Observation of Clouds Using the CSIR Transportable LIDAR: A Case Study over Durban, South Africa

The Council for Scientific and Industrial Research (CSIR) transportable Light Detection And Ranging (LIDAR) was used to collect data over Durban (29.9°S, 30.9°E) during 20–23 November 2012. Aerosol measurements have been carried out in the past over Durban; however, no cloud measurements using LIDAR have ever been performed. Therefore, this study further motivates the continuation of LIDAR for atmospheric research over Durban. Low level clouds were observed on 20–22 November 2012 and high level clouds were observed on 23 November 2012. The low level cloud could be classified as stratocumulus clouds, whereas the high level clouds could be classified as cirrus clouds. Low level cloud layers showed high extinction coefficients values ranging between 0.0009 and 0.0044 m−1, whereas low extinction coefficients for high level clouds were observed at values ranging between 0.000001 and 0.000002 m−1. Optical depth showed a high variability for 20 and 21 November 2012. This indicates a change in the composition and/or thickness of the cloud. For 22 and 23 November 2012, almost similar values of optical depth were observed. Cloud-Aerosol LIDAR and Infrared Pathfinder Satellite Observations (CALIPSO) revealed high level clouds while the CSIR LIDAR could not. However, the two instruments complement each other well to describe the cloudy condition

Optical properties of vanadium oxide nanostructures synthesized by laser pyrolysis

M.Sc., Faculty of Science, University of the Witwatersrand, 2011In this work, the primary investigation has been on the development of the laser pyrolysis setup and its optimization for the synthesis of nano-size VO2-x films. More specifically the focus was on making VO2-x depositions using various laser pyrolysis parameters and establish in this way (1) an optimum laser wavelength threshold for the photon induced dissociation of the molecular precursors while the thermal contribution was kept minimal by using low power density (laser energy of 30 W) and (2) the lower threshold for pure thermal contributions by working with wavelengths far from resonance in order to minimize pure photon induced contributions. The interest in synthesizing nano-size VO2-x materials stems from the low metal-insulator transition temperature at near room temperature with opto-electronic and thermo-electronic properties that can be used in specialised applications. A large number of samples were synthesized under various conditions and annealed under argon atmosphere for 17 hours. XRD analysis identified the VO2 (B) and/or β-V2O5 vanadium oxide phases characteristic for certain samples grown under optimum conditions. Raman spectroscopy also confirmed these vanadium oxide phases with bands observed at 175, 228, 261, 303, 422 and 532 cm-1. SEM analysis revealed a plethora of different nanostructures of various size and shapes. The particles have a range of sizes between 55 nm to 185 nm in diameter. The particles showed morphologies which included nano-rods, nanospheres and nano-slabs. An interesting phenomenon was observed on the samples synthesized with high power density, which was observed and reported by Donev iii et al. EDS analysis on the particles was also used to probe the elemental composition of the sample. Optical studies were performed on the samples which showed transitions in the visible and infrared region in accordance with the ones observed in the international literature using different nano-synthesis methods

Formation of tungsten oxide nanostructures by laser pyrolysis: stars, fibres and spheres

In this letter, the production of multi-phase WO3 and WO3-x (where x could vary between 0.1 and 0.3) nanostructures synthesized by CO2-laser pyrolysis technique at varying laser wavelengths (9.22-10.82 mm) and power densities (17-110 W/cm2) is reported. The average spherical particle sizes for the wavelength variation samples ranged between 113 and 560 nm, and the average spherical particle sizes for power density variation samples ranged between 108 and 205 nm. Synthesis of W18O49 (= WO2.72) stars by this method is reported for the first time at a power density and wavelength of 2.2 kW/cm2 and 10.6 μm, respectively. It was found that more concentrated starting precursors result in the growth of hierarchical structures such as stars, whereas dilute starting precursors result in the growth of simpler structures such as wires

Analysis of Wildfires in the Mid and High Latitudes Using a Multi-Dataset Approach: A Case Study in California and Krasnoyarsk Krai

In this study, we investigate the emissions from wildfires in the mid latitude (California) and high latitude (Krasnoyarsk Krai) during the periods of 16–17 August 2020 and 28 July 2019, respectively. Wildfires are unique in themselves as they are driven by various factors such as fuel type, topology, and meteorology. In this study, we analyze whether there are any major variations in the emissions and transport of pollutants between two large wildfire cases in the mid latitude of California and high latitude of Krasnoyarsk Krai. The study is important to understand and characterize the emission regime from biomass burning of different land covers using a mutli-dataset approach. We analyze whether there are any major variations in the emissions and transport of pollutants from these wildfires. For example, the aerosol extinction coefficient profile showed smoke detected at the highest altitude of 9 km in Krasnoyarsk Krai, whereas in California the highest altitude was observed at approximately 6 km. Moreover, large values of black carbon (BC) concentration were observed in Krasnoyarsk Krai approximately 7 µg/m3 compared to the 0.44 µg/m3 observed in California. Areas with an immense dense vegetation are prone to large emissions. The results from this case study suggest that high latitude wildfires emit more pollutants than mid latitude wildfires. However, more studies in the future will be conducted to conclude this observation and finding with certainty

Global Distribution of Clouds over Six Years: A Review Using Multiple Sensors and Reanalysis Data

A six-year global study of cloud distribution and cloud properties obtained from observations of the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO), the Atmospheric Infrared Sounder (AIRS), and the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) data is presented in this study. From the CALIPSO observations, the highest clouds for both daytime and night-time were found in the Inter Tropical Convergence Zone (ITCZ) region. The lowest cloud heights were found towards the poles due to the decrease in the tropopause height. Seasonal studies also revealed a high dominance of clouds in the 70 °S–80 °S (Antarctic) region in the June–July–August (JJA) season and a high dominance of Arctic clouds in the December–January–February (DJF) and September–October–November (SON) seasons. The coldest cloud top temperatures (CTT) were mostly observed over land in the ITCZ and the polar regions, while the warmest CTTs were mostly observed in the mid-latitudes and over the oceans. Regions with CTTs greater than 0 °C experienced less precipitation than regions with CTTs less than 0 °C

Assessing the Responses of Aviation-Related SO2 and NO2 Emissions to COVID-19 Lockdown Regulations in South Africa

Aircraft emit harmful substances, such as carbon dioxide (CO2), water vapour (H2O), nitrogen oxides (NOx), sulphur oxides (SOx), particulates, and other trace compounds. These emissions degrade air quality and can deteriorate human health and negatively impact climate change. Airports are the nucleus of the ground and low-altitude emissions from aircraft during approach, landing, take-off, and taxi. During the global lockdown due to the COVID-19 pandemic, tight restrictions of the movement were imposed, leading to temporary closures of airports globally. In this study, we look at the variability of emissions at two major airports in South Africa, namely the OR Tambo international airport (FAOR) and the Cape Town international airport (FACT). Trend analysis of aircraft movements, i.e., departures and arrivals, showed a sharp decline at the two airports coinciding with the lockdowns to prevent the spread of the COVID-19. Consequently, a decrease in NO2 emissions by 70.45% (12.6 × 10−5 mol/m2) and 64.58% (11.6 × 10−5 mol/m2) at FAOR and FACT were observed, respectively. A noticeable SO2 emission decline was also observed, particularly over FAOR during the lockdown period in South Africa. Overall, this study observed that the global lockdown regulations had a positive impact on the air quality, causing a brief decline in emissions from commercial aviation at the South African major airports

Assessment of the Characteristics of Recent Major Wildfires in the USA, Australia and Brazil in 2018–2019 Using Multi-Source Satellite Products

