When Does Paternalistic Control Positively Relate to Job Satisfaction and Citizenship Behavior in Taiwan?:The Role of Follower Expectation

Although prior research predicts mainly that followers expect leaders to exert less paternalistic control (such as emphasis on discipline, didactic instruction, and belittling followers), we argue that such an expectation may not be stable overtime or across settings. Based on the connectionist perspectives of implicit leadership theories, we propose a follower expectation model of paternalistic control, in which followers compare their perceived with expected levels of paternalistic control. Two inconsistent conditions—insufficient and excessive control—are identified, and the consistency between perceived and expected paternalistic control is predicted to relate to favorable follower outcomes. We examine this model by conducting two daily experience sampling studies in Taiwan. Our findings indicate that insufficient control is as unfavorable as excessive control in lowering followers’ job satisfaction and citizenship behavior, and this pattern is particularly salient in terms of emphasis on discipline and the belittling of followers. A supplemental, qualitative analysis additionally demonstrated the conditions under which the expectation–perception consistency regarding belittling followers relates to favorable follower responses. (PsycInfo Database Record (c) 2023 APA, all rights reserved

Priprava toplinskoizolacijske žbuke s FGD-gipsom

Thermal insulation gypsum plaster was prepared from flue gas desulphurization (FGD) gypsum. K12 is more recommendable as foaming agent, when the mass fraction of K12 is around 0.1 %, the setting time and compressive strength meet the requirements of gypsum-based construction materials. In the meanwhile, the thermal conductivity is 0.18 W m–1 K–1, which can be used as a thermal insulation material. The hemihydrate mixtures obtained, allow the design of a new wall structure, which is more efficient as a thermal insulation system. The wall heat transfer coefficient test was carried out to compare thermal performance of two different thermal insulation systems. Compared with the thermal performance of a conventional system, the heat transfer coefficient of the new system was reduced by 5.6 %. Finally, energy-saving analysis of a building was carried out to compare the energy-saving effect of the conventional and new systems of building. The energy-savings of the building with the new system increased by almost 2 %, thus resulting in low energy consumption of the building.Toplinskoizolacijska gipsana žbuka izrađena je od gipsa nastalog odsumporavanjem dimnog plina (FGD). Uz maseni udjel sredstva za pjenjenje (K12) 0,1 % toplinska provodnost iznosi 0,18 W m–1 K–1 pa se materijal može upotrijebiti za toplinsku izolaciju. Žbuka i sredstvo za pjenjenje uključeni su u novi tip zidne toplinske izolacije. Koeficijent prijenosa topline novog izolacijskog sustava određen je eksperimentalno i iznosi 0,608 W m–2 K–1. Na temelju analize zaključeno je da se s novim sustavom ušteda energije u zgradi može popeti do 66,99 %. Novi materijal može imati velik utjecaj na energijsku učinkovitost zgrade

Polo-like kinase 1 regulates mitotic arrest after UV irradiation through dephosphorylation of p53 and inducing p53 degradation

AbstractUltraviolet (UV) irradiation can result in cell cycle arrest. The reactivation of Polo-like kinase 1 (Plk1) is necessary for cell cycle reentry. But the mechanism of how Plk1 regulates p53 in UV-induced mitotic arrest cells remained elusive. Here we find that UV treatment leads HEK293 cells to inverse changes of Plk1 and p53. Over-expression of Plk1 rescue UV-induced mitotic arrest cells by inhibiting p53 activation. Plk1 could also inhibit p53 phosphorylation at Ser15, thus facilitates its nuclear export and degradation. Further examination shows that Plk1, p53 and Cdc25C can form a large complex. Plk1 could bind to the sequence-specific DNA-binding domain of p53 and active Cdc25C by hyperphosphorylation. These results hypothesize that Plk1 and Cdc25C participate in recovery the mitotic arrest through binding to the different domain of p53. Cdc25C may first be actived by Plk1, and then its phosphatase activity makes p53 dephosphorylated at Ser15

A Structural Gel Composite Enabled Robust Underwater Mechanosensing Strategy with High Sensitivity

One of the key challenges in developing gel-based electronics is to achieve robust sensing performance, by overcoming the intrinsic weaknesses such as unwanted swelling induced deformation, signal distortion caused by dehydration, large hysteresis in sensing signal, etc. In this work, we proposed a structural gel composite (SGC) approach by encapsulating the conductive hydrogel/MXene with a lipid gel (Lipogel) layer through an in situ polymerization. The hydrophobic Lipogel coating fulfils the SGC with unique anti-swelling property at an aqueous environment and excellent dehydration feature at an open-air, thus leading to long-term ultra-stability (over 90 days) and durability (over 2000 testing cycles) for underwater mechanosensing applications. As a result, the SGC based mechanoreceptor demonstrates a high and stable sensitivity (GF of 14.5). Moreover, several SGC based conceptual sensors with high sensitivity are developed to unveil their profound potentials in underwater monitoring of human motions, waterproof anti-counterfeiting application, and tactile trajectory tracking

Polyhedral Carbon Anchored on Carbon Nanosheet with Abundant Atomic Fe-Nx Moieties for Oxygen Reduction

Carbon-based single-atom iron electrocatalysts with nitrogen coordination (CSAIN) have recently shown enormous promise to replace the costly Pt for boosting the cathodic oxygen reduction reaction (ORR) in fuel cells. However, there remains a great challenge to achieve highly efficient CSAIN catalysts for the ORR in acidic electrolytes. Herein, a novel CSAIN catalyst is synthesized by pyrolyzing a precursor mixture consisting of metal–organic framework and conductive polymer hybrid. After pyrolysis at a high temperature, the CSAIN with a structure of carbon nanosheet supported polyhedral carbon is achieved, where the unique structure endows CSAIN with expediting electron transfer and mass transport, as well as largely exposed surface to host atomically dispersed iron active sites. As a result, the optimal CSAIN catalyst shows a high ORR activity with its half-wave potential of 0.77 V (vs RHE) and a Tafel slope of 74.1 mV dec–1, which are comparable to that of commercial Pt/C catalyst (0.80 V and 81.9 mV dec–1)

Manipulating Multiple Order Parameters via Oxygen Vacancies: The case of Eu0.5Ba0.5TiO3-{\delta}

Controlling functionalities, such as magnetism or ferroelectricity, by means of oxygen vacancies (VO) is a key issue for the future development of transition metal oxides. Progress in this field is currently addressed through VO variations and their impact on mainly one order parameter. Here we reveal a new mechanism for tuning both magnetism and ferroelectricity simultaneously by using VO. Combined experimental and density-functional theory studies of Eu0.5Ba0.5TiO3-{\delta}, we demonstrate that oxygen vacancies create Ti3+ 3d1 defect states, mediating the ferromagnetic coupling between the localized Eu 4f7 spins, and increase an off-center displacement of Ti ions, enhancing the ferroelectric Curie temperature. The dual function of Ti sites also promises a magnetoelectric coupling in the Eu0.5Ba0.5TiO3-{\delta}.Comment: Accepted by Physical Review B, 201

Conformally Anodizing Hierarchical Structure in a Deformed Tube towards Energy-saving Liquid Transportation

The creation of drag-reducing surfaces in deformed tubes is of vital importance to thermal management, energy, and environmental applications. However, it remains a great challenge to tailor the surface structure and wettability inside the deformed tubes of slim and complicated feature. Here, we describe an electrochemical anodization strategy to achieve uniform and superhydrophobic coating of TiO2 nanotube arrays throughout the inner surface in deformed/bend titanium tubes. Guided by a hybrid carbon fibre cathode, conformal electric field can be generated to adaptatively fit the complex geometries in the deformed tube, where the structural design with rigid insulating beads can self-stabilize the hybrid cathode at the coaxial position of the tube with the electrolyte flow. As a result, we obtain a superhydrophobic coating with a water contact angle of 157° and contact angle hysteresis of less than 10°. Substantial drag reduction can be realised with an overall reduction up to 25.8 % for the anodized U-shaped tube. Furthermore, we demonstrate to spatially coat tubes with complex geometries, to achieve energy-saving liquid transportation. This facile coating strategy has great implications in liquid transport processes with the user-friendly approach to engineer surface regardless of the deformation of tube/pipe

Genetic Variations in Plasma Circulating DNA of HBV-Related Hepatocellular Carcinoma Patients Predict Recurrence after Liver Transplantation

BACKGROUND: Recurrence prediction of hepatitis B virus (HBV)-related hepatocellular carcinoma (HCC) patients undergoing liver transplantation (LT) present a great challenge because of a lack of biomarkers. Genetic variations play an important role in tumor development and metastasis. METHODS: Oligonucleotide microarrays were used to evaluate the genetic characteristics of tumor DNA in 30 HBV-related HCC patients who were underwent LT. Recurrence-related single-nucleotide polymorphism were selected, and their prognostic value was assessed and validated in two independent cohorts of HCC patients (N = 102 and N = 77), using pretransplant plasma circulating DNA. Prognostic significance was assessed by Kaplan-Meier survival estimates and log-rank tests. Multivariate analyses were performed to evaluate prognosis-related factors. RESULTS: rs894151 and rs12438080 were significantly associated with recurrence (P = .003 and P = .004, respectively). Multivariate analyses demonstrated that the co-index of the 2 SNPs was an independent prognostic factor for recurrence (P = .040). Similar results were obtained in the third cohort (N = 77). Furthermore, for HCC patients (all the 3 cohorts) exceeding Milan criteria, the co-index was a prognostic factor for recurrence and survival (P<.001 and P = .002, respectively). CONCLUSIONS: Our study demonstrated first that genetic variations of rs894151 and rs12438080 in pretransplant plasma circulating DNA are promising prognostic markers for tumor recurrence in HCC patients undergoing LT and identify a subgroup of patients who, despite having HCC exceeding Milan criteria, have a low risk of post-transplant recurrence