthermore, a quantitative trial evaluation of the core support structure of the next SFR under development in Japan is also performed using the maintenance optimization scheme

Current status of development in the 3D seismic isolation applied to SFRs

A sodium-cooled fast reactor (SFR) considers adopting 3-dimensional seismic isolation devices for withstanding seismic loads not only horizontal but also vertical direction. A seismic isolation device consists of a laminated rubber bearing and horizontal oil dampers for horizontal direction, coned disc springs and vertical oil dampers for vertical direction, respectively. And also, in order to make horizontal and vertical motion independent, sliding elements are adopted. In order to investigate the performance of each component and the feasibility of integrated system for SFR, the experiments such as load-displacement tests, vibrating tests, etc., to each component of seismic isolation devices and seismic response analysis are carried out. As those experimental results, the mechanical characteristics of each component and the devices are grasped, then it is demonstrated that components and devices have expected performances to reduce the seismic loading within the design range. As the analytical results of seismic response, it is indicated that this 3-dimesional seismic isolation device and system can reduce the seismic response on horizontal and vertical simultaneously. Based on the analytical studies and experimental results, the feasibility of newly developed 3-dimensional seismic isolation system is obtained and the prospect of practical application of 3D seismic isolation system for fast reactor is implied in this paper