Superconducting properties of Gd-Ba-Cu-O single grains processed from a new, Ba-rich precursor compound

Gd-Ba-Cu-O (GdBCO) single grains have been previously melt-processed successfully in air using a generic Mg-Nd-Ba-Cu-O (Mg-NdBCO) seed crystal. Previous research has revealed that the addition of a small amount of BaO2 to the precursor powders prior to melt processing can suppress the formation of Gd/Ba solid solution, and lead to a significant improvement in superconducting properties of the single grains. Research into the effects of a higher Ba content on single grain growth, however, has been limited by the relatively small grain size in the earlier studies. This has been addressed by developing Ba-rich precursor compounds Gd-163 and Gd-143, fabricated specifically to enable the presence of greater concentrations of Ba during the melt process. In this study, we propose a new processing route for the fabrication of high performance GdBCO single grain bulk superconductors in air by enriching the precursor powder with these new Ba rich compounds. The influence of the addition of the new compounds on the microstructures and superconducting properties of GdBCO single grains is reported

Properties of Mg-doped Nd-Ba-Cu-O generic seed crystals for the top seeded melt growth of (RE)-Ba-Cu-O bulk superconductors

We have recently developed a new generic seed crystal that has been used successfully to fabricate any oriented, single grain (RE)-Ba-Cu-O bulk superconductor by a cold seeding technique. In this paper we report the chemical, structural and microstructural properties of these seed crystals, including the variation of melting point, crystallographic parameters and volume fraction of Mg-rich inclusions in the Nd1 + xBa 2-x(Cu1-yMgy)3Oz matrix as a function of externally added MgO content. The influence of Mg-doping on the superconducting transition temperatures of YBCO grains fabricated using these seeds is investigated. Finally, an optimum MgO content of the generic seed that effectively controls the orientation of the seeded grain without compromising its superconducting properties is suggested from the many seed crystals fabricated with a wide range of Mg-rich addition

Growth rate and superconducting properties of Gd-Ba-Cu-O bulk superconductors melt processed in air

A generic Mg-doped Nd-Ba-Cu-O seed crystal has been developed recently for the fabrication of any type of rare earth (RE) based (RE)-Ba-Cu-O single grain bulk superconductor in air. The new generic seed simplifies significantly the top seeded melt growth (TSMG) process for light rare earth based (Nd, Sm, Gd, or mixed rare earth elements) bulk superconductors, in particular. GdBCO single grains have been fabricated successfully in air using the new seed in a cold-seeding process. In this study, precursor powders were enriched with different amounts of BaO2 to investigate the extent of substitution of Gd for Ba in the Gd1+xBa2-xCu3O7-delta solid solution phase. The growth process of large single grains in air was investigated at various growth temperatures under isothermal processing conditions. Crystal growth rate as a function of under-cooling and BaO2 content has been determined from these experiments. The spatial variation of Tc and transition temperature width for applied field aligned along the a/b and c-axis of grains fabricated with different BaO2 content has also been investigated in order to understand the extent of the formation of Gd/Ba solid solution with varying growth temperature and precursor composition. These results have been used to establish the optimum conditions for fabricating solid solution-free, large single grains of GdBCO in air

Bulk superconducting nano-composites with high critical currents

Flux pinning sites are most effective if their size is comparable to the superconducting coherence length, which is on the nano-meter scale for RE-Ba-Cu-O superconductors [RE = rare earth element]. Introducing nano-phase inclusions directly into the bulk superconducting material has only been partially successful to date, however, due primarily to the absence of chemically stable phases that can co-exist with RE-Ba-Cu-O without suppressing its key superconducting properties. We have identified novel isostructural phases based on (RE)2Ba4CuMOy (where M = W, Zr, Nb, Ag and Bi) and have fabricated successfully superconducting bulk nano-composites with a high current carrying capability. The average size of the nano-inclusions is observed to vary from 20 nm to 300 nm depending on element M. An observed improvement in Jc under low and high external magnetic fields at 77 K correlates directly with an increased density of nano-inclusions in the superconducting matrix

Optical study of phase transitions in single-crystalline RuP

RuP single crystals of MnP-type orthorhombic structure were synthesized by the Sn flux method. Temperature-dependent x-ray diffraction measurements reveal that the compound experiences two structural phase transitions, which are further confirmed by enormous anomalies shown in temperature-dependent resistivity and magnetic susceptibility. Particularly, the resistivity drops monotonically upon temperature cooling below the second transition, indicating that the material shows metallic behavior, in sharp contrast with the insulating ground state of polycrystalline samples. Optical conductivity measurements were also performed in order to unravel the mechanism of these two transitions. The measurement revealed a sudden reconstruction of band structure over a broad energy scale and a significant removal of conducting carriers below the first phase transition, while a charge-density-wave-like energy gap opens below the second phase transition.Comment: 5 pages, 6 figure

Neutrino-Mixing-Generated Lepton Asymmetry and the Primordial 4^4He Abundance

It has been proposed that an asymmetry in the electron neutrino sector may be generated by resonant active-sterile neutrino transformations during Big Bang Nucleosynthesis (BBN). We calculate the change in the primordial $^4$He yield $Y$ resulting from this asymmetry, taking into account both the time evolution of the $\nu_e$ and $\bar\nu_e$ distribution function and the spectral distortions in these. We calculate this change in two schemes: (1) a lepton asymmetry directly generated by $\nu_e$ mixing with a lighter right-handed sterile neutrino $\nu_s$; and (2) a lepton asymmetry generated by a $\nu_\tau\leftrightarrow\nu_s$ or $\nu_\mu\leftrightarrow\nu_s$ transformation which is subsequently partially converted to an asymmetry in the $\nu_e\bar\nu_e$ sector by a matter-enhanced active-active neutrino transformation. In the first scheme, we find that the percentage change in $Y$ is between -1% and 9% (with the sign depending on the sign of the asymmetry), bounded by the Majorana mass limit m_{\nu_e}\la 1 eV. In the second scheme, the maximal percentage reduction in $Y$ is 2%, if the lepton number asymmetry in neutrinos is positive; Otherwise, the percentage increase in $Y$ is \la 5% for m^2_{\nu_\mu,\nu_\tau}-m^2_{\nu_s}\la 10^4 eV. We conclude that the change in the primordial $^4$He yield induced by a neutrino-mixing-generated lepton number asymmetry can be substantial in the upward direction, but limited in the downward direction.Comment: 15 pages, 7 figures, submitted to PR