This study analysed the characteristics of the recent (2018–2019) wildfires that occurred in the USA, Brazil, and Australia using Moderate Resolution Imaging Spectroradiometer (MODIS) active fires (AF), fire radiative power (FRP, MW) and burned area (BA) products. Meteorological and environmental parameters were also analysed. The study found various patterns in the spatial distribution of fires, FRP and BA at the three sites, associated with various vegetation compositions, prevailing meteorological and environmental conditions and anthropogenic activities. We found significant fire clusters along the western and eastern coasts of the USA and Australia, respectively, while vastly distributed clusters were found in Brazil. Across all sites, significant fire intensity was recorded over forest cover (FC) and shrublands (SL), attributed to highly combustible tree crown fuel load characterised by leafy canopies and thin branches. In agreement, BA over FC was the highest in the USA and Australia, while Brazil was dominated by the burning of SL, characteristic of fire-tolerant Cerrado. The relatively lower BA over FC in Brazil can be attributed to fuel availability and proximity to highly flammable cover types such as cropland, SL and grasslands rather than fuel flammability. Overall, this study contributes to a better understanding of wildfires in various regions and the underlying environmental and meteorological causal factors, towards better wildfire disaster management strategies and habitat-specific firefighting

First Observations of Cirrus Clouds Using the UZ Mie Lidar over uMhlathuze City, South Africa

Clouds cover more than two-thirds of the earth’s surface and play a dominant role in the energy and water cycle of our planet. Cirrus clouds are high-level clouds composed mostly of ice crystals and affect the earth’s radiation allocation mainly by absorbing outgoing longwave radiation and by reflecting solar radiation. This study presents the characterization of cirrus clouds observed on 10 and 11 April 2019 using the ground-based University of Zululand (UZ) light detection and ranging (lidar) for the first time. Dense cirrus clouds with an average thickness of ~1.5 km at a height range of 9.5–12 km on 10 and 11 April 2019 were observed by the UZ lidar. The UZ lidar observation on 10 April 2019 agreed with the Cloud–Aerosol Lidar with Orthogonal Polarization (CALIOP) observation

Observations of Emissions and the Influence of Meteorological Conditions during Wildfires: A Case Study in the USA, Brazil, and Australia during the 2018/19 Period

Wildfires can have rapid and long-term effects on air quality, human health, climate change, and the environment. Smoke from large wildfires can travel long distances and have a harmful effect on human health, the environment, and climate in other areas. More recently, in 2018–2019 there have been many large fires. This study focused on the wildfires that occurred in the United States of America (USA), Brazil, and Australia using Cloud-Aerosol Lidar with Orthogonal Polarisation (CALIOP) and a TROPOspheric Monitoring Instrument (TROPOMI). Specifically, we analyzed the spatial-temporal distribution of black carbon (BC) and carbon monoxide (CO) and the vertical distribution of smoke. Based on the results, the highest detection of smoke (~14 km) was observed in Brazil; meanwhile, Australia showed the largest BC column burden of ~1.5 mg/m2. The meteorological conditions were similar for all sites during the fires. Moderate temperatures (between 32 and 42 °C) and relative humidity (30–50%) were observed, which resulted in drier conditions favorable for the burning of fires. However, the number of active fires was different for each site, with Brazil having 13 times more active fires than the USA and five times more than the number of active fires in Australia. However, the high number of active fires did not translate to higher atmospheric constituent emissions. Overall, this work provides a better understanding of wildfire behavior and the role of meteorological conditions in emissions at various sites

First Observations of Cirrus Clouds Using the UZ Mie Lidar over uMhlathuze City, South Africa

Clouds cover more than two-thirds of the earth’s surface and play a dominant role in the energy and water cycle of our planet. Cirrus clouds are high-level clouds composed mostly of ice crystals and affect the earth’s radiation allocation mainly by absorbing outgoing longwave radiation and by reflecting solar radiation. This study presents the characterization of cirrus clouds observed on 10 and 11 April 2019 using the ground-based University of Zululand (UZ) light detection and ranging (lidar) for the first time. Dense cirrus clouds with an average thickness of ~1.5 km at a height range of 9.5–12 km on 10 and 11 April 2019 were observed by the UZ lidar. The UZ lidar observation on 10 April 2019 agreed with the Cloud–Aerosol Lidar with Orthogonal Polarization (CALIOP) observation