1 research outputs found
Fast Photoinduced Large Deformation of Colloidal Spheres from a Novel 4‑arm Azobenzene Compound
A novel
4-arm shaped amphiphilic azobenzene compound was synthesized.
The tetraphenylethylene (TPE) core precursor was prepared and further
modified by azo coupling reaction at the four peripheral groups. Colloidal
spheres could be directly prepared by self-assembly of the prepared
amphiphilic azobenzene compound in selective solvents (THF/H<sub>2</sub>O), which were characterized by using transmission electron microscopy.
The colloid diameters could be controlled by adjusting the initial
compound concentration and water-adding rate in the preparation processes.
By irradiation with visible linearly polarized LED light (450 nm),
fast photoinduced deformation of the colloidal spheres along the polarization
direction was observed. A very large deformation degree (<i>l</i>/<i>d</i> > 4) could be easily obtained