1,399 research outputs found

    Shepherd's Dilemma

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    Recent outbreaks of Rift Valley Fever in sheep have led to boycotts of African livestock by Middle Eastern importers. To normalize trade, attempts have been made to apply new livestock forecasting and monitoring technologies. In this process, producers have exhibited a resistance in revealing livestock health information, a resistance that could jeopardize the information system and lead to further boycotts. We investigate the incentives governing this problem and model the most fundamental contract issues, those concerning reputation and credibility. Equilibrium contracts require that the buyer compensate the producer for private information to address the shepherd's dilemma of concealing livestock information (and facing continued boycotts) or revealing the information and being blacklisted.Livestock Production/Industries,

    An evaluation of students' and lecturers' use of technologies: an engineering case study.

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    yesThe introduction in the early 1990s of the world wide web was a significant factor in the creation of a global information society, allowing new possibilities to work, entertain and communicate, from home, at the workplace or on the move. In recent years, there have been significant advances in information technology (IT), while a new generation of applications that are able to harness the power of the world wide web has been introduced under the banner of Web 2.0. The increased capabilities of IT and the nature of Web 2.0 applications have attracted interest from the academic community as a means of enhancing the delivery of higher education. This paper considers the implications of introducing technology into the higher education sector from the perspectives of academic staff and students, with particular emphasis on the use of technology and Web 2.0 applications, and the relationship between technology and teaching and learning

    Selective oxidative degradation of azo dyes by hydrogen peroxide catalysed by manganese(II) ions

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    Manganese(II) ions catalyse the oxidative degradation of Calmagite (H3CAL) dye in aqueous solution at 20 ± 1 °C in the pH range 7.5–9.0 using hydrogen peroxide (H2O2) as oxidant by a mechanism that involves strong complexation to the MnII centre. It is proposed that [MnIII(CAL)(O2H)]− i.e. a dye coordinated hydroperoxyl (O2H−) MnIII complex is formed and bleaching of the dye is initiated by an electron-transfer to MnIII, with the binding of H2O2 being the rate determining step. At pH 9.0 in (bi)carbonate, HCO3−, H3CAL is rapidly bleached via the in situ formation of coordinated peroxycarbonate (HCO4−); a TOF (TOF = moles of dye bleached per mole of manganese per hour) of ∼5000 h−1 can be achieved. The bleaching of the related azo dyes Orange II and Orange G is different because, unlike Calmagite, they lack an o,o-dihydroxy motif so are unable to complex strongly to MnII and no oxidation to MnIII occurs. At pH 8.0 (phosphate buffer) Orange II and Orange G are not bleached but bleaching can be achieved at pH 9.0 (HCO3− buffer); the rate determining step is dye coordination and it is proposed bleaching is achieved via an outer-sphere oxygen atom transfer. Mechanisms for dye bleaching at pH 8.0 and pH 9.0 are proposed using data from EPR, UV/VIS and ESI-MS. MnII/H2O2/HCO3− form a potent oxidising mixture that is capable of removing stubborn stains such as curcumin
